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A new Nylon 11 (PA11)/polyethylene-octene (POE) blends compatibilized by maleic anhydride grafted mixture polyethyleneocten (POE-g-MAH) was prepared through melt blending method.The isothermal crystallization kinetics and melting behaviors of PA11/POE blends were investigated in detail by differential scanning calorimetry (DSC) and polarized optical microscope.The n values of PA11 blending with POE or POE-g-MAH are almost similar with pure PA11,which indicates that the effect of POE and POE-gMAH on nucleation and growth of PA11 crystal is slight.The overall crystallization rate of PA11/POE blends are higher than ones of pure PA11 at the same crystallization temperatures,but they decrease significantly when POE-g-MAH is added into PA11/POE blends.DSC heating curves of both PA11 and its blends exhibit two melting peaks,but the two melting peak become weaker when POE-g-MAH is add into PA11/POE blend systems.And the spherulite size is reduced significantly by the addition of POE-g-MAH compared with pure PA11 and PA11/POE blends.

参考文献

[1] Ya-lin Ma;Guo-sheng Hu;Xing-lin Ren;Biao-bing Wang .Non-isothermal crystallization kinetics and melting behaviors of nylon 11/tetrapod-shaped ZnO whisker (T-ZnOw) composites[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(0):611-618.
[2] Xikui Zhang;Tingxiu Xie;Guisheng Yang .Isothermal crystallization and melting behaviors of nylon 11/nylon 66 alloys by in situ polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(6):2116-2126.
[3] Mehrabzadeh M.;Burford RP. .IMPACT MODIFICATION OF POLYAMID 11[J].Journal of Applied Polymer Science,1996(13):2305-2314.
[4] Wang BB;Wei LX;Hu GS .Synergetic toughness and morphology of poly(propylene)/nylon 11/maleated ethylene-propylene diene copolymer blends[J].Journal of Applied Polymer Science,2008(3):1344-1350.
[5] G. Hu;B. Wang;X. Zhou .Effect of EPDM-MAH compatibilizer on the mechanical properties and morphology of nylon 11/PE blends[J].Materials Letters,2004(27/28):3457-3460.
[6] Mehrabzadeh M.;Burford RP. .EFFECT OF CROSSLINKING ON POLYAMIDE 11 BUTADIENE-ACRYLONITRILE COPOLYMER BLENDS[J].Journal of Applied Polymer Science,1997(8):1605-1611.
[7] Mehrabzadeh M.;Burford RP. .IMPACT MODIFICATION OF POLYAMID 11[J].Journal of Applied Polymer Science,1996(13):2305-2314.
[8] 赵军峰.超韧尼龙11合金的力学性能和相态研究[J].郑州经济管理干部学院学报,2006(01):93-96.
[9] 高彧,吕坤,李齐方.接枝率对尼龙11/POE/POE-g-MAH韧性的影响[J].现代塑料加工应用,2001(04):8-10.
[10] 李齐方,田明,冯威,陈松,金日光.尼龙11/MBS/环氧树脂共混合金的力学性能和增韧机理[J].高分子材料科学与工程,2001(04):57-61.
[11] 李齐方,金日光,冯威,陈松.增塑型超韧尼龙11的力学性能和增塑机理[J].材料研究学报,2000(03):265-270.
[12] 吴彤,罗运军,周贵忠,谭惠民,胡国胜.树形分子对尼龙11/尼龙6共混物的增韧增强[J].高分子材料科学与工程,2002(06):119-121,125.
[13] 李迎春,胡国胜,朱华,周应学.尼龙11/蒙脱土纳米复合材料的研究[J].工程塑料应用,2004(06):11-13.
[14] 王志强,李迎春,胡国胜,蒋士宝,邢志光.纳米二氧化硅改性尼龙11的研究[J].塑料工业,2005(z1):73-75.
[15] Wang, B.;Wang, W.;Wang, H.;Hu, G. .Isothermal crystallization kinetics and melting behavior of in situ compatibilized polyamide 6/Polyethylene-octene blends[J].Journal of Polymer Research,2010(3):429-437.
[16] 罗忠富,黄锐,蔡碧华.塑料冲击改性剂的研究进展[J].中国塑料,2000(04):17-20.
[17] WANG Shaohui,XU Weibing,ZHOU Zhengfa,REN Fengmei.Non-isothermal Melt Crystallization Kinetics of Anhydrite-Filled Polypropylene Composites[J].武汉理工大学学报(材料科学版)(英文版),2010(01):12-19.
[18] Tzong-Ming Wu;Chuh-Yi Liu .Poly(ethylene 2,6-naphthalate)/layered silicate nanocomposites:fabrication,crystallization behavior and properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(15):5621-5629.
[19] Wengui Weng;Guohua Chen;Dajun Wu .Crystallization kinetics and melting behaviors of nylon 6/foliated graphite nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(26):8119-8132.
[20] Minying Liu;Qingxiang Zhao;Yudong Wang;Chenggui Zhang;Zhishen Mo;Shaokui Cao .Melting behaviors, isothermal and non-isothermal crystallization kinetics of nylon 1212[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(8):2537-2545.
[21] Biaobing Wang;Zuowan Zhou;Lixia Gu .Influence of tetrapod-shaped zinc oxide whisker on poly(vinylidene fluoride) based gel polymer electrolyte[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2003(8):1449-1455.
[22] V.Everaert;G.Groeninckx;M.H.J.Koch .Influence of fractionated crystallization on the semicrystalline structure of (POM/(PS/PPE)) blends. Static and time-resolved SAXS, WAXD and DSC studies[J].Polymer: The International Journal for the Science and Technology of Polymers,2003(12):3491-3508.
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