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Durability of traditional reactive powder concrete(RPC)with rich cement and high volume of fly-ash reactive powder concrete(FRPC)were studied.The X-diffraction and scanning electron microscope(SEM)measurement was imployed to analyze the microstructure.The results show that both types of RPC have higher compressive strength,less volume shrinkage ratio and better carbonation-,chloride-,freezing-resistances than the conventional concrete.The results of X-diffraction indicate that they basically have C-S-H as the main composition without Ca(OH)_2 crystal and ettringite.SEM results show that hydration products of FRPC is mainlyⅢ-C-S-H which is piled up closely like densely arranged stone body and it has very compacted structure,in addition,Ca/Si ratio of C-S-H gel is lower than 1.5.

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