{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过1,3-偶极环加成反应合成出2-[(8-羟基喹啉)-2-基]-5-(2-噻吩基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>,利用UV-Vis、FT-IR、RAMAN、MALDI-TOF MS、1HNMR、13C NMR等手段对产物的结构进行了表征,并研究了产物的光学及电化学性能.结果表明,相对于C60来说,该产物的紫外吸收波长及荧光发射波长均发生红移,各对氧化还原峰的半峰电位发生明显的负移,更有利于应用于光电转化领域.","authors":[{"authorName":"李祥子","id":"5dbc85bc-b0c7-4412-965c-c0edbc719f10","originalAuthorName":"李祥子"},{"authorName":"魏先文","id":"3b57e8ab-f677-47c9-96b0-d0197d0bf9fe","originalAuthorName":"魏先文"}],"doi":"","fpage":"866","id":"0b305051-176f-4460-a896-a9dea7ed531a","issue":"6","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"90419a34-1f7a-482c-ada5-25713f9145c1","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>","originalKeyword":"富勒烯吡咯烷"},{"id":"15821a45-c51a-4855-b2cb-b7620bca7c2c","keyword":"8-羟基喹啉","originalKeyword":"8-羟基喹啉"},{"id":"7c0fbfc8-f257-49c4-9093-1685740262c9","keyword":"C60","originalKeyword":"C60"},{"id":"f4425572-ca19-45ad-be6f-1df8b0f8599d","keyword":"性能","originalKeyword":"性能"}],"language":"zh","publisherId":"gncl201306026","title":"2-[(8-羟基喹啉)-2-基]-5-(2-噻吩基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>的合成、光学及电化学性能","volume":"44","year":"2013"},{"abstractinfo":"利用亚胺叶立德的1,3-偶极环加成法合成了2种带活性基团的<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>中间体,即氨基乙基<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>和N取代3,4-<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>.经基质辅助激光解吸电离飞行时间质谱仪、傅里叶变红外光谱仪和紫外可见光分光光度计表征可知,它们是2种<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>中间体.这2种中间体含活性基团,可用于合成更多的<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生物,因此在<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>化学领域具有广阔的应用前景.","authors":[{"authorName":"康峰","id":"2473fca8-c547-4f05-9354-70d380c1b4b9","originalAuthorName":"康峰"},{"authorName":"张海峰","id":"fd251354-aee2-4423-87d1-5aa4210960da","originalAuthorName":"张海峰"},{"authorName":"卢胜明","id":"fedb85da-fc90-4b16-87bc-b76cc79e9e7c","originalAuthorName":"卢胜明"}],"doi":"","fpage":"1","id":"39e1bdc1-b148-4b5c-996c-1004b10f111f","issue":"22","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"5770746a-791d-4e2a-82ea-bd65e311855d","keyword":"氨基乙基<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>","originalKeyword":"氨基乙基富勒烯吡咯烷"},{"id":"3fc3a435-8385-4da4-afb5-14601a1c9781","keyword":"N取代3,4-<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>","originalKeyword":"N取代3,4-富勒烯吡咯烷"},{"id":"db3be50f-9b92-4d2b-a50c-0a352699babd","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"cldb201022001","title":"2种<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>中间体的合成","volume":"24","year":"2010"},{"abstractinfo":"为进一步认识羟基[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的空间结构,借助密度泛函考察了羟基取代位置和取代基数量对羟基[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物空间结构的影响.结果显示,5种羟基[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的LUMO均集中在[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>上,羟基出现在邻位时其衍生物的LUMO和HOMO能量差△E最小,而羟基在间位时其△E最大.<span style=\"color:red\">吡咯烷</span>键长和键角并不随羟基数量的增加而呈规律性的变化,但羟基取代基位置对<span style=\"color:red\">吡咯烷</span>键长和键角的影响由大到小的顺序是:对位、间位、邻位.","authors":[{"authorName":"蔡艳华","id":"92bba76f-3095-4948-b465-f45a2163c928","originalAuthorName":"蔡艳华"},{"authorName":"罗文","id":"3f2d6702-c50d-4f23-89f8-0ce5fd926fbd","originalAuthorName":"罗文"},{"authorName":"张艳华","id":"01272c37-699c-4bd2-81d3-389cb074a0b2","originalAuthorName":"张艳华"},{"authorName":"倪海涛","id":"d7f99f3d-b6bc-412e-8d82-4e1abc6a6599","originalAuthorName":"倪海涛"},{"authorName":"任莉平","id":"0e7a0487-c875-4010-b8ac-e7331235172d","originalAuthorName":"任莉平"}],"doi":"","fpage":"139","id":"38a9581c-82b0-43c9-909f-0c1aa8572784","issue":"4","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"765f943b-5564-4a78-9d01-3abd90881301","keyword":"[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>","originalKeyword":"[60]富勒烯"},{"id":"e9cafec2-3534-46d3-b5d1-3a613f051224","keyword":"取代基","originalKeyword":"取代基"},{"id":"64164fcb-2c94-4532-9828-6d2aa4085427","keyword":"羟基","originalKeyword":"羟基"},{"id":"27aa9f92-cfbb-46b3-baab-d3f13371bbea","keyword":"空间结构","originalKeyword":"空间结构"}],"language":"zh","publisherId":"cldb201304035","title":"取代基位置对羟基[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物空间结构的影响","volume":"27","year":"2013"},{"abstractinfo":"利用肌氨酸和对羟基苯甲醛所形成的亚胺叶立德与C60发生 1,3-偶极环加成反应,合成了一种新型含羟基C60<span style=\"color:red\">吡咯烷</span>衍生物:N-甲基-2-(4-羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>.通过UV-vis、1H-NMR、MS、FT-IR确定了产物的结构.探讨了反应条件对产物产率的影响,得到了最佳工艺条件:反应物摩尔比为1:2:6,温度为90℃,反应时间为5h,此时产物的产率可达到87%(以消耗的C60计).","authors":[{"authorName":"马冬梅","id":"695bd314-6075-4351-a663-0f20e70c6208","originalAuthorName":"马冬梅"},{"authorName":"彭汝芳","id":"2cf34945-9d47-4e1c-b704-d3159aae03cb","originalAuthorName":"彭汝芳"},{"authorName":"蔡艳华","id":"1ad81367-e828-413f-af76-34b150f33f08","originalAuthorName":"蔡艳华"},{"authorName":"金波","id":"9395ba23-d226-4aa1-83c9-352280bc24f8","originalAuthorName":"金波"},{"authorName":"楚士晋","id":"6156aa8f-7d6d-4244-ad25-04ba35a3051a","originalAuthorName":"楚士晋"}],"doi":"","fpage":"105","id":"9fe548ff-d582-45b9-a38b-4e9de3e7776c","issue":"1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"34049492-b842-4bb3-8729-450f861d8d9d","keyword":"肌氨酸","originalKeyword":"肌氨酸"},{"id":"1ef0f25d-a152-409f-9ca1-9a0dcefd85c2","keyword":"对羟基苯甲醛","originalKeyword":"对羟基苯甲醛"},{"id":"3be7e2f0-9358-4c15-a83b-789fc07b6cff","keyword":"C60","originalKeyword":"C60"},{"id":"0a0c528b-5d5d-4396-a76b-6f89a0e08e23","keyword":"合成工艺","originalKeyword":"合成工艺"}],"language":"zh","publisherId":"gncl200801031","title":"N-甲基-2-(4-羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的合成研究","volume":"39","year":"2008"},{"abstractinfo":"利用1,3-偶极环加成反应,合成分离得到了一种C60<span style=\"color:red\">吡咯烷</span>衍生物:N-基-2-(3-羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>,通过单因素方法,探讨了反应条件对产物产率的影响,并得到了最佳工艺条件:反应物摩尔比(C60:3-羟基苯甲醛:N-甲基甘氨酸)为1:2:4,反应温度90℃,反应时间2h,产物的产率可达82%(以消耗的C60计).同时用Uv-Vis、FT-IR、1H-NMR、MS等测试手段表征了产物的结构.","authors":[{"authorName":"马冬梅","id":"27d5789a-8f89-4ec9-aa3c-3ee50429fda1","originalAuthorName":"马冬梅"},{"authorName":"彭汝芳","id":"5371f5cb-433f-4835-8f0f-ad77d59154d6","originalAuthorName":"彭汝芳"},{"authorName":"蔡艳华","id":"dd038264-0dbd-4911-8a4b-f664705548f3","originalAuthorName":"蔡艳华"},{"authorName":"楚士晋","id":"496e94fe-dacc-4831-ba4d-7eedd59618e7","originalAuthorName":"楚士晋"}],"doi":"","fpage":"153","id":"c77acf8f-66af-4e5f-8d96-2c935484bdc4","issue":"10","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"baacca10-f12f-42f5-b2b6-722745b0f531","keyword":"C60","originalKeyword":"C60"},{"id":"1ec4adf0-f589-4af7-8b71-cc6ec9a853b1","keyword":"N-甲基甘氨酸","originalKeyword":"N-甲基甘氨酸"},{"id":"c48bccbd-18e4-4a14-9013-3b584fdcc8b3","keyword":"3-羟基苯甲醛","originalKeyword":"3-羟基苯甲醛"},{"id":"92edbf84-7500-46f1-bcfd-c84ef83f4f7f","keyword":"合成工艺","originalKeyword":"合成工艺"},{"id":"fab81b46-b56b-4a4a-96c7-b77f9aeddb56","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"cldb200810040","title":"N-甲基-2-(3-羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的合成研究","volume":"22","year":"2008"},{"abstractinfo":"在N2气保护下,由1,3-偶极环加成反应合成了含2个羟基的C60<span style=\"color:red\">吡咯烷</span>衍生物:N-甲基-2-(3,4-二羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>. 用UV-Vis、FT-IR、1H NMR、MS等测试技术表征了产物的结构,通过单因素方法,探讨了反应条件对产物产率的影响. 最佳反应条件为:n(C60)∶ n(N-甲基甘氨酸)∶ n(3,4-二羟基苯甲醛)=1∶ 2∶ 5,温度为95 ℃,反应时间为28 h,产率可达66%(以消耗的C60计).","authors":[{"authorName":"马冬梅","id":"c1af9010-7290-4f15-87bb-48a691666253","originalAuthorName":"马冬梅"},{"authorName":"彭汝芳","id":"bd6459b7-c44c-49de-a1b7-31a612b69207","originalAuthorName":"彭汝芳"},{"authorName":"蔡艳华","id":"d274ac51-5c81-4003-9bcc-c2daee6d425e","originalAuthorName":"蔡艳华"},{"authorName":"朱根华","id":"0620d5b4-21d0-4039-8f4d-18a10ffcaf75","originalAuthorName":"朱根华"},{"authorName":"王金刚","id":"ec5cde2e-7d46-459e-b4ad-e9bd62a8dcb9","originalAuthorName":"王金刚"},{"authorName":"俞海军","id":"05d28094-443a-43d9-b352-225d3bc645b3","originalAuthorName":"俞海军"},{"authorName":"楚士晋","id":"6395b933-fdf3-4d61-bbfc-2418affbce7d","originalAuthorName":"楚士晋"}],"doi":"10.3969/j.issn.1000-0518.2008.10.005","fpage":"1142","id":"21ec0f62-0370-4034-94f3-f9e606f4cc01","issue":"10","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"746ed934-057a-481d-b1b8-abe9f586fe61","keyword":"C60衍生物","originalKeyword":"C60衍生物"},{"id":"70c0ff1f-d545-49d7-826d-dbfdb320136c","keyword":"二羟基苯甲醛","originalKeyword":"二羟基苯甲醛"},{"id":"d57dfed6-6597-4cfc-a598-fdc241ef3f94","keyword":"合成","originalKeyword":"合成"},{"id":"0f7cb7d0-e327-419b-960b-b4df9346c46a","keyword":"表征","originalKeyword":"表征"}],"language":"zh","publisherId":"yyhx200810005","title":"N-甲基-2-(3,4-二羟基苯基)[60]<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的合成","volume":"25","year":"2008"},{"abstractinfo":"利用α-氨基、α-羧基均被保护的天冬氨酸或谷氨酸的非α-羧基与中间体N-取代的3,4-<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯烷</span>衍生物的活化羟基进行缩合反应,产物脱保护后得到了2种新的α-<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>氨基酸:<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>天冬氨酸和<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>谷氨酸.采用MALDI-TOF质谱、红外光谱、紫外可见光谱、1HNMR等方法对它们进行了结构表征.合成的新型<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>氨基酸含有游离的氨基、羧基,具有独特的化学结构和性质,在生物医学领域具有潜在的应用前景.","authors":[{"authorName":"张静","id":"9b3e92e5-96e2-465e-9a66-5d2cae35d0c8","originalAuthorName":"张静"},{"authorName":"王艳霞","id":"3204601a-1767-419e-840f-d0b23167607a","originalAuthorName":"王艳霞"},{"authorName":"康峰","id":"5d921626-00df-4597-837a-b6a48768f431","originalAuthorName":"康峰"},{"authorName":"邵颖雅","id":"5884589f-d5c2-4553-9674-055aaae427f1","originalAuthorName":"邵颖雅"},{"authorName":"李忠杰","id":"7ec69e34-9956-4c88-b575-17a4c263d3d9","originalAuthorName":"李忠杰"}],"doi":"","fpage":"112","id":"9d35085f-cc80-4c00-9dfc-1f350dfc8575","issue":"7","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"20f0f9a1-119a-4fa0-ba10-cd38450157f5","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>天冬氨酸","originalKeyword":"富勒烯天冬氨酸"},{"id":"4b952d5f-dfdd-4a0b-998c-c4d41278c516","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>谷氨酸","originalKeyword":"富勒烯谷氨酸"},{"id":"a7c7649c-93ba-4cd7-9765-b638e9a22058","keyword":"合成","originalKeyword":"合成"}],"language":"zh","publisherId":"cldb200807029","title":"新型<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>天冬氨酸与<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>谷氨酸的合成","volume":"22","year":"2008"},{"abstractinfo":"采用肌氨酸甲酯(CH3NHCH2COOMe)与C60光化学反应制得<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯</span>衍生物(C60Pyr),产率为67%(基于已反应的C60),并以其为配体,在N2气气氛下利用配体取代法合成了<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯</span>金属配合物(PyrC60)-Pd(dppe),产率为51%(基于C60<span style=\"color:red\">吡咯</span>衍生物).采用元素分析、质谱、紫外-可见吸收光谱、红外光谱、X射线光电子能谱和核磁共振(31P NMR)等测试技术对中间物及产物进行了表征,同时在光电化学电池中于GaAs电极上测量了化合物(PyrC60)-Pd(dppe)的光伏效应(PVE),研究了介质电对、配合物薄膜厚度对光电性能的影响.研究结果表明,(PyrC60)-Pd(dppe)/GaAs电极的值比单纯的GaAs电极的△V和△I相应值大得多,这种化合物具有优良的光电性能.尤其在O2/H2O介质电对中,光生电压值最大可达230 mV,光生电流最大可达8.7 μA.镀层厚度在0.5～1 μm时,光伏效应值较大.","authors":[{"authorName":"林永生","id":"d1b732c4-64f6-41a6-8c3d-b3885ea5a933","originalAuthorName":"林永生"},{"authorName":"陈昕","id":"3fefe859-146e-4317-b06a-b750ac2fdb2a","originalAuthorName":"陈昕"},{"authorName":"田玲","id":"d119cb88-821e-42b7-8ab3-e08196ca8980","originalAuthorName":"田玲"},{"authorName":"吴振奕","id":"8cee0c81-09b1-4ddd-87ef-7c558b9d7fe7","originalAuthorName":"吴振奕"},{"authorName":"杨森根","id":"552a7c95-c09f-419c-ad0d-e4106926b7de","originalAuthorName":"杨森根"},{"authorName":"凡素华","id":"c081614e-587e-4922-91ed-59ab7b8f89fe","originalAuthorName":"凡素华"},{"authorName":"詹梦熊","id":"e1a636a9-5063-46ab-acae-79a4b29e2981","originalAuthorName":"詹梦熊"}],"doi":"10.3969/j.issn.1000-0518.2007.02.009","fpage":"157","id":"46f7c142-1255-452f-8982-1f60614691d7","issue":"2","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"e2e25a55-bc0d-4bfd-b274-5187e9e8fdba","keyword":"<span style=\"color:red\">吡咯</span>","originalKeyword":"吡咯"},{"id":"7361b4fc-9263-4111-af64-ef82b6567b60","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>","originalKeyword":"富勒烯"},{"id":"988361f1-b556-491d-a01c-d4ffb4047a37","keyword":"光电转换","originalKeyword":"光电转换"}],"language":"zh","publisherId":"yyhx200702009","title":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span><span style=\"color:red\">吡咯</span>金属配合物的合成、表征及光电性能","volume":"24","year":"2007"},{"abstractinfo":"详细概述了燃烧法形成<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>的机理和碳氧比、燃烧炉内压力、稀释气体种类、火焰离燃烧喷嘴的距离、燃烧气体流速、火焰温度等对<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>产率的影响.","authors":[{"authorName":"王金刚","id":"f4d4f6ef-93c6-499c-9ae9-79ba19671ab8","originalAuthorName":"王金刚"},{"authorName":"彭汝芳","id":"df9f5ca8-d4e1-40f4-afc9-6935d83149e1","originalAuthorName":"彭汝芳"},{"authorName":"朱根华","id":"5137836b-898b-4270-a0dc-df3a12001d08","originalAuthorName":"朱根华"},{"authorName":"俞海军","id":"d2b9ea92-b7f5-49eb-ba5d-6ee2e1d5e175","originalAuthorName":"俞海军"},{"authorName":"楚士晋","id":"75e7431f-c220-4147-8060-d33a3fc4377a","originalAuthorName":"楚士晋"}],"doi":"10.3969/j.issn.1001-4381.2008.10.076","fpage":"299","id":"240b1596-bc2b-4e71-b42d-370271de2e40","issue":"10","journal":{"abbrevTitle":"CLGC","coverImgSrc":"journal/img/cover/CLGC.jpg","id":"9","issnPpub":"1001-4381","publisherId":"CLGC","title":"材料工程"},"keywords":[{"id":"c892b39b-9eef-48b6-a3bb-befa5d2478a8","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>","originalKeyword":"富勒烯"},{"id":"167cc15b-f23b-4696-92c3-a4daabd4b4af","keyword":"燃烧法","originalKeyword":"燃烧法"},{"id":"95397530-e832-4a4d-9594-5c75f1e88166","keyword":"机理","originalKeyword":"机理"}],"language":"zh","publisherId":"clgc200810076","title":"燃烧法制备<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>研究进展","volume":"","year":"2008"},{"abstractinfo":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生化合物在有机光电、生物医学等领域表现出良好应用前景,相关的<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生化方法研究引起了广泛关注,近年来发展迅速. <span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>由于具有较强的缺电子性质,容易与亲核试剂反应. 但相比于碳亲核试剂,含氧亲核试剂与<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>的反应发展缓慢,长期被忽略. 我们结合本课题组最近开展的工作,对OH-与MeO-含氧亲核试剂参与的<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生化反应的最新进展进行了总结,并对反应机理进行了较为详尽的阐述,为进一步扩展<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生化方法提供参考.","authors":[{"authorName":"赫法贵","id":"c37f62b3-16eb-47ce-a56b-fe5fbed955f7","originalAuthorName":"赫法贵"},{"authorName":"高翔","id":"a84aa782-5a6b-4346-9438-801792602bcf","originalAuthorName":"高翔"}],"doi":"10.11944/j.issn.1000-0518.2017.05.160477","fpage":"489","id":"bd090a1a-ec83-415e-88a3-dc9477f39b80","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"646fc213-e62e-43ad-b6cb-e14e8f6c7469","keyword":"<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>","originalKeyword":"富勒烯"},{"id":"9501cdb7-9d86-42a4-8a71-f71aec7694a5","keyword":"含氧亲核试剂","originalKeyword":"含氧亲核试剂"},{"id":"f2a05624-e977-4d8b-8cee-31b28395cfa1","keyword":"杂环化合物","originalKeyword":"杂环化合物"},{"id":"def6a5e6-88cc-4dbb-bd35-7c8913f16821","keyword":"反应机理","originalKeyword":"反应机理"},{"id":"fc25e5d1-bc10-4937-b266-c0a3a24fa597","keyword":"空间选择性","originalKeyword":"空间选择性"}],"language":"zh","publisherId":"yyhx201705001","title":"氢氧根和<span style=\"color:red\">烷</span>氧基负离子含氧亲核试剂在<span style=\"color:red\">富</span><span style=\"color:red\">勒</span><span style=\"color:red\">烯</span>衍生化中的应用","volume":"34","year":"2017"}],"totalpage":736,"totalrecord":7353}