材料热处理学报, 2010, 31(1): 3-9.
相变研究的重要性——以Spinodal分解示例(为庆贺《材料热处理学报》创刊30周年而作)

徐祖耀 1,

1.上海交通大学材料科学与工程学院,上海,200240

以Spinodal分解为例,说明相变研究的重要意义.铁素体不锈钢中呈现400~550℃时效脆性的原由为Spinodal分解而非有序化.介绍了含不溶区间及Spinodal线的Fe-Cr相图.Mn-Al-C钢奥氏体经Spinodal分解显示抗拉强度和屈服强度分别增至1120 MPa和1080 MPa,伸长率约30%,值得给予关注.Cu-15Ni-8Sn和Cu-15Ni-8Sn-0.2Nb合金由于Spinodal分解和有序析出相呈显著强化,并具良好应力松弛,高的弹性模量和导电性.Cu-Ni-Sn经Spinodal分解还会出现胞状或条状组织,称非连续Spi-nodal分解,铝合金时效时也会发生Spinodal分解,Co_(45),Cu_(55)薄膜通过Spinodal分解显示18%的最大巨磁阻.
关键词: 相变   Spinodal分解   Fe-Cr系   Fe-Mn-Al-C   Cu-Ni-Sn   Al-Zn-Mg   CoCu
引用: 徐祖耀 相变研究的重要性——以Spinodal分解示例(为庆贺《材料热处理学报》创刊30周年而作). 材料热处理学报, 2010, 31(1): 3-9. doi: 
参考文献:
[1] 徐祖耀 .热处理的基本理论-相变研究的新进展(一)[J].金属热处理学报,1980,1(01):1-14.
[2] 徐祖耀 .热处理的基本理论-相变研究的新进展(二)[J].金属热处理学报,1980,1(02):1-15.
[3] Williams R O .Further studies of the iron-chromium system[J].Transactions TMS-AIME,1958,212:497-4502.
[4] Williams R O;Paxton H W .The nature of ageing of binary iron-chromium alloys around 500 ℃[J].Journal of British Iron and Steel Inst,1957,185:358-3374.
[5] Marcinowski M J;Fisher R M;Szirmae A .Effect of 500 ℃ aging on the deformation behavior of an iron-chromium alloy[J].Transactions TMS-AIME,1964,230:676-689.
[6] Brenner S S;Miller M K;Sofia W A .Spinodal decomposition of iron-32at% chromium at 470 ℃[J].Sctipta Metall,1982,16:831-8836.
[7] Cook A J;Jones F W .The brittle constituent of the iron-chromium system[J].The Journal of the Iron and Steel Institute,1943,168:217-2226.
[8] Tagaya M;Nenno S;Nishiya Z .The iron-chromium superlattice[J].Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals,1951,B-15:235-2236.
[9] Hasumoto H;Saito H A;Sugihara M .On the anomaly of the specific heat at high temperature in the alpha phase alloys of iron and chromium[J].Science Reports of the Research Institutes Tohoku University:Series A,1953,5:203-2207.
[10] Imai A;Kumada K .Study on high chromium steel,Ⅰ:On the anomaly of solid solution of the iron-chromium system at high temperature Ⅱ:On the alpha solid solution of Fe-Cr system at high temperature[J].Science Reports of the Research Institutes Tohoku University:Series A,1953,5:218-226, 520-532.
[11] Josso E .Interpretation of the brittleness at 475 ℃ for Fe-Cr alloys[J].Comptes rendus de l'Académie des sciences,1955,240:776-7778.
[12] Pomey G;Bastein P .The transformation of iron-chromium alloys of roughly equiatomic composition[J].Revue De Metallurgie,1956,53:147-1160.
[13] Takoda S;Nagai E O .Mem Fac Eng[D].Nagoya University,1956.
[14] Fisher R M;Dulis E J;Carroll K G .Identification of the precipitates accompanying 885 °F embrittlement in chromium steels[J].Transactions AIME,1953,197:690-6695.
[15] Imai Y;Izumiyama M;Masumoto T .[J].Science Reports of the Research Institutes Tohoku University:Series A,1966,18:56.
[16] Chandra D;Schwartz L H .Mossbauer effect study of the 475 ℃ decomposition of Fe-Cr[J].Metallurgical and Materials Transactions,1971,2:511-5519.
[17] Nishizawa T;Hasebe M;Ko M .Thermodynamic analysis of solubility and miscibility gap in ferromagnetic alpha iron alleys[J].Acta Metallurgica,1976,27:817-828.
[18] Liu Xingjun;Hao Shiming .An analysis on interaction parameters of binary solid solutions[J].Calphad-computer coupling of phase diagrams and thermochemistry,1993,17:67-678.
[19] Miller M K;Hyde J M;Hetherington M G;Cerezo A,Smith G D W,Elliott C M .Spinodal decomposition in Fe-Cr alloys:Experimental study at the atomic level and comparison with computer models-Ⅰ.Introduction and methodology[J].Acta Metallurgica Et Materialia,1995,43:3385-33401.
[20] Hyde J M;Miller M K;Hetherington M G;Cerezo A,Smith G D W,Elliott C.M .Spinodal decomposition in Fe-Cr alloys:Experimental study at the atomic level and comparison with computer models-Ⅱ.Development of domain size and composition amplitude[J].Acta Metallurgica Et Materialia,1995,43:3403-33413.
[21] Hyde J M;Miller M K;Hetheringtun M G;Cerezo A,Smith G D W,Elliott C M .Spinodal decomposition in Fe-Cr alloys:Experimental study at the atomic level and eompariann with computer models-Ⅲ.Development of morphology[J].Acta Metallurgica Et Materialia,1995,43:3415-33426.
[22] Ujihara T;Osamura K .Kinetics analysis of epinodal decomposition process in Fe-Cr alloys by small angle neutron scattering[J].Acta Materialia,2000,48:1629-11637.
[23] Murayama M;Katayama;Y Hono K .Microstractural evolution in a 17 -4 PH stainless steel after aging at 400 ℃[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1999,30:345-3353.
[24] Wang Jun;Zou Hong;Li Cong;Qiu Shaoyu Shun Baoluo .The spinodal decomposition in 17-4PH stainless steel subjected to long-term aging at 350 ℃[J].Materials Characterization,2008,59:587-591.
[25] Benerji S K .An Austenitie stainless steel without nickel and chromium[J].Metal Progress,1978,113:59-562.
[26] Han K H;Choo W K .Phase decomposition of rapidly solidified Fe-Mn-Al-C nustenitic alloys[J].Metallurgical and Materials Transactions,1989,2OA:205-2214.
[27] Shun T;Wan C M;Byrne J G .A study of work hardening in austenitic Fe-Mn-C and Fe-Mn-Al-C alloys[J].ACTA METALLURGICA,1992,40:3407-33412.
[28] Han K H;Yoon J C;Choo W K .TEM evidence of modulated structure in Fe-Mn-Al-C austenitic alloys[J].Scripta Metallurgica,1986,20:33-336.
[29] Choo W K;Kim J H;Yoon J C .Microstructnral change in austenitic Fe-30.0wt% Mn-7.8wt% Al-1.3wt% C initiated by spinodal decomposition and its influence on mechanical properties[J].Acta Materialia,1997,45:4877-44885.
[30] Cahn J W .Hardening by spinodal decomposition[J].Acta Metallurgica,1963,11:1275-11282.
[31] Ditchek B;Schwartz L H .Application of spinodal alloys[J].Annual Review of Materials Science,1979,9:219-2253.
[32] Lougon J T .Tin and its uses[J].,1983,137:1.
[33] 江伯鸿;魏庆;徐祖耀;王承宝,许雄成 .Cu-15Ni-8Sn及Cu-15Ni-8Sn-0.2Nb Spinodal型弹性合金的研究[J].仪表材料,1989,2(05):257-264.
[34] J.-C.Zhao;M.R.Notis .Spinodal decomposition, ordering transformation, and discontinuous precipitation in a Cu-15Ni-8Sn alloy[J].Acta materialia,1998(12):4203-4218.
[35] Gronsky R;Thomas G .Discontinuous coarsening of spinodally decomposed Cu-Ni-Fe alloys[J].Acta Metallurgica,1975,23:1 163-11 171.
[36] Ramanarayan H;Abinandanan T A .Grain boundary effects on Spinodal decomposition Ⅱ:Discontinuous microstructures[J].Acta Materialia,2004,52:921-9930.
[37] Binder K;P Haason;刘治国.失稳分解[A].北京:科学出版社,1999:407.
[38] Shen K;Yin Z M;Wang T .On spinodal decomposition in aging 7055 aluminum alloys[J].Materials Science and Engineering A,2008,477:395-3398.
[39] Mebed AM;Howe JM .Spinodal induced homogeneous nanostructures in magnetoresistive CoCu granular thin films[J].Journal of Applied Physics,2006(7):74310-1-74310-5-0.
[40] TOSHIYUKI KOYAMA;TORU MIYAZAKI;ABD Et-AZEAM M. MEBED .Computer Simulations of Phase Decomposition in Real Alloy Systems Based on the Modified Khachaturyan Diffusion Equation[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,1995(10):2617-2623.

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