NiFe2O4 nanorods have been successfully synthesized via thermal treatment of the rod-like precursor fabricated by Ni-doped α-FeOOH,which was enwrapped by the complex of citric acid and Ni2+. The morphology evolution during the calcination of the precursor nanorods was investigated with transmission electron microscopy (TEM), and the phase and the magnetic properties of samples were analyzed through X-ray diffraction (XRD) and vibrating sample magnetometer (VSM). The results indicated that the diameter of the NiFe2O4 nanorods obtained ranged between 30 and 50 nm, and the length ranged between 2 and 3 μm. As the calcination temperature was up to 600℃, the coertively. The NiFe2O4 nanorods prepared have higher shape anisotropy and superior magnetic properties than those with irregular shapes.
参考文献
[1] | Ziolo R.F;Giaunelis E.P;Weinstein B.A;O'Horo M.P.,Gangnli .Matrix-mediated synthesis of nanocrystalline γ-ferric oxide:A new optically transparent magnetic material[J].Science,1992,257(5067):219. |
[2] | Wirtz D;Fermigier M .One-dimensional patterns and forced periodicity in magnetic fluids[J].Physical Review Letters,1994,72(14):2294. |
[3] | Ombretta Masala;Darin Hoffman;Nalini Sundaram .Preparation of magnetic spinel ferrite core/shell nanoparticles: Soft ferrites on hard ferrites and vice versa[J].Solid state sciences,2006(9):1015-1022. |
[4] | Cvejic Z;Rakic S;Kremenovic A;Antic B;Jovalekic C;Colomban P .Nanosize ferrites obtained by ball milling: Crystal structure, cation distribution, size-strain analysis and Raman investigations[J].Solid state sciences,2006(8):908-915. |
[5] | Speliotis D.E .Magnetic recording beyond the fast 100 years[J].Journal of Magnetism and Magnetic Materials,1999,193(1-3):29. |
[6] | Raj K.;Casciari R.;Moskowitz B. .ADVANCES IN FERROFLUID TECHNOLOGY[J].Journal of Magnetism and Magnetic Materials,1995(1/2):174-180. |
[7] | Wang J;Zhua Y.J;Lia W.P;Chen Q.W .Necklace-shaped assembly of single-crystal NiFe2O4 nanospheres under magnetic field[J].Materials Letters,2005,59(16):2101. |
[8] | Cheng Y;Zheng YH;Wang YS;Bao F;Qin Y .Synthesis and magnetic properties of nickel ferrite nano-octahedra[J].International Journal of Quantum Chemistry,2005(7):2394-2397. |
[9] | Kinemuchi Y.;Ishizaka K.;Suematsu H.;Jiang WH.;Yatsui K. .Magnetic properties of nanosize NiFe2O4 particles synthesized by pulsed wire discharge[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(1/2):109-113. |
[10] | Huang Y;Duan X.F;Wei Q.Q;Lieber C.M .Directed assembly of one-dimensional nanostructures into functional networks[J].Science,2001,291(5504):630. |
[11] | Gudiksen M.S;Lauhon L.J;Wang J;Smith D.C.,and Lieber C.M .Growth of nanowire superlattice structures for nanoscale photonics and electronics[J].Nature,2002,415:617. |
[12] | Mieszawska A.J;Jalilian R;Sumanasekera G.U;Zamborini F.P .The synthesis and fabrication of one-dimensional nanoscale heterojunctious[J].Small,2007,3(05):722. |
[13] | Chatterjee A;Das D;Pradhan S.K;Chakravorty D .Synthesis of nanocrystalline nickel-zinc ferrite by the sol-gel method[J].Journal of Magnetism and Magnetic Materials,1993,127(1-2):214. |
[14] | S.G. Doh;E.B. Kim;B.H. Lee .Characteristics and synthesis of Cu-Ni ferrite nanopowders by coprecipitation method with ultrasound irradiation[J].Journal of Magnetism and Magnetic Materials,2004(3):2238-2240. |
[15] | Baruwati B;Rana RK;Manorama SV .Further insights in the conductivity behavior of nanocrystalline NiFe2O4[J].Journal of Applied Physics,2007(1):14302-1-14302-7-0. |
[16] | Balaji S;Selvan RK;Berchmans LJ;Angappan S;Subramanian K;Augustin CO .Combustion synthesis and characterization of Sn4+ substituted nanocrystalline NiFe2O4[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2005(2):119-124. |
[17] | Huaming Yang;Xiangchao Zhang;Weiqin Ao;Guanzhou Qiu .Formation of NiFe_2O_4 nanoparticles by mechanochemical reaction[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2004(6):833-837. |
[18] | Li, XD;Yang, WS;Li, F;Evans, DG;Duan, X .Stoichiometric synthesis of pure NiFe2O4 spinel from layered double hydroxide precursors for use as the anode material in lithium-ion batteries rtyree[J].The journal of physics and chemistry of solids,2006(5/6):1286-1290. |
[19] | Jiang J;Yang Y.M;Li L.C .Surfactant-assisted synthesis of nanostructured NiFe2O4 via a refluxing route[J].Materials Letters,2008,62(12-13):1973. |
[20] | Misra RDK;Gubbala S;Kale A;Egelhoff WF .A comparison of the magnetic characteristics of nanocrystalline nickel, zinc, and manganese ferrites synthesized by reverse micelle technique[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2004(2/3):164-174. |
[21] | Krehula S;Musi(c)S;Skoko Z;Popovi(c)S .The influence of Zn-dopant on the precipitation of α-FeOOH in highly alkaline media[J].Journal of Alloys and Compounds,2006,420(1-2):260. |
[22] | Katsuya Inoue;Masato Okui;Masahiko Tanaka;Kozo Shinoda;Shigeru Suzuki;Yoshio Waseda .Influence of manganese on iron oxyhydroxides and oxides formed in aqueous solution[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2008(3):811-817. |
[23] | Che A.X;Li C.Z .Study on the preparation of homogeneous spindle-type a-FeOOH[J].Chemistry World,1997,4:404. |
[24] | Kodama R.H;Berkowitz A.E;McNiff E.J .and Foner S.Surface spin disorder in NiFe2O4 nanoparticles[J].Physical Review Letters,1996,77(02):394. |
[25] | Rezlescu L;Rezlescu E;Popa P.D;Rezlescu N .Fine barium hexaferrite powder prepared by the crystallisation of glass[J].Journal of Magnetism and Magnetic Materials,1999,193(1-3):288. |
[26] | Dan Li;Thurston Herricks;Younan Xia .Magnetic nanofibers of nickel ferrite prepared by electrospinning[J].Applied physics letters,2003(22):4586-4588. |
[27] | Carpenter E.E;O'Connor C.J;Harris V.G .Atomic structure and magnetic properties of MnFe2O4 nanoparticles produced by reverse micelle synthesis[J].Journal of Applied Physics,1999,85(08):5175. |
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