{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"5-O-三苯硅基<span style=\"color:red\">阿维菌素</span><span style=\"color:red\">B1a</span>与羧酸在4-二甲氨基吡啶 (DMAP)/二环己基碳二亚胺 (DCC)体系中直接酯化,得到10种5-O-三苯硅基-4＂-O-酰基<span style=\"color:red\">阿维菌素</span><span style=\"color:red\">B1a</span>衍生物,产率55%～76%. 生测结果表明,4＂位不同的取代基团对化合物的杀虫活性有不同的影响,其中部分化合物具有较好的杀虫、杀螨活性.","authors":[{"authorName":"廖联安","id":"a1e5e2ab-aada-4819-b50c-c1f073dd371c","originalAuthorName":"廖联安"},{"authorName":"李正名","id":"1fc17276-e8c7-489f-88a1-72454aa87321","originalAuthorName":"李正名"},{"authorName":"方红云","id":"55693465-f5f6-4b93-9bb7-40e04f0851f5","originalAuthorName":"方红云"},{"authorName":"赵卫光","id":"e63b9e33-f87a-426e-a4e9-be4f219ba222","originalAuthorName":"赵卫光"},{"authorName":"范志金","id":"958a7b5c-1860-40c3-8376-eda772a01db6","originalAuthorName":"范志金"},{"authorName":"陈明德","id":"5e4ea558-89c6-452c-97f4-f048473e8fa6","originalAuthorName":"陈明德"},{"authorName":"刘桂龙","id":"d225f7b9-f1b2-4bf0-ad63-fd0ff1aa9ed7","originalAuthorName":"刘桂龙"}],"doi":"10.3969/j.issn.1000-0518.2002.06.003","fpage":"521","id":"7e4a0846-84ce-4a81-b454-cd811169de76","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"9082fb2d-461c-4645-b0a7-edc46713d8c2","keyword":"<span style=\"color:red\">阿维菌素</span><span style=\"color:red\">B1a</span>","originalKeyword":"阿维菌素B1a"},{"id":"c4dccb3c-92bf-4b28-b638-219f710e7a63","keyword":"酯化","originalKeyword":"酯化"},{"id":"8ced3ee6-e1b7-4f6c-88f2-c188437a45a6","keyword":"二甲氨基吡啶/二环己基碳二亚胺","originalKeyword":"二甲氨基吡啶/二环己基碳二亚胺"},{"id":"765aabd2-5e3e-434e-9050-65d4dfc16b05","keyword":"生物活性","originalKeyword":"生物活性"}],"language":"zh","publisherId":"yyhx200206003","title":"5-O-三苯硅基-4＂-O-酰基<span style=\"color:red\">阿维菌素</span><span style=\"color:red\">B1a</span>的合成和生物活性","volume":"19","year":"2002"},{"abstractinfo":"伊维<span style=\"color:red\">菌素</span>是一种安全、广谱的抗寄生虫药物,目前已广泛用于人体及动物的抗寄生虫治疗.伊维<span style=\"color:red\">菌素</span>主要采用对<span style=\"color:red\">阿维菌素</span>选择性催化加氢来制备的.介绍了以铑、钌、铱及其配合物为催化剂,在均相或多相体系中对<span style=\"color:red\">阿维菌素</span>的催化反应,并对其加氢反应的条件、产率进行了比较.","authors":[{"authorName":"马晓艳","id":"23331d55-ae7c-468f-b9c7-e9118586b22b","originalAuthorName":"马晓艳"},{"authorName":"陈涛","id":"5c7cf978-e143-48f3-bf4b-fc1ad9f0a15b","originalAuthorName":"陈涛"},{"authorName":"黄梁","id":"18130da5-57f8-46ba-8c73-9986133b7d87","originalAuthorName":"黄梁"}],"doi":"10.3969/j.issn.1004-0676.2010.03.013","fpage":"60","id":"9c33b977-929d-4528-91a1-f057a85afeee","issue":"3","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"8619430e-d11a-471f-8bd9-8ef2e72cc87c","keyword":"催化化学","originalKeyword":"催化化学"},{"id":"41bea703-448b-419e-89c7-a4f2af617ca2","keyword":"伊维<span style=\"color:red\">菌素</span>","originalKeyword":"伊维菌素"},{"id":"8c8ec6cf-183c-4219-922f-2c08e74a0ec3","keyword":"<span style=\"color:red\">阿维菌素</span>","originalKeyword":"阿维菌素"},{"id":"8f649211-5c19-4b77-a717-d828a9e41af8","keyword":"选择加氢","originalKeyword":"选择加氢"}],"language":"zh","publisherId":"gjs201003013","title":"<span style=\"color:red\">阿维菌素</span>选择加氢制备伊维<span style=\"color:red\">菌素</span>的研究进展","volume":"31","year":"2010"},{"abstractinfo":"作者合成了4种膦配体钌配合物,并将它们应用于催化<span style=\"color:red\">阿维菌素</span>的氢化反应中,研究了其催化活性与选择性,并考察了温度、压力和反应时间对催化反应的影响.结果表明,RuCl2(PPh3)3、RuH(COOCH3)(PPh3)3有一定的催化性能;当氢气压力<span style=\"color:red\">1</span>MPa,温度60℃,反应6h,RuCl2(PPh3)3的催化效果较好;使用钌配合物催化<span style=\"color:red\">阿维菌素</span>的氢化反应能降低伊维<span style=\"color:red\">菌素</span>的生产成本.","authors":[{"authorName":"熊晓东","id":"383154d5-c7bb-4333-b088-3cc4eb2b011a","originalAuthorName":"熊晓东"},{"authorName":"吴松","id":"8044c8bc-96ca-4726-9849-60c571b99cab","originalAuthorName":"吴松"},{"authorName":"王胜国","id":"4b9b28bf-d9e9-43f8-ad47-cdfc7e9c989d","originalAuthorName":"王胜国"},{"authorName":"梁敬博","id":"ea87655b-f480-4f99-9ade-f3d651c8f25f","originalAuthorName":"梁敬博"}],"doi":"10.3969/j.issn.1004-0676.2008.01.001","fpage":"1","id":"b1e06cfc-8881-407b-863c-5f5751565198","issue":"1","journal":{"abbrevTitle":"GJS","coverImgSrc":"journal/img/cover/GJS.jpg","id":"38","issnPpub":"1004-0676","publisherId":"GJS","title":"贵金属"},"keywords":[{"id":"63e5b55b-1e8f-42d2-af1e-460de9007454","keyword":"催化化学","originalKeyword":"催化化学"},{"id":"ad7d9afd-05b8-4285-a8f2-9a4c55596fcd","keyword":"均相催化","originalKeyword":"均相催化"},{"id":"919d9f22-7ad5-4866-a490-542a854dfa21","keyword":"钌配合物","originalKeyword":"钌配合物"},{"id":"483a1c21-3eaf-4c1e-afdb-f49cbb92a29f","keyword":"<span style=\"color:red\">阿维菌素</span>","originalKeyword":"阿维菌素"},{"id":"64ce9370-3554-49db-a590-458ff4f17402","keyword":"氢化","originalKeyword":"氢化"}],"language":"zh","publisherId":"gjs200801001","title":"膦配体钌配合物催化<span style=\"color:red\">阿维菌素</span>氢化的研究","volume":"29","year":"2008"},{"abstractinfo":"以三聚氰胺-甲醛树脂为壁材,采用原位聚合法制备了甲胺基<span style=\"color:red\">阿维菌素</span>苯甲酸盐微胶囊,研究了三聚氰胺与甲醛的质量比、芯壁比、乳化剂、搅拌速度与时间、pH值、温度等因素对微胶囊形成的影响,对制备的微胶囊进行了表征,测定了甲维盐微胶囊化前后的光解率. 结果表明,三聚氰胺与甲醛质量比为<span style=\"color:red\">1</span>: 2、芯材与壁材质量比为3: 2、以质量分数<span style=\"color:red\">1</span>%羟乙基纤维素(HEC)为乳化剂、在1000 r/min搅拌速度下、pH=5.0和50 ℃保温2 h可制备出形貌较好、平均粒径4.4 μm的甲维盐微胶囊. 红外光谱分析证明,甲维盐已完全被包覆在微胶囊中. 紫外分光光度法测定其缓释性能良好. 光解实验表明,微胶囊化可有效降低甲维盐原药的光解.","authors":[{"authorName":"李伟","id":"84c6dc91-53ab-4ea7-acc8-a82706490554","originalAuthorName":"李伟"},{"authorName":"路福绥","id":"da8762af-3f32-44c9-a9f1-8e91a98eabca","originalAuthorName":"路福绥"},{"authorName":"郭雯婷","id":"3b516f9f-3638-4364-97fa-dea0d7f65b25","originalAuthorName":"郭雯婷"},{"authorName":"李慧","id":"1da1a12a-d706-41a1-97be-24226b0810c7","originalAuthorName":"李慧"}],"doi":"10.3724/SP.J.1095.2010.00160","fpage":"1381","id":"a82cfde3-08e3-425c-9155-6e378e02ceb3","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"769d41d6-1d54-4d9f-a6c3-7d851d70344b","keyword":"甲胺基<span style=\"color:red\">阿维菌素</span>苯甲酸盐","originalKeyword":"甲胺基阿维菌素苯甲酸盐"},{"id":"8173786f-e97c-492f-9a79-d046cdd81ad9","keyword":"微胶囊","originalKeyword":"微胶囊"},{"id":"cd860d4c-c8a8-42d8-9e47-c135a73a01e7","keyword":"原位聚合法","originalKeyword":"原位聚合法"},{"id":"766c8627-b268-4330-869a-6f78dfdd4d3d","keyword":"制备","originalKeyword":"制备"},{"id":"791b8501-cde4-4f9c-99cf-deaf0bf5fa57","keyword":"三聚氰胺-甲醛树脂","originalKeyword":"三聚氰胺-甲醛树脂"}],"language":"zh","publisherId":"yyhx201012004","title":"甲胺基<span style=\"color:red\">阿维菌素</span>苯甲酸盐微胶囊的制备与表征","volume":"27","year":"2010"},{"abstractinfo":"建立了牛肝中5种<span style=\"color:red\">阿维菌素</span>类药物残留的疏水整体柱在线固相萃取结合高效液相色谱-串联质谱测定的方法。以疏水的聚（甲基丙烯酸丁酯-乙二醇二甲基丙烯酸酯）整体柱（10 mm×2.1 mm）作为固相萃取介质，考察了上样流动相和洗脱流速对<span style=\"color:red\">阿维菌素</span>类药物的萃取效果，优化了梯度洗脱流动相的种类及质谱条件。方法在<span style=\"color:red\">1</span>~100μg／L范围内线性关系良好（ r﹥0.995），定量限为5μg／kg。在5、10、50、100μg／kg 添加水平的回收率为77.4％~98.4％，日内和日间相对标准偏差分别为4.46％~8.03％和4.79％~8.68％，并且该柱反复使用400次后未发现萃取效率降低。结果表明，该整体柱对牛肝中5种<span style=\"color:red\">阿维菌素</span>类药物能够有效萃取，并且可以重复使用。该方法简单，自动化程度高，可应用于常规<span style=\"color:red\">阿维菌素</span>类药物残留分析。","authors":[{"authorName":"李欣","id":"bf32a7c3-c91d-4edf-9d66-13c1fc8832fe","originalAuthorName":"李欣"},{"authorName":"张瑶琴","id":"d61a2fb3-e89f-4418-beae-22e15899f4e5","originalAuthorName":"张瑶琴"},{"authorName":"艾连峰","id":"6f8c9680-c92b-4143-8832-77b0b3153236","originalAuthorName":"艾连峰"},{"authorName":"王学生","id":"e19a37c6-a4b9-4a2c-a0af-0f45b34cafe2","originalAuthorName":"王学生"},{"authorName":"王曼曼","id":"d28dddb8-0cbf-499d-a004-cd8c96ad10bb","originalAuthorName":"王曼曼"},{"authorName":"徐厚君","id":"c134c4be-fb10-4e48-a0df-1a73eeea22f0","originalAuthorName":"徐厚君"},{"authorName":"郝玉兰","id":"f524b008-289c-4423-a635-8f5deea6720e","originalAuthorName":"郝玉兰"}],"doi":"10.3724/SP.J.1123.2015.02062","fpage":"590","id":"d8ac4fa2-d78a-4608-bc7d-859a69a06a72","issue":"6","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"ad4154a2-84ad-458c-a24e-0bacacdced90","keyword":"疏水整体柱","originalKeyword":"疏水整体柱"},{"id":"feb9ad4c-958f-4650-a0bd-9ebb4818bb76","keyword":"在线固相萃取","originalKeyword":"在线固相萃取"},{"id":"ad7886f3-b365-4c5b-a82d-dd576333d053","keyword":"高效液相色谱-串联质谱","originalKeyword":"高效液相色谱-串联质谱"},{"id":"2885ed2b-0259-41cd-886f-c428c1ad31b2","keyword":"<span style=\"color:red\">阿维菌素</span>类药物","originalKeyword":"阿维菌素类药物"},{"id":"d9b2aef7-625a-4674-887d-b66a828ddca5","keyword":"牛肝","originalKeyword":"牛肝"}],"language":"zh","publisherId":"sp201506011","title":"疏水整体柱在线固相萃取与高效液相色谱-串联质谱联用测定牛肝中5种<span style=\"color:red\">阿维菌素</span>类药物残留","volume":"","year":"2015"},{"abstractinfo":"建立了采用超高效液相色谱-电喷雾电离串联质谱同时检测茶叶中爱比<span style=\"color:red\">菌素</span>、甲胺基<span style=\"color:red\">阿维菌素</span>、乙酰胺基<span style=\"color:red\">阿维菌素</span>、伊维<span style=\"color:red\">菌素</span>、多拉<span style=\"color:red\">菌素</span>、莫西丁克残留的方法.试样经饱和氯化钠溶液浸润后,用乙腈提取,C18固相萃取小柱净化,超高效液相色谱-电喷雾串联质谱法(UPLC/ESI-MS/MS)测定.对流动相、监测离子、校正曲线等进行了优化和探讨.6种分析物在2.0～50 μg/L 范围内线性关系良好,相关系数均大于 0.9920.莫西丁克在5,10,20 μg/kg,其余分析物在2,5,10 μg/kg加标水平的平均回收率为61.7% ～85.4% ,相对标准偏差为9.37% ～17.19% .该方法可靠、稳定,可满足茶叶中<span style=\"color:red\">阿维菌素</span>类药物残留检测与确证的需要.","authors":[{"authorName":"杨方","id":"26d3340f-3a78-49af-b72f-deac2b5b246b","originalAuthorName":"杨方"},{"authorName":"杨守深","id":"1d1f039a-b4c0-4c5a-9696-73496b474f57","originalAuthorName":"杨守深"},{"authorName":"林永辉","id":"efcb1f80-ef8d-4c5f-adc9-43615b66e9bb","originalAuthorName":"林永辉"},{"authorName":"郑丹萍","id":"7193536e-9641-42ca-b795-5b8847451c88","originalAuthorName":"郑丹萍"},{"authorName":"卢声宇","id":"cc832b35-7ffd-4330-acbc-68a0edff7716","originalAuthorName":"卢声宇"},{"authorName":"黄志强","id":"a55d044a-d054-46c7-b489-628130429ffc","originalAuthorName":"黄志强"},{"authorName":"张莹","id":"9a3064c9-6f02-4965-b4e9-4b37dcad856a","originalAuthorName":"张莹"}],"doi":"10.3321/j.issn:1000-8713.2009.02.005","fpage":"153","id":"23bf12b9-edbc-4150-9a53-22cb179782de","issue":"2","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"b80727ee-82d9-4705-9308-5983bc3cf22d","keyword":"超高效液相色谱-质谱联用法","originalKeyword":"超高效液相色谱-质谱联用法"},{"id":"3b2c8acd-9f18-4f61-b894-fc8324d87035","keyword":"<span style=\"color:red\">阿维菌素</span>类药物残留","originalKeyword":"阿维菌素类药物残留"},{"id":"c55618e9-221d-44a2-a7c3-6a3cf055ddf0","keyword":"茶叶","originalKeyword":"茶叶"}],"language":"zh","publisherId":"sp200902005","title":"超高效液相色谱-电喷雾电离串联质谱联用法检测茶叶中<span style=\"color:red\">阿维菌素</span>类药物残留","volume":"27","year":"2009"},{"abstractinfo":"建立了甘蓝和蘑菇中甲氨基<span style=\"color:red\">阿维菌素</span>苯甲酸盐的固相萃取-高效液相色谱荧光分析方法.蔬菜样品用乙酸乙酯提取,提取液旋转浓缩近干后用少量乙酸乙酯溶解,再经PRS固相萃取(SPE)柱净化,洗脱液经氮气吹干后用氮甲基咪唑和三氟乙酸酐衍生,衍生物用高效液相色谱分析,采用外标法定量.在添加浓度1.0～20.0 μg/kg范围内,平均添加回收率为78.6%～84.9%,日内相对标准偏差(RSD)为2.7%～6.0%,日间RSD为3.1%～8.9%,检出限为0.10 μg/kg.甲氨基<span style=\"color:red\">阿维菌素</span>苯甲酸盐衍生物在0.002～0.10 mg/L范围内呈良好的线性关系,相关系数为0.999 9.","authors":[{"authorName":"张艳","id":"81521320-742b-4587-9d5b-a18186580117","originalAuthorName":"张艳"},{"authorName":"吴银良","id":"8874e08d-bb40-42e9-9030-4d157abff6ec","originalAuthorName":"吴银良"},{"authorName":"胡继业","id":"f1662d5c-661c-4e2b-b7f7-c0b780f12376","originalAuthorName":"胡继业"},{"authorName":"王宏卫","id":"400e2708-47be-480d-af19-156f3c6ad688","originalAuthorName":"王宏卫"},{"authorName":"潘灿平","id":"0e3a6a9f-e28e-4e06-bec2-41c1a24a9fe4","originalAuthorName":"潘灿平"},{"authorName":"刘丰茂","id":"d3cc8a12-52b4-48b3-8bb9-d7be142ece47","originalAuthorName":"刘丰茂"}],"doi":"10.3321/j.issn:1000-8713.2008.01.022","fpage":"110","id":"5b34a2f3-52a3-47c4-8f6e-b02c45e48862","issue":"1","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"2e4a3771-f842-48b0-b6fb-84e5e2d51e21","keyword":"高效液相色谱法","originalKeyword":"高效液相色谱法"},{"id":"d3078187-f66d-469b-9055-872cb953af41","keyword":"固相萃取","originalKeyword":"固相萃取"},{"id":"9e5f8ec8-cb45-477e-9294-0ec5dc080e9d","keyword":"甲氨基<span style=\"color:red\">阿维菌素</span>苯甲酸盐","originalKeyword":"甲氨基阿维菌素苯甲酸盐"},{"id":"ed2538f2-d47d-4b2f-b535-c989905c9b7a","keyword":"残留","originalKeyword":"残留"},{"id":"bc37f9dc-33fa-48b0-be16-1a486f96c42a","keyword":"蔬菜","originalKeyword":"蔬菜"}],"language":"zh","publisherId":"sp200801022","title":"高效液相色谱荧光检测法测定蔬菜中残留的甲氨基<span style=\"color:red\">阿维菌素</span>苯甲酸盐","volume":"26","year":"2008"},{"abstractinfo":"建立了猪肉中<span style=\"color:red\">阿维菌素</span>、伊维<span style=\"color:red\">菌素</span>、多拉<span style=\"color:red\">菌素</span>、莫两<span style=\"color:red\">菌素</span>,乙酰氨基<span style=\"color:red\">阿维菌素</span>等5种<span style=\"color:red\">阿维菌素</span>类药物以及地克珠利、妥曲珠利、妥曲珠利砜、妥曲珠利亚砜等4种均三嗪类药物及其代谢物残留的高效液相色谱.串联质谱分析方法.样品采用乙腈提取,ODS粉分散固相萃取净化,经Venusil ASB C18色谱柱(150 mm × 2.1 mm,3.0 p,m)分离,电喷雾串联四极杆质谱多反应离子监测方式测定.9种分析物在0.005～0.2 mg/L范围内线性关系良好,相关系数均大于0.990.猪肉基质中9种分析物在0.005、0.01、0.02 mg/kg加标水平下.回收率为73.2%～91.5%,相对标准偏差为12%～17%.该方法稳定、可靠,可满足猪肉中<span style=\"color:red\">阿维菌素</span>类、均三嗪类药物残留的检测与确证.","authors":[{"authorName":"宫小明","id":"0987edb5-00ed-4193-b133-301b39d19c4a","originalAuthorName":"宫小明"},{"authorName":"孙军","id":"bdb15259-bf97-455a-9c65-0d5997fb8bc0","originalAuthorName":"孙军"},{"authorName":"董静","id":"6992ec9f-9d1b-4b88-a2da-f162c938d523","originalAuthorName":"董静"},{"authorName":"于金玲","id":"f55af11a-d742-4b3f-b600-ee2386eba78b","originalAuthorName":"于金玲"},{"authorName":"王洪涛","id":"db3f9355-b323-4159-ab24-fc57682621fa","originalAuthorName":"王洪涛"}],"doi":"10.3724/SP.J.1123.2011.00217","fpage":"217","id":"8b2092fd-87f2-4eff-964a-0ecce1003afa","issue":"3","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"9ba04a8f-9011-40d0-922c-b7bcf7fdaac5","keyword":"高效液相色谱-串联质谱","originalKeyword":"高效液相色谱-串联质谱"},{"id":"55dd68e3-96d7-4ada-901c-a37802b3083b","keyword":"<span style=\"color:red\">阿维菌素</span>类药物","originalKeyword":"阿维菌素类药物"},{"id":"b6c42ed1-0a19-43b7-aff5-340dcb3b6ffc","keyword":"地克珠利","originalKeyword":"地克珠利"},{"id":"2a58af1f-0039-46aa-a1eb-eb828593bf0c","keyword":"妥曲珠利及其代谢物","originalKeyword":"妥曲珠利及其代谢物"},{"id":"875d4154-5d54-4ea0-a856-888cc7fa709d","keyword":"猪肉","originalKeyword":"猪肉"}],"language":"zh","publisherId":"sp201103006","title":"高效液相色谱-串联质谱法测定猪肉中的<span style=\"color:red\">阿维菌素</span>类、地克珠利、妥曲珠利及其代谢物残留","volume":"29","year":"2011"},{"abstractinfo":"建立了邻苯二甲醛(OPA)柱后衍生-高效液相色谱测定玉米中伏马<span style=\"color:red\">菌素</span><span style=\"color:red\">B1</span>和<span style=\"color:red\">B</span>2(FB<span style=\"color:red\">1</span>和FB2)的方法.采用ZORBAX SB-C18色谱柱,以0.1 mol/L磷酸二氢钠溶液(pH 3.3)-甲醇为流动相,梯度洗脱.流动相流速为0.8mL/min,柱温40℃；衍生剂的流速为0.4 mL/min,衍生温度为室温.实验对衍生剂缓冲液的pH、衍生剂的浓度和流速、激发和发射波长等重要条件进行了优化.结果表明,衍生剂的pH在10.5、OPA的质量浓度为2 g/L、流速为0.4 mL/min、激发波长335 nm、发射波长440 nm时测定效果良好,FB<span style=\"color:red\">1</span>、FB2在0.2～20 mg/L范围内线性关系良好,相关系数大于0.999；FB<span style=\"color:red\">1</span>和FB2的检出限均为0.02 mg/kg;在0.1～4.0 mg/kg范围内,3个添加水平的平均回收率为82.5％ ～89.8％.该方法精确、简单、快速,适合玉米中FB<span style=\"color:red\">1</span>和FB2的测定.","authors":[{"authorName":"张晓旭","id":"4459f4a8-9351-4ba6-b444-b8d5a0d01e55","originalAuthorName":"张晓旭"},{"authorName":"肖志勇","id":"003d864f-fbac-4b2e-af1a-5ce301a78b95","originalAuthorName":"肖志勇"},{"authorName":"张红艳","id":"3e6ec186-fd4f-41eb-b385-6d2ccf7deaac","originalAuthorName":"张红艳"},{"authorName":"杨丽丽","id":"6e7e1903-573b-431d-b716-f47d47b26514","originalAuthorName":"杨丽丽"},{"authorName":"马丽艳","id":"f1e9e862-c331-4a49-beae-48e827287209","originalAuthorName":"马丽艳"}],"doi":"10.3724/SP.J.1123.2012.03048","fpage":"792","id":"4b5b0367-633f-4ced-bf85-556c3086d25e","issue":"8","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"3d7ba5ef-caf1-4432-bee9-e5812e6c4a2f","keyword":"高效液相色谱","originalKeyword":"高效液相色谱"},{"id":"716c7fa3-8c50-4d5c-adae-0e89111d691d","keyword":"邻苯二甲醛","originalKeyword":"邻苯二甲醛"},{"id":"25f7214d-eb50-4672-8678-d59690770d47","keyword":"柱后衍生","originalKeyword":"柱后衍生"},{"id":"d1a470a0-2a72-4227-ac44-07d383f93f68","keyword":"伏马<span style=\"color:red\">菌素</span>","originalKeyword":"伏马菌素"},{"id":"40158e40-c1a2-45ed-9275-780d5860568e","keyword":"玉米","originalKeyword":"玉米"}],"language":"zh","publisherId":"sp201208007","title":"柱后衍生-高效液相色谱法测定玉米中伏马<span style=\"color:red\">菌素</span><span style=\"color:red\">B1</span>和<span style=\"color:red\">B</span>2","volume":"30","year":"2012"},{"abstractinfo":"采用胶束电动毛细管色谱法(MECC)对硫酸多粘<span style=\"color:red\">菌素</span>E药物中的主要成分多粘<span style=\"color:red\">菌素</span>E<span style=\"color:red\">1</span>和E2进行了分离,并测定了多粘<span style=\"color:red\">菌素</span>E<span style=\"color:red\">1</span>、E2的含量.分别考察了电泳电压、表面活性剂种类、Brij-35(月桂醇聚氧乙烯醚)浓度、乙腈含量、磷酸盐缓冲液的pH值、氯化钠浓度等实验参数对实验结果的影响,从而确定了最佳的分离条件:电泳电压为10 kV,运行缓冲液为含有30 mmol/L Brij-35、5%(体积分数)乙腈、0.167 mol/L氯化钠的磷酸二氢钠缓冲液(0.01 mol/L,pH 4.1).在优化的实验条件下,E<span style=\"color:red\">1</span>和E2得到了较好的分离,分离度达到1.94.以多粘<span style=\"color:red\">菌素</span>E<span style=\"color:red\">1</span>为例,柱效和峰面积的日间及日内测定的相对标准偏差(RSD)均小于5% .E<span style=\"color:red\">1</span>和E2在硫酸多粘<span style=\"color:red\">菌素</span>E药物中的含量分别为67%和32% .该方法简便、快速、准确、重现性好.","authors":[{"authorName":"闫永娜","id":"53a286a3-78ef-45ab-b733-5b6673a184fb","originalAuthorName":"闫永娜"},{"authorName":"王利娟","id":"e7dbc9c5-3d0d-46d8-a32e-deb83f6cf3d8","originalAuthorName":"王利娟"},{"authorName":"杨更亮","id":"050e10b4-8ba9-4df3-a4c1-a3d6a3d5969f","originalAuthorName":"杨更亮"},{"authorName":"侯文欣","id":"1b8258a9-b567-4925-808b-efee7354bf76","originalAuthorName":"侯文欣"},{"authorName":"张巧霞","id":"a52d683c-8e66-4807-a10c-14de376ed220","originalAuthorName":"张巧霞"}],"doi":"10.3321/j.issn:1000-8713.2009.06.025","fpage":"860","id":"d5ce63fb-e548-42ff-8f5f-c239aceba8bf","issue":"6","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"bcbfe5e5-68df-411a-82d8-95899958ea8e","keyword":"胶束电动毛细管色谱","originalKeyword":"胶束电动毛细管色谱"},{"id":"f9a89151-2c3e-4149-ab6d-72890b07e339","keyword":"多粘<span style=\"color:red\">菌素</span>E<span style=\"color:red\">1</span>","originalKeyword":"多粘菌素E1"},{"id":"e83c1928-cf5c-4e64-a3c6-b1190309e071","keyword":"多粘<span style=\"color:red\">菌素</span>E2","originalKeyword":"多粘菌素E2"},{"id":"8b8a2dc0-04c2-4b27-a0a8-7d4e0618c0d8","keyword":"硫酸多粘<span style=\"color:red\">菌素</span>E","originalKeyword":"硫酸多粘菌素E"}],"language":"zh","publisherId":"sp200906025","title":"胶束电动毛细管色谱法测定硫酸多粘<span style=\"color:red\">菌素</span>E药物中的多粘<span style=\"color:red\">菌素</span>E<span style=\"color:red\">1</span>和E2","volume":"27","year":"2009"}],"totalpage":5122,"totalrecord":51218}