{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过共混法制备了含辣素衍生结构聚合物的抑菌性聚醚砜超滤膜.首先,用<span style=\"color:red\">N-</span>(<span style=\"color:red\">5-</span><span style=\"color:red\">甲基</span>-<span style=\"color:red\">3-</span><span style=\"color:red\">异</span><span style=\"color:red\">丁基</span>-<span style=\"color:red\">2</span><span style=\"color:red\">羟基</span>-<span style=\"color:red\">苄基</span>)-<span style=\"color:red\">丙烯酰胺</span>(MBHBA)和<span style=\"color:red\">丙烯</span>酸(AA)、<span style=\"color:red\">甲基丙烯</span>酸甲酯(MMA)制备了三元共聚物P(A-M-M),并通过红外光谱证实了聚合物的合成；然后考察了铸膜液中三元共聚物的质量浓度对所制备超滤膜性能的影响.结果表明,当P(A-M-M)质量分数为1％时,改性膜具有较高的综合性能:纯水通量和BSA截留率分别为183.8 L/(m<span style=\"color:red\">2</span>·h)和93.8％,与基膜相比略有提高；同时亲水性大幅增加,水静态接触角仅为57°,比基膜降低了17°；抑菌率达到了76％,远高于基膜的抑菌率(20％).","authors":[{"authorName":"王剑","id":"24d3e146-a220-41a7-a729-424afceb5d3a","originalAuthorName":"王剑"},{"authorName":"高学理","id":"5fa99b13-6291-4fe5-8370-4798bac71553","originalAuthorName":"高学理"},{"authorName":"王汉敏","id":"c9614c7c-7fcd-4a90-a732-b5ba6a8f07e2","originalAuthorName":"王汉敏"},{"authorName":"黄星","id":"8fe6a8de-82ed-4fea-a356-ed8298b1d71f","originalAuthorName":"黄星"},{"authorName":"高从堦","id":"c14861a5-b0fa-4cbb-b83f-dda6e6c8d5eb","originalAuthorName":"高从堦"}],"doi":"","fpage":"12","id":"2a607e50-8d7e-4358-9dbc-e36364521341","issue":"3","journal":{"abbrevTitle":"MKXYJS","coverImgSrc":"journal/img/cover/MKXYJS.jpg","id":"54","issnPpub":"1007-8924","publisherId":"MKXYJS","title":"膜科学与技术   "},"keywords":[{"id":"61509aaa-7a31-43ea-9520-e002cf611bf0","keyword":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">5-</span><span style=\"color:red\">甲基</span>-<span style=\"color:red\">3-</span><span style=\"color:red\">异</span><span style=\"color:red\">丁基</span>-<span style=\"color:red\">2</span><span style=\"color:red\">羟基</span>-<span style=\"color:red\">苄基</span>)-<span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"N-(5-甲基-3-异丁基-2羟基-苄基)-丙烯酰胺"},{"id":"805a45e4-7751-4b89-838d-68a2c5385968","keyword":"聚醚砜","originalKeyword":"聚醚砜"},{"id":"5dc50ec0-cb40-455b-9d55-7bceaec0d14b","keyword":"共混","originalKeyword":"共混"},{"id":"c646c149-93e6-449f-852d-ebbbf17d7003","keyword":"抑菌性","originalKeyword":"抑菌性"}],"language":"zh","publisherId":"mkxyjs201303003","title":"抑菌性聚醚砜超滤膜的制备及性能表征","volume":"33","year":"2013"},{"abstractinfo":"以愈创木酚和<span style=\"color:red\">N-</span>羟<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>为原料通过弗瑞德-克来福特烷基化反应,合成了含辣素衍生结构的<span style=\"color:red\">丙烯酰胺</span>类功能单体<span style=\"color:red\">N-</span>(4-<span style=\"color:red\">羟基</span>-<span style=\"color:red\">3-</span>甲氧基-苯<span style=\"color:red\">甲基</span>)<span style=\"color:red\">丙烯酰胺</span>(HMBA),并通过红外光谱(FT-IR)和核磁波谱(1HNMR)对其结构进行了表征.初步研究了该化合物在海洋防污涂料中的防污性能.","authors":[{"authorName":"于良民","id":"b807b7cf-3fdd-4819-8903-44618212524c","originalAuthorName":"于良民"},{"authorName":"安正国","id":"4547a5f6-008e-4e80-a640-50f542d77005","originalAuthorName":"安正国"},{"authorName":"董磊","id":"eb796024-9a10-4a37-8e5f-269611ffd1e9","originalAuthorName":"董磊"}],"doi":"10.3969/j.issn.0253-4312.2007.07.020","fpage":"70","id":"5f0d8941-aa4f-4c76-a6f7-42506697212b","issue":"7","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"5b821957-c04e-4389-b952-e962c04955bf","keyword":"<span style=\"color:red\">N-</span>(4-<span style=\"color:red\">羟基</span>-<span style=\"color:red\">3-</span>甲氧基-苯<span style=\"color:red\">甲基</span>)<span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"N-(4-羟基-3-甲氧基-苯甲基)丙烯酰胺"},{"id":"bf91f462-6074-41ef-9841-31cee254c49e","keyword":"合成","originalKeyword":"合成"},{"id":"f976f129-adcd-4686-9a1f-c7f70f4b50b7","keyword":"防污涂料","originalKeyword":"防污涂料"}],"language":"zh","publisherId":"tlgy200707020","title":"<span style=\"color:red\">N-</span>(4-<span style=\"color:red\">羟基</span>-<span style=\"color:red\">3-</span>甲氧基-苯<span style=\"color:red\">甲基</span>)<span style=\"color:red\">丙烯酰胺</span>的合成及其防污性能研究","volume":"37","year":"2007"},{"abstractinfo":"以<span style=\"color:red\">3-</span>氯丙胺盐酸盐(Ⅰ)为原料,经<span style=\"color:red\">甲基丙烯</span>酸酐酰化得到<span style=\"color:red\">N-</span>(<span style=\"color:red\">3-</span>氯丙基)<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>(Ⅱ)后,通过Gabriel合成法得到<span style=\"color:red\">N-</span>[<span style=\"color:red\">N</span>'-(<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯</span>酰基)-<span style=\"color:red\">3-</span>氨基丙基]邻苯二甲酰亚胺(Ⅲ)和肼解产物<span style=\"color:red\">N-</span>(<span style=\"color:red\">3-</span>氨基丙基)<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>(Ⅳ),再经盐酸化得到<span style=\"color:red\">N-</span>(<span style=\"color:red\">3-</span>氨基丙基)<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>盐酸盐(Ⅴ),全程收率可达61.1％.该工艺中无需使用价格昂贵的氨基保护试剂,可极大降低原料成本.","authors":[{"authorName":"戴鹏","id":"9704585c-4206-4e3f-b4be-104ffd983864","originalAuthorName":"戴鹏"},{"authorName":"肖云杰","id":"524d4ec3-efaa-4c56-b950-305e228aa9aa","originalAuthorName":"肖云杰"},{"authorName":"王泽瑜","id":"b9035db5-0775-4d16-92ba-5ea56e9c3d9e","originalAuthorName":"王泽瑜"},{"authorName":"陈世坤","id":"f04bbff3-a727-40b6-b42a-385420c498f1","originalAuthorName":"陈世坤"},{"authorName":"何同胜","id":"15262124-a8f1-45ae-9a71-dacbf136c224","originalAuthorName":"何同胜"},{"authorName":"申永存","id":"1f087c8e-3963-4e58-b8f3-f7d0e850c444","originalAuthorName":"申永存"}],"doi":"10.3724/SP.J.1095.2013.30071","fpage":"1289","id":"79cbd374-8873-4fce-9a2d-c6cdedf422d2","issue":"11","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"367cb021-e56e-4da9-9064-d3acc708dda4","keyword":"氯丙胺盐酸盐","originalKeyword":"氯丙胺盐酸盐"},{"id":"3314a1d0-e776-41d5-bb58-26be91084249","keyword":"<span style=\"color:red\">N-</span>(氨基丙基)<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>盐酸盐","originalKeyword":"N-(氨基丙基)甲基丙烯酰胺盐酸盐"},{"id":"6c86b761-1bc0-404d-a6a3-c0e69934a167","keyword":"工艺改进","originalKeyword":"工艺改进"}],"language":"zh","publisherId":"yyhx201311009","title":"<span style=\"color:red\">N-</span>(<span style=\"color:red\">3-</span>氨基丙基)<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>盐酸盐的新合成路线","volume":"30","year":"2013"},{"abstractinfo":"由磺胺甲(噁)唑、对<span style=\"color:red\">羟基</span>苯乙酮和芳香醛反应直接合成了13个未见报道的β-氨基酮,反应选择性发生在羰基α位. 产物结构通过1H NMR、13C NMR、MS进行了表征. 生物活性试验显示,低浓度范围,所得化合物不仅对蛋白质酪氨酸磷酸酶1B(PTP1B)和α-葡萄糖苷酶有一定抑制活性,而且对过氧化物酶体增殖物激活受体反应元件(PPRE)具有中等强度的激动活性,8个化合物的激动活性超过40%,其中化合物11的活性达到72.7%.","authors":[{"authorName":"张映霞","id":"cb5560a8-380d-4000-ae2b-ee9139c424da","originalAuthorName":"张映霞"},{"authorName":"晏菊芳","id":"1bbe313e-463e-4552-b3b3-796900dd1096","originalAuthorName":"晏菊芳"},{"authorName":"范莉","id":"caf6bcf0-202f-4833-a844-7ab9920c5cec","originalAuthorName":"范莉"},{"authorName":"张蔚瑜","id":"9bae86a2-9d22-49e0-8aba-4157ca6d9ba9","originalAuthorName":"张蔚瑜"},{"authorName":"苏小燕","id":"107dbad2-1c5a-4ea2-b3c7-4432940df3d1","originalAuthorName":"苏小燕"},{"authorName":"陈欣","id":"c5e4f043-222f-47a0-9793-dd793c71cdba","originalAuthorName":"陈欣"},{"authorName":"唐雪梅","id":"fd1127c4-bd10-45c6-885d-cf969d4090b2","originalAuthorName":"唐雪梅"},{"authorName":"周祖文","id":"4857a675-966c-4a2e-a946-744673fbe821","originalAuthorName":"周祖文"},{"authorName":"杨大成","id":"31515f6d-1f48-414e-88ca-f68185f0cf0e","originalAuthorName":"杨大成"}],"doi":"10.3724/SP.J.1095.2010.90506","fpage":"1026","id":"94226dfd-1b5b-4b30-855a-ba8d72b4c9e3","issue":"9","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"bc51deee-5719-4432-974b-9c3513276127","keyword":"α-葡萄糖苷酶","originalKeyword":"α-葡萄糖苷酶"},{"id":"08eba2e1-6e3a-4653-9154-72409cd25f58","keyword":"蛋白质酪氨酸磷酸酶1B","originalKeyword":"蛋白质酪氨酸磷酸酶1B"},{"id":"9abd9038-7f9c-4c2d-b813-4eca361f83f6","keyword":"过氧化物酶体增殖物激活受体反应元件","originalKeyword":"过氧化物酶体增殖物激活受体反应元件"},{"id":"afc59af6-3648-49ce-b0a2-fa62f69b9d09","keyword":"对<span style=\"color:red\">羟基</span>苯乙酮","originalKeyword":"对羟基苯乙酮"},{"id":"2d389da7-a548-4a0c-93b0-b909b78e290a","keyword":"磺胺甲(噁)唑","originalKeyword":"磺胺甲(噁)唑"},{"id":"150213cf-adfa-4b7b-9538-39cc58bfe0be","keyword":"β-氨基酮","originalKeyword":"β-氨基酮"},{"id":"3900a608-2ea1-4018-afb3-1d82788bc627","keyword":"Mannich反应","originalKeyword":"Mannich反应"}],"language":"zh","publisherId":"yyhx201009008","title":"4-(<span style=\"color:red\">3-</span>(4-<span style=\"color:red\">羟基</span>苯基)-<span style=\"color:red\">3-</span>氧代-1-芳基丙氨基)-<span style=\"color:red\">N-</span>(<span style=\"color:red\">5-</span><span style=\"color:red\">甲基</span><span style=\"color:red\">异</span>唑-<span style=\"color:red\">3-</span>基)苯磺<span style=\"color:red\">酰胺</span>的合成及其抗糖尿病活性","volume":"27","year":"2010"},{"abstractinfo":"以<span style=\"color:red\">N-</span>羟<span style=\"color:red\">甲基</span><span style=\"color:red\">丙烯酰胺</span>和苯酚类化合物为原料,合成了<span style=\"color:red\">N-</span>(<span style=\"color:red\">2</span>-<span style=\"color:red\">羟基</span>-<span style=\"color:red\">3</span>..<span style=\"color:red\">丙烯酰胺</span><span style=\"color:red\">甲基</span>-4,6-二<span style=\"color:red\">甲基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(HMABA)、<span style=\"color:red\">N-</span>(<span style=\"color:red\">2</span>-<span style=\"color:red\">羟基</span>-<span style=\"color:red\">3-</span><span style=\"color:red\">丙烯酰胺</span><span style=\"color:red\">甲基</span>-4,<span style=\"color:red\">5-</span>二<span style=\"color:red\">甲基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(AMHBA)、<span style=\"color:red\">N-</span>(<span style=\"color:red\">3,5-</span>二<span style=\"color:red\">甲基</span>-4-<span style=\"color:red\">羟基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(MHBA)、<span style=\"color:red\">N-</span>(<span style=\"color:red\">3</span>,6-二<span style=\"color:red\">甲基</span>-4-<span style=\"color:red\">丙烯酰胺</span><span style=\"color:red\">甲基</span>-<span style=\"color:red\">2</span>-<span style=\"color:red\">羟基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(MAHBA)和<span style=\"color:red\">N-</span>(<span style=\"color:red\">2</span>-甲氧基-4-<span style=\"color:red\">甲基</span>-<span style=\"color:red\">5-</span><span style=\"color:red\">丙烯酰胺</span><span style=\"color:red\">甲基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(MMABA)<span style=\"color:red\">5</span>个类辣素结构的<span style=\"color:red\">丙烯酰胺</span>衍生物.通过红外光谱(IR)、核磁波谱(1H NMR)、质谱(HR-MS)和元素分析对化合物的结构进行了表征.抑菌试验表明,HMABA对金黄色葡萄球菌和大肠杆菌的抑制效果最好,最低抑菌浓度均可达0.125 g/L.将此<span style=\"color:red\">5</span>个化合物作为防污剂制备海洋防污涂料,120 d的实海结果表明,基本无污损海生物附着.","authors":[{"authorName":"于晓琳","id":"5bcc756e-7d23-4a58-845c-7f4f21c6fcaa","originalAuthorName":"于晓琳"},{"authorName":"于良民","id":"0a044baf-29f6-4595-8468-0f8a325c2d2b","originalAuthorName":"于良民"},{"authorName":"姜晓辉","id":"c4fecc74-eb70-4ead-8bec-3e253b016ee1","originalAuthorName":"姜晓辉"}],"doi":"10.3724/SP.J.1095.2014.30466","fpage":"594","id":"375b4cfc-f160-4dcb-ab05-751778c1a376","issue":"5","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"21bcc8b4-32fe-465c-96b8-a678bb79b99b","keyword":"含类辣素结构的<span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"含类辣素结构的丙烯酰胺"},{"id":"4e0fe5c3-66cd-41df-8914-8732f648009c","keyword":"合成","originalKeyword":"合成"},{"id":"25da787d-1418-471a-b75b-64fa93334e6f","keyword":"抑菌","originalKeyword":"抑菌"},{"id":"e08f4963-b4ff-4ff3-8b88-f433f6194e81","keyword":"防污性能","originalKeyword":"防污性能"}],"language":"zh","publisherId":"yyhx201405016","title":"具类辣素结构<span style=\"color:red\">丙烯酰胺</span>的合成及其抑菌和防污性能","volume":"31","year":"2014"},{"abstractinfo":"通过Friedel-Crafts反应合成了<span style=\"color:red\">N-</span>(<span style=\"color:red\">5-</span><span style=\"color:red\">甲基</span>-<span style=\"color:red\">3-</span>叔<span style=\"color:red\">丁基</span>-<span style=\"color:red\">2</span>-<span style=\"color:red\">羟基</span><span style=\"color:red\">苄基</span>)<span style=\"color:red\">丙烯酰胺</span>(MBHBA)和<span style=\"color:red\">N-</span>(<span style=\"color:red\">5-</span><span style=\"color:red\">甲基</span>-<span style=\"color:red\">3-</span>叔<span style=\"color:red\">丁基</span>-<span style=\"color:red\">2</span>-<span style=\"color:red\">羟基</span><span style=\"color:red\">苄基</span>)苯甲<span style=\"color:red\">酰胺</span>(MBHBB),并通过红外光谱(FT-IR)和核磁波谱(1HNMR)对其结构进行了表征.对比了MBHBA和MBHBB的抑菌性能和防污性能,结果显示<span style=\"color:red\">2</span>种化合物均有良好的抑制金黄色葡萄球菌和大肠杆菌的性能,且MBHBA的最小抑菌浓度可达0.125 mg/mL；以MBHBA和MBHBB为防污剂制备海洋防污涂料,60d的实海挂板仍无明显的污损生物附着.","authors":[{"authorName":"张智嘉","id":"1e636291-e622-4e67-b217-ab836f21ea53","originalAuthorName":"张智嘉"},{"authorName":"于良民","id":"09613382-565f-4c86-899e-2af7738ebfb0","originalAuthorName":"于良民"},{"authorName":"姜晓辉","id":"644a3440-c85a-4bf3-b294-faf3c8390c54","originalAuthorName":"姜晓辉"}],"doi":"","fpage":"20","id":"ecf5875e-7fd4-4ac6-b0f9-03dbbe50853e","issue":"12","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"f49c8b3b-b8cb-489b-99d0-3e746388e679","keyword":"<span style=\"color:red\">2</span>-叔<span style=\"color:red\">丁基</span>对<span style=\"color:red\">甲基</span>酚","originalKeyword":"2-叔丁基对甲基酚"},{"id":"d61a2e0f-c433-4a96-ac14-5bd8ffbb403b","keyword":"合成","originalKeyword":"合成"},{"id":"77dcc6f3-d9ef-4e19-b561-3067dc7187a8","keyword":"抑菌","originalKeyword":"抑菌"},{"id":"528ea7ca-311a-471c-9d4c-bb55755e9d98","keyword":"防污性能","originalKeyword":"防污性能"}],"language":"zh","publisherId":"tlgy201212005","title":"<span style=\"color:red\">2</span>-叔<span style=\"color:red\">丁基</span>对<span style=\"color:red\">甲基</span>酚<span style=\"color:red\">酰胺</span>衍生物的合成及其抑菌和防污性能的研究","volume":"42","year":"2012"},{"abstractinfo":"采用自由基溶液聚合,在水溶液中合成了具有温敏性的羧<span style=\"color:red\">甲基</span>壳聚糖接枝<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>共聚物,采用红外、 X射线衍射,对相关化合物进行了表征,并探讨了反应的机理. 通过对温度、反应时间、引发剂浓度、溶剂体积、<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>浓度的调节,获得最佳的反应条件:壳聚糖0.3 g,引发剂K<span style=\"color:red\">2S2</span>O810 mg,单体<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>1.5 g,溶剂(水)用量15 mg,70 ℃左右反应<span style=\"color:red\">2</span> h左右.","authors":[{"authorName":"郑静","id":"5f277ab4-dc62-4196-86c4-350dbf0edfc3","originalAuthorName":"郑静"},{"authorName":"王俊卿","id":"305036cf-6844-4ad9-8b30-771bfa319dd1","originalAuthorName":"王俊卿"},{"authorName":"苏致兴","id":"882333db-4358-4265-a683-1df1af49fd08","originalAuthorName":"苏致兴"}],"doi":"10.3969/j.issn.1000-0518.2003.12.019","fpage":"1204","id":"590298ea-c316-4ce3-a211-6a2c0eda9e21","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"248cd56d-9657-4bd9-9204-0803f16b8b8e","keyword":"壳聚糖","originalKeyword":"壳聚糖"},{"id":"980b9daa-3c1a-45f5-b88f-5f532a211a63","keyword":"<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"N-异丙基丙烯酰胺"},{"id":"eb1922a6-0465-44d3-be3f-1a5708b74878","keyword":"接枝共聚","originalKeyword":"接枝共聚"},{"id":"2b14134c-ee8e-470b-8623-8cde42553708","keyword":"温敏性","originalKeyword":"温敏性"}],"language":"zh","publisherId":"yyhx200312019","title":"壳聚糖与<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>接枝共聚","volume":"20","year":"2003"},{"abstractinfo":"分别合成了端羧基三硫代酯链转移剂(CTA)和<span style=\"color:red\">3-</span>叠氮丙醇,并以此为反应物通过1,<span style=\"color:red\">3-</span>二环己基碳二亚胺/4-(二<span style=\"color:red\">甲基</span>氨基)吡啶催化合成得到带有叠氮端基链转移剂.采用可逆加成-断裂链转移自由基聚合(RAFT)<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>(NIPAAm)得到叠氮端基聚(<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>)(PNIPAAm).核磁氢谱和红外分析表明,叠氮端基CTA反应转化完全,叠氮端基在聚合反应中稳定;聚合反应可控,GPC测定的分子量与理论分子量一致,聚合物分子量分布较窄((M-)w/(M-)<span style=\"color:red\">n</span>＜1.2).","authors":[{"authorName":"冯新亮","id":"6dcc98c3-752d-4404-952a-294a13b48575","originalAuthorName":"冯新亮"},{"authorName":"刘旭","id":"d6e91bab-ca37-4ee0-aebc-87fbb69653ca","originalAuthorName":"刘旭"},{"authorName":"曹亚","id":"6f7e13f6-5729-4cbe-a0f2-2aeabcfdac05","originalAuthorName":"曹亚"}],"doi":"","fpage":"24","id":"2717ef02-c7a9-4380-8818-4d611fc563fb","issue":"10","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"5215c622-f707-4e33-9682-f8a42c0e1f2b","keyword":"<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"N-异丙基丙烯酰胺"},{"id":"cdb5c6ae-8259-4ce1-a76f-6243e72f4226","keyword":"叠氮端基链转移剂","originalKeyword":"叠氮端基链转移剂"},{"id":"fc827601-581f-486b-9cf5-5c37bcfc7915","keyword":"可逆加成-断裂链转移自由基聚合","originalKeyword":"可逆加成-断裂链转移自由基聚合"}],"language":"zh","publisherId":"gfzclkxygc200910007","title":"叠氮端基聚<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>的合成与表征","volume":"25","year":"2009"},{"abstractinfo":"合成了一种新的腐蚀抑制及广谱抑菌剂:<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>(NIPAM)与<span style=\"color:red\">N-</span>烯丙基-1-苯甲酰基-<span style=\"color:red\">3-</span>苯基-4,5-<span style=\"color:red\">2</span>H-4-甲<span style=\"color:red\">酰胺</span>基吡唑(BPCP)的共聚物PNIPAM-Co-PBPCP.分别采用静态失重法和电化学阻抗谱研究了该共聚物在1 mol/L HCl溶液中对<span style=\"color:red\">N</span>80钢片化学腐蚀的抑制作用以及共聚物分子在<span style=\"color:red\">N</span>80钢片表面的吸附行为;采用液体稀释法测定了共聚物对各种菌类的最小抑菌浓度(MIC).结果表明,在质量浓度为0.5～7.0 g/L的范围内该共聚物对<span style=\"color:red\">N</span>80钢片的酸(1 mol/L HCl)腐蚀的抑制效果随缓蚀剂浓度增大而增强;最大缓蚀效率(90.3%)时的缓蚀剂质量浓度为6.0 g/L,仅为文献报道共聚物用量的1/<span style=\"color:red\">2</span>左右,为小分子缓蚀剂1-苯甲酰基-<span style=\"color:red\">3-</span>苯基-4,5-<span style=\"color:red\">2</span>H-4-羧基吡唑(NABPPAA)用量的1/10.在以上质量浓度范围内共聚物分子在<span style=\"color:red\">N</span>80钢片表面的吸附满足Langmuir等温吸附模式,其吸附热为30.4 kJ/mol.该共聚物具有较高的缓蚀效能热稳定性,在25～80 ℃的范围内缓蚀效率保持在80%以上且无明显变化.据此可以判断,共聚物分子在<span style=\"color:red\">N</span>80钢片表面上以化学吸附为主.结果还表明,共聚物分子具有广谱抑菌性,对大肠杆菌、金黄色葡萄球菌、蜡样芽胞杆菌、枯草芽孢杆菌活菌、铜绿假单胞菌、荧光假单胞菌以及沙门氏菌等多种菌类均具有良好的杀灭效果.","authors":[{"authorName":"曾涵","id":"9b4bb05d-1bf8-40fb-82bd-6837976d7028","originalAuthorName":"曾涵"},{"authorName":"赵淑贤","id":"e3a0bf7e-99ec-496b-ab7c-6861867ca021","originalAuthorName":"赵淑贤"},{"authorName":"李亚薇","id":"ed46e33a-7738-49ca-a86f-db7d82acf45b","originalAuthorName":"李亚薇"}],"doi":"10.3724/SP.J.1095.2010.90351","fpage":"478","id":"52f4a7cc-45c7-45b7-901b-80a74de2d381","issue":"4","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"235dd76b-7aed-4338-a4bc-cd74f4070694","keyword":"NIPAM-Co-BPCP","originalKeyword":"NIPAM-Co-BPCP"},{"id":"2c3496a8-4806-4f43-adbb-7d79e65fd51f","keyword":"缓蚀剂","originalKeyword":"缓蚀剂"},{"id":"ee8ba072-609d-4873-9b2e-21716099a5de","keyword":"吸附行为","originalKeyword":"吸附行为"},{"id":"7c02a617-e785-4864-b276-5be245e4d8a5","keyword":"抑菌效果","originalKeyword":"抑菌效果"}],"language":"zh","publisherId":"yyhx201004024","title":"<span style=\"color:red\">N-</span><span style=\"color:red\">异</span>丙基<span style=\"color:red\">丙烯酰胺</span>与<span style=\"color:red\">N-</span>烯丙基-1-苯甲酰基-<span style=\"color:red\">3-</span>苯基-4,5-<span style=\"color:red\">2</span>H-4-甲<span style=\"color:red\">酰胺</span>基吡唑共聚物对<span style=\"color:red\">N</span>80钢片的化学和细菌腐蚀的抑制作用","volume":"27","year":"2010"},{"abstractinfo":"将<span style=\"color:red\">丙烯</span>酰氯与二<span style=\"color:red\">丁基</span>胺反应合成了<span style=\"color:red\">N</span>,<span style=\"color:red\">N-</span>二<span style=\"color:red\">丁基</span><span style=\"color:red\">丙烯酰胺</span>(DBA),分别用红外光谱、碳谱分析了DBA的结构;DBA与<span style=\"color:red\">丙烯酰胺</span>(AM)经自由基微乳液聚合制备了水溶性疏水缔合共聚物P(AM-DBA),考察了共聚物中疏水单体含量、共聚物浓度、溶液温度对共聚物水溶液粘度的影响.结果表明,在试验范围内,P(AM-DBA)比聚<span style=\"color:red\">丙烯酰胺</span>具有更优异的耐温耐盐性能和明显的盐增稠现象.并解决了疏水缔合聚合物的水溶性与耐温耐盐性之间的矛盾.","authors":[{"authorName":"王云芳","id":"b30f0ad6-3dfc-4c13-a1ca-c0d1b9f3a447","originalAuthorName":"王云芳"},{"authorName":"孔瑛","id":"a1a42871-3432-4902-b9e7-a170a5557050","originalAuthorName":"孔瑛"},{"authorName":"辛伟","id":"aa1cbbc4-3bc8-487e-b4fa-defba6ca7c48","originalAuthorName":"辛伟"},{"authorName":"杨金荣","id":"ede786a0-fae5-41e4-bf65-9bfe913c5455","originalAuthorName":"杨金荣"},{"authorName":"史德清","id":"9b94d27f-ba39-4d11-a22e-e7b94656abb8","originalAuthorName":"史德清"}],"doi":"","fpage":"106","id":"ba3f1573-a170-4026-af25-cec0f9f83f18","issue":"6","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"2b4751df-38f1-4b58-a43d-6e9d65221b5c","keyword":"<span style=\"color:red\">N</span>,<span style=\"color:red\">N-</span>二<span style=\"color:red\">丁基</span><span style=\"color:red\">丙烯酰胺</span>","originalKeyword":"N,N-二丁基丙烯酰胺"},{"id":"c92d36cd-82e1-4343-a4ad-77905275d800","keyword":"合成","originalKeyword":"合成"},{"id":"99fe5279-3a5a-46f1-a9e2-455ef1ff0217","keyword":"微乳液","originalKeyword":"微乳液"},{"id":"978e32aa-58f0-4b66-8176-d04310a3291f","keyword":"疏水缔合聚合物","originalKeyword":"疏水缔合聚合物"},{"id":"38f8c81e-9a44-4843-9eac-7160ec961df3","keyword":"三次采油","originalKeyword":"三次采油"}],"language":"zh","publisherId":"gfzclkxygc200406026","title":"<span style=\"color:red\">N</span>,<span style=\"color:red\">N-</span>二<span style=\"color:red\">丁基</span><span style=\"color:red\">丙烯酰胺</span>及其共聚物的合成","volume":"20","year":"2004"}],"totalpage":12053,"totalrecord":120528}