机械工程材料, 2017, 41(1): 13-19.
10.11973/jxgccl201701003
TiO2含量对等离子喷涂Al2 O3-TiO2涂层物相组成和力学性能的影响

翁鹏翔 1, , 郭平 2, , 郑振环 3, , 叶辉 4, , 李强 5,

1.福州大学材料科学与工程学院,福州,350116;
2.福建省特种设备检验研究院,福州,350008;
3.福州大学材料科学与工程学院,福州,350116;
4.福建省特种设备检验研究院,福州,350008;
5.福州大学材料科学与工程学院,福州,350116

采用等离子喷涂工艺在灰铸铁基体上制备了4种TiO2含量不同的 Al2 O3-TiO2涂层,运用X射线衍射技术,并结合Rietveld全谱拟合方法,对不同涂层中的物相进行定量分析;采用显微硬度测试和拉伸试验研究 TiO2含量对涂层力学性能的影响。结果表明:Al2 O3-3%TiO2涂层中存在大量的γ-Al2 O3相、α-Al2 O3相以及少量的非晶相;在Al2 O3-13%TiO2涂层中,非晶相含量出现最大值,并有Al2 TiO5相形成;随着TiO2含量进一步增加,非晶相含量降低,Al2 TiO5相含量增加,在Al2 O3-40%TiO2涂层中只存在α-Al2 O3和Al2 TiO5相;随着TiO2含量增加,涂层的显微硬度降低,但涂层的结合强度升高,这与涂层中Al2 TiO5相的含量有关。
引用: 翁鹏翔, 郭平, 郑振环, 叶辉, 李强 TiO2含量对等离子喷涂Al2 O3-TiO2涂层物相组成和力学性能的影响. 机械工程材料, 2017, 41(1): 13-19. doi: 10.11973/jxgccl201701003
参考文献:
[1] 何康康;田宗军;王东生;沈理达;刘志东;黄因慧.等离子喷涂纳米Al2O3-13%TiO2陶瓷涂层的组织结构与抗冲蚀性能[J].机械工程材料,2009(8):77-80.
[2] Jianxin Zhang;Jining He;Yanchun Dong;Xiangzhi Li;Dianran Yan.Microstructure characteristics of Al{sub}2O{sub}3-13 wt.% TiO{sub}2 coating plasma spray deposited with nanocrystalline powders[J].Journal of Materials Processing Technology,20081-3(1-3):31-35.
[3] Senol Yilmaz.An evaluation of plasma-sprayed coatings based on Al_2O_3 and Al_2O_3-13 wt. percent TiO_2 with bond coat on pure titanium substrate[J].CERAMICS INTERNATIONAL,20095(5):2017-2022.
[4] R. Yilmaz;A.O. Kurt;A. Demir.Effects of TiO_2 on the mechanical properties of the Al_2O_3-TiO_2 plasma sprayed coating[J].Journal of the European Ceramic Society,20072/3(2/3):1319-1323.
[5] 贾胜凯;邹勇;徐计元;王静;余蕾.TiO2含量对等离子喷涂Al2O3热障涂层性能的影响[J].中国有色金属学报(英文版),2015(1):175-183.
[6] 张金星;程西云.等离子喷涂氧化铝陶瓷涂层研究现状及展望[J].热加工工艺,2013(12):18-21.
[7] 袁鸿斌;王泽华;张晶晶;周泽华;江少群;易于;陆洋.热处理对等离子喷涂Al2O3-13%TiO2涂层结合强度的影响[J].机械工程材料,2011(1):65-68,75.
[8] 田博;丁庆军;赵盖;章玉丹.等离子喷涂Al2O3-TiO2陶瓷涂层摩擦学性能研究[J].热加工工艺,2014(22):142-144,148.
[9] Habib KA;Saura JJ;Ferrer C;Damra MS;Gimenez E;Cabedo L.Comparison of flame sprayed Al2O3/TiO2 coatings: Their microstructure, mechanical properties and tribology behavior[J].Surface & Coatings Technology,20063/4(3/4):1436-1443.
[10] Vargas, F.;Ageorges, H.;Fournier, P.;Fauchais, P.;López, M.E..Mechanical and tribological performance of Al_2O_3-TiO_2 coatings elaborated by flame and plasma spraying[J].Surface & Coatings Technology,20104(4):1132-1136.
[11] N. Dejang;A. Watcharapasorn;S. Wirojupatump;P. Niranatlumpong;S. Jiansirisomboon.Fabrication and properties of plasma-sprayed Al2O3/TiO2 composite coatings: A role of nano-sized TiO2 addition[J].Surface & Coatings Technology,20109/10(9/10):1651-1657.
[12] 何继宁;阎殿然;董艳春;李香芝;刘艳改.等离子喷涂Al2O3与Al2O3/TiO2涂层中的相变及涂层的耐腐蚀行为[J].金属热处理,2005(8):46-48.
[13] O. Sarikaya.Effect of the substrate temperature on properties of plasma sprayed Al_2O_3 coatings[J].Materials & Design,20051(1):53-57.
[14] M. Uma Devi.On the nature of phases in Al_2O_3 and Al_2O_3-SiC thermal spray coatings[J].Ceramics International,20044(4):545-553.
[15] Vicent, M.;Bannier, E.;Benavente, R.;Salvador, M.D.;Molina, T.;Moreno, R.;Sánchez, E..Influence of the feedstock characteristics on the microstructure and properties of Al_2O_3-TiO_2 plasma-sprayed coatings[J].Surface & Coatings Technology,2013:74-79.
[16] K. Ramachandran;V. Selvarajan;P. V. Ananthapadmanabhan;K. P. Sreekumar.Microstructure, adhesion, microhardness, abrasive wear resistance and electrical resistivity of the plasma sprayed alumina and alumina-titania coatings[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,19981/2(1/2):144-152.

相似文献: