工程热物理学报 , 2015, 36(6): 1307-1310.
本文以十二烷为相变材料,利用膨胀石墨多孔吸附特性制备出十二烷/膨胀石墨复合相变蓄冷材料.通过扫描电镜(SEM)、差示扫描量热仪(DSC)和热常数分析仪(HotDisk)对复合相变材料的结构及热性能进行了表征.实验结果表明,十二烷被膨胀石墨均匀吸附,吸附后膨胀石墨保持了原来的疏松多孔的蠕虫状形态.复合相变材料的相变焓值随着添加的膨胀石墨质量分数增加而降低,导热系数随着添加的膨胀石墨质量分数增加而增加.相变材料质量分数为80%,复合相变材料熔化焓和凝固焓分别为132.8 J/g和132.5 J/g,表观密度为700 kg/m3时,导热系数为2.64 W/(m.K).复合相变材料具有良好的热循环稳定性能.
引用:
陈嘉杰,
徐涛,
方晓明,
高学农,
张正国
膨胀石墨基十二烷复合相变蓄冷材料的性能研究.
工程热物理学报 ,
2015, 36(6): 1307-1310.
doi:
参考文献:
[1] K. Azzouz;D. Leducq;D. Gobin .Performance enhancement of a household refrigerator by addition of latent heat storage[J].International Journal of Refrigeration,2008(5):892-901.
[2] Effect of door opening and defrost cycle on a freezer with phase change panels[J].Energy conversion & management,2010(12):2698-2706.
[3] Belen Zalba;Jose M Marin;Luisa F. Cabeza;Harald Mehling .Review on thermal energy storage with phase change: materials, heat transfer analysis and applications[J].Applied thermal engineering: Design, processes, equipment, economics,2003(3):251-283.
[4] Cemil Alkan;Ahmet Sari .Fatty acid/poly(methyl methacrylate) (PMMA) blends as form-stable phase change materials for latent heat thermal energy storage[J].Solar Energy,2008(2):118-124.
[5] Su JF;Wang LX;Ren L .Fabrication and thermal properties of MicroPCMs: Used melamine-formaldehyde resin as shell material[J].Journal of Applied Polymer Science,2006(3):1522-1528.
[6] Xiaoming Fang;Zhengguo Zhang .A novel montmorillonite-based composite phase change material and its applications in thermal storage building materials[J].Energy and buildings,2006(4):377-380.
[7] Zhengguo Zhang;Guoquan Shi;Shuping Wang;Xiaoming Fang;Xiaohong Liu .Thermal energy storage cement mortar containing n-octadecane/expanded graphite composite phase change material[J].Renewable energy,2013(Feb.):670-675.