欢迎登录材料期刊网

材料期刊网

高级检索

The element diffusion process of Nb3Sn superconductors by bronze route was studied using X-ray diffraction,scanning electron microscopy and energy dispersive spectroscopy.The critical current of superconductors was measured by four-point method.The results show that a diffusion layer has formed around the boundaries between the filaments and bronze matrix after 15 h heat treatment.The diffusion layer thickness keeps stable after heat treatment duration of 50~75 h.The stable and solid Nb3Sn layer is obtained in the sample after 100 h heat treatment.Excessive heat treatment would induce superconductivity degeneration because of superconductor grain coarsening.The characteristics of the element diffusion process were discussed.The diffusion of tin atom is the governing factor in diffusion.In this study,Nb3Sn superconductors with good superconducting property were fabricated successfully at 670 ℃ after 100 h heat treatment.

参考文献

[1] Liu Z.Y;Ma L;Zhao J.J;Yan B.J.and Suo H.L .Fabrication and characterization of SmO0.7F0.2FeAs bulk with a transition temperature of 56.5 K[J].Rare Metals,2011,30(05):496.
[2] Durante M.;Devred A.;Otmani R.;Reytier M.;Schild T. Trillaud F.;Bredy P. .Development of a Nb3Sn multifilamentary wire for accelerator magnet applications[J].Physica, C. Superconductivity and its applications,2001(1/4):449-453.
[3] den Ouden A.;Wessel S.;Krooshoop E.;ten Kate H. .Application of Nb<SUB>3</SUB>Sn superconductors in high-fieldaccelerator magnets[J].IEEE Transactions on Applied Superconductivity: A Publication of the IEEE Superconductivity Committee,1997(2):733-738.
[4] Smith B.A.;Schultz J.H.;Zhukovsky A.;Radovinsky A.;Gung C.;Michael P.C.;Minervini J.V.;Kesner J.;Garnier D.;Mauel M.;Naumovich G.;Kocher R. .Design, fabrication and test of the react and wind, Nb3Sn, LDXfloating coil[J].IEEE Transactions on Applied Superconductivity: A Publication of the IEEE Superconductivity Committee,2001(1):2010-2013.
[5] Markiewicz W.D.;Goddard R.E. .Bronze tin content and grain size in Nb<SUB>3</SUB>Sn composite superconductors[J].IEEE Transactions on Applied Superconductivity: A Publication of the IEEE Superconductivity Committee,2002(1):1063-1066.
[6] Hopkins S.C;Tan K.S;Glowacki B.A .Computerised optimisation of bronze route Nb3Sn conductors[J].Journal of Physics:Condensed Matter,2006,43:35.
[7] Taillard R.;Verwaerde C.;Bruzek C.E.;Sulten P. .Heat treatments, microstructure and properties of internal-tin Nb<SUB>3</SUB>Sn[J].IEEE Transactions on Applied Superconductivity: A Publication of the IEEE Superconductivity Committee,1997(2):1504-1507.
[8] Muller H.;Schneider T. .Optimization of the heat treatment of Nb3Sn-superconductors[J].Physica, C. Superconductivity and its applications,2004(1/4):325-329.
[9] Watanabe K.;Noto K. .Upper critical fields and critical current densities in bronze processed commercial multifilamentary Nb/sub 3/Sn wires[J].IEEE Transactions on Magnetics,1991(2):1759-1762.
[10] 程军胜,王秋良,王晖.热分析技术在Nb3Sn超导材料扩散热处理中的应用[J].金属热处理,2010(06):80-84.
[11] Ekin J.W.Experimental Techniques for Low-Temperature Measurements[M].Oxford:Oxford University Press,2006:351.
[12] Tachikawa K;Natsuume M;Kuroda Y;Tomori H .Nb3Sn superconductors prepared from intermediate compound phase[J].Cryogenics,1996,36(02):113.
[13] Gale W.F;Totemeier T.C.Smithells Metals Reference Book[M].Elsevier Butterworth-Heinemann,The Netherlands,2004:4.
[14] Godeke A.Performance Boundaries in Nb3Sn Conductors[M].University of Twente,Enschede.The Netherlands,2005:87.
[15] Kazuya Takahata;Hitoshi Tamura;Toshiyuki Mito .Critical current of react-and-jacket processed Nb_3Sn conductor[J].Cryogenics,2011(7):397-399.
[16] A.K. KUMAR;A. PAUL .Interdiffusion and Growth of the Superconductor Nb_(3)Sn in Nb/Cu(Sn) Diffusion Couples[J].Journal of Electronic Materials,2009(5):700-705.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%