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ADVANCED SYNTHESIS OF LIGHT METALS

F.H. Froes(IMAP , University of Idaho , Moscow , ID 838443026 , USA Manuscript received 26 August 1996)

金属学报(英文版)

The synthesis, processing and mechanical properties of the light metals, aluminum,magnesium and titanium Produced by advanced techniques are reviewed. Synthesis techniques to be addressed will include rapid solidification, spray deposition, mechanical alloying, plasma Processing and vapor deposition.

关键词: :synthesis/processing , null , null , null , null , null , null , null , null , null , null

NICKEL-BASE ALLOY SHEET ALLOYS USED IN AEROSPACE APPLICATIONS

J.H. Tundermann(Inco Alloys International , Inc. , Huntington , WV 25705 , USA Manuscript received 26 August 1996)

金属学报(英文版)

Many gas turbine components are made from nickel alloy sheet. Most are used for directing or containing gases at high temperatures and pressures where metal temperatures can be as high as 1090℃ (2000°F). These applications included combustor systems, casings and liners, transition and exhaust ducting, afterburners, and thrust reversere. Light weight components and sub-assemblies call for alloy sheet with high levels of stength and oxidation resistance. Complex component design calls for excellent ductility and ease of fabrication.The wide range of nickel alloy sheet alloys presently used in aircraft and land-based gas turbines is briefly described and typical properties presented. New sheet alloy developments, involving INCONEL~* alloys 625LCF, 718SPF and MA754, are presented including the process routes involved and material properties.

关键词: :aerospace , null , null , null , null , null , null , null , null

DEVELOPMENT OF INCONEL ALLOY 783, A LOW THERMAL EXPANSION, CRACK GROWTH RESISTANT SUPERALLOY

J.H.Thndermann(Inco Alloys International , Inc. , Huntington , WV 25705 , USA Manuscript received 26 August 1996)

金属学报(英文版)

Low thermal expansion superalloys have been used for a number of years in a variety of applications, including gas turbine engines. The low thermal expansion characteristics of the most widely used class of materials are derived from the ferromagnetic characteristics of Ni, Fe, and Co-based austenitic matrices containing little or no Cr.Alloy developments have been aimed at improving the oxidation resistance and stress accelerated grain boundary oxygen (SAGBO) attack.INCONEL alloy 783 is an oxidation resistant, low coefficient of thermal expansion superalloy developed for gas turbine applications. Alloy 783 represents a culmination in the development, of an alloy system with very high alumtnum content that, in addition to forming γ′,causes βaluminide phase precipitation in the austenitic matrix.This type of structure can be processed to resist both SAGBO and general oxidation,while providing low thermal expansion and useful mechanical properties up to 700℃.Key aspects of the alloy's development are presented.

关键词: :coefficient of thermal expansion , null , null , null , null , null , null , null

Solidification Studies of 3003 Aluminium Alloys with Cu and Zr Additions

Majed M.R. Jaradeh , Torbjorn Carlbergy

材料科学技术(英)

The effects of Cu and Zr additions, on the microstructure formation, precipitation and ingot cracking, in commercial 3003 Al alloys have been studied. The investigation was carried out by characterizing the grain structure in DC-cast rolling ingots, and studying the solidification microstructure of Bridgman directionally solidified samples. To better understand the influence of the different Cu and Zr contents on the phase precipitations, differential thermal analysis (DTA) experiments were performed. Results from the ingot microstructure analysis show that in commercial alloys with relatively high contents of Cu and Zr, no significant differences in measured grain sizes compared to conventional 3003 Al alloys could be found. However, only Zr containing alloys exhibited significantly larger grain sizes. Increased grain refiner and/or titanium additions could compensate for the negative effects on nucleation normally following Zr alloying. Different types of precipitates were observed. Based on DTA experiments, increased Cu and Zr contents resulted in the formation of Al2Cu phase, and increased solidification range. It was also found that increased Mn content favors an early precipitation of Al6(Mn,Fe) giving relatively coarse precipitates. It was concluded that the Cu alloying has a detrimental effect on hot tearing.

关键词: Aluminium 3003 , null , null , null , null , null , null , null

Al_(80)Ni_6Y_8Co_4Cu_2 GLASS ALLOYS CONTAINING NANOSCALE PARTICLES BY ISOTHERMAL ANNEALING OR QUENCHING

Z. Bian , G. He and G.L. Chen (State Key Laboratory for Advanced Metals and Materials , University of Science and Technology Beijing , Beijing 100083 , China) J. Lu , D.J. Chen , G.C. Tu , G.J. Chen and X.J. Hu (Shougang Metallurgical Research Institute , Beijing 100085 , China)

金属学报(英文版)

Al80Ni6 Y8 Co4 Cu2 amorphous ribbons were isothermally annealed and a mixed structure consisting of α-Al particle with a size of less than 15nm and Al3Ni compound with a size of about 30nm was obtained. The crystallization kinetics of Al80Ni6 Y8 Co4 Cu2 amorphous alloy shows that the precipitation of α-Al particles is the growth process controlled by diffusion of the solute elements rejected from the growing crystals. By quenching at different cooling rates, a mixed structure consisting of nanoscale α-Al particles and the remaining glass matrix or structure consisting of nanoscale particle (Al phase or Al3Ni compound) with a size of about 100nm was formed. The addition of Co elements and Cu elements to Al-Ni-Y alloy systems increases the glass formation ability of the alloy and the thermal stability of the supercooled liquid region against crystallization, which results from significant difference of atomic size, strong bonding nature among constituent elements and the low diffisivity of the solute elements due to the concentration gradient in the growing front of crystals.

关键词: a mixed structure , null , null , null , null , null , null

COMPUTER SIMULATION OF PHASE SEPARATION IN CaO MgO Fe 2O 3 Al 2O 3 SiO 2 GLASS

Y.H. Xia 1) , T.P. Lou 1) , Z.T. Sui 1) and B. Li 2) 1) School of Material & Metallurgy , Northeastern University , Shenyang 110006 , China 2) Jiamusi University , Jiamusi 154007 , China

金属学报(英文版)

The fractal and spinodal decomposition models combined Monte Carlo method were used in computer simulation of phase separation from CaO MgO Fe 2O 3 Al 2O 3 SiO 2 glass. The fractal dimension was applied to quantitative analysis. The mechanism of phase separation was investigated. The results showed that the fractal dimensions and simulated micrographs of phase separation were in good agreement with the experimental results. And the mechanism of phase separation was spinodal decomposition.

关键词: glass , null , null , null , null , null , null

INTERACTION OF Ce AGAINST Cu,P OR Ti IN Fe-BASE SOLUTION

WANG Yuekui DU Ting Central Iron and Steel Research Institute , Ministry of Metallurgical Industry , Beijing , China

金属学报(英文版)

The equilibrium product in Fe-Cu-Ce,Fe-P-Ce or Fe-Ti-Ce solution have ben Mentified to be Ce_2O_2S,but not the intermetallic compounds of Ce against Cu,P or Ti.The equilibrium eonstant of Ce_2O_2S=2[Ce]+2[O]+[S] and the interaction coefficients between solutes in Fe-base solution have been determined as follows: K_(Ce_2O_2S)=2.57×10~(-5) e_(Ce)~(Cu)=-0.49;e_(Ce)~P=1.77;e_(Ce)~(Ti)=-3.62 e_(Cu)~(Ce)=-0.22;e_P~(Ce)=0.39;e_(Ti)~(Ce)=-1.23 ε_(Ce)~(Cu)=-128.0;ε_(Ce)~P=-224.1;ε_(Ce)~(Ti)=-710.0 Ce decreases the activities of Cu and Ti in Fe-base solution and increases their solubifities,as well as increases the activity of P and decreases its solubility.

关键词: Fe-base solution , null , null , null , null , null , null

PHYSICAL SIMULATION BASED INTELLIGENT SYSTEM FOR THE PREDICTION OF SHEET METAL DRAWING CAPABILITY

$ D.L* , D.N.He , X.J.Bao , Y. Q.Zhang , X. Y.Ruan , J.L. Cheng and J. Y. Jiang 1) National Die & Mold CAD Engineering Research Center , Shanghai Jiaotong University , Shanghai 200030 , China 2) Shanghai Volkswagen Automotive Company Limited , Shanghai 201805 , China

金属学报(英文版)

With the combination of a new theoretical formula, physical simulation experiments, the technology of artificial neural network and database, an intelligent system for the prediction of sheet metal drawing capability is constructed for the first time. A modified criterion for sheet metal drawing capability is proposed in this paper, namely, the Technological Limiting Drawing Ratio, TLDR = f(R, n, s, t, F, μ,r_d,r_p…). Based on the studies of other scholars, a new formula is derived to predict the TLDR in this paper. Then a series of orthogonal physical simulation experiments are designed to investigate the effect of technological parameters on the TLDR, and the results are analyzed in the paper. Then the predicting system is constructed with the combination of the theoretical formula, orthogonal experiments, the technology of artifocial neural network and database. The predicted results show good agreements with experimental data, so it can be used to avoid the blindness in the selection of sheet metal before stamping. The system operates under the Windows operating system, and it supports the mechanism of Client/Server as well as Intranet, so the system has high engineering value.

关键词: TLDR , null , null , null , null , null , null

Plasma Post Oxidation of Plasma Nitrocarburized SKD 61 Steel

Insup Lee , Kwang-Ho Jeong

材料科学技术(英)

Plasma nitrocarburizing and plasma oxidizing treatments were performed to improve the wear and corrosion resistance of SKD 61 steel. Plasma nitrocarburizing was conducted for 12 h at 540℃ in the nitrogen, hydrogen and methane atmosphere to produce the ε-Fe2–3 (N,C) phase. The compound layer produced by plasma nitrocarburising was predominantly composed of ε-phase, with a small proportion of γ′-Fe4(N,C) phase. The thickness of the compound layer and the diffusion layer are about 10 μm and about 200 μm, respectively. Plasma post oxidation was performed on the nitrocarburized samples with various oxygen/hydrogen ratio at constant temperature of 500℃ for 1 h. The very thin magnetite (Fe3O4) layer of 1–2 μm in thickness on top of the compound layer was obtained. Anodic polarization test revealed that plasma nitrocarburizing process contributed a significant improvement of corrosion resistance of SKD 61 steel. However, the corrosion characteristics of the nitrocarburized compound layer was deteriorated by oxidation treatment.

关键词: Plasma nitrocarburizing , null , null , null , null , null , null

CYCLIC DEFORMATION OF FACE CENTERED CUBIC CRYSTALS AND ITS DISLOCATION INTERACTION MODEL——Ⅰ.CYCLIC DEFORMATION OF COPPER CRYSTALS

JIN Nengyun Shanghai Jiaotong University , Shanghai Jin Nengyun , Department of Materials Science , Shanghai Jiaotong University , Shanghai 200030 , ChinaPresent address:Max-Planck-Institut für Metallforschung-Institut für Physik , Stuttgart 80 , FRG

金属学报(英文版)

Cyclic stress-strain responses and dislocation structure of copper single crystals with various tensile axes were systematically studied and compared with each other.Experimental results reveal that the evolution of microscopic dislocation configurations in a crystal and, accordingly,its macroscopic cyclic behaviours are closely related with its orientation.Re- markable secondary slip has been observed in some crystals with orientations well inside the crystallographic triangle, which are usually considered as single-slip ones.Their cyclio behaviours and dislocation structures at saturation are similar to those of their neighbouring multi-slip crystals.These results have constructed the experimental basis for the newly pro- posed dislocation interaction model Jor cyclic deformation of fee crystals,which will be des- cribed in the second part of this article.

关键词: Copper , null , null , null , null , null , null

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