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SiO2 coated Ce2S3 red pigment was prepared in ethanol/H2O system via sol-gel method and TEOS were used as silica sources. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX), UV-visible spectro-photometer and automatic colorimeter were used to investigate the properties of the samples. The results showed that the compact SiO2 film formed on the surface of Ce2S3 pigment at a cerium silicon molar ratio of 2. The thermal stability temperature of Ce2S3 pigment was improved to 450 oC after SiO2 coating. In addition, the color of Ce2S3 pigment was not affected significantly through coating colorless and transparent SiO2 and it could be used as safe red pigment in higher temperature fields.

参考文献

[1] Maestro Patrick .Use of coloured pigments based on rare earths sulphurs in plastics, paints, or vanishes[P].European Patent,EP 0203838(A2),1956.
[2] Maestro P;Huguenin H .Industrial applications of rare earths:which way for the end of the century[J].Journal of Alloys and Compounds,1995,225:520.
[3] Vasilyeva IG.;Vlasov AA.;Malakhov VV.;Macaudiere P. Maestro P.;Ayupov BM. .Color and chemical heterogeneities of gamma-[Na]-Ce2S3 solid solutions[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):72-77.
[4] Prokofiev A V;Shelykh A I;Golubkov A V;Smirnov I A .Crystal growth and optical properties of rare earth ses-quiselenides and sesquisulphides-new magneto-optic ma-terials[J].Journal of Alloys and Compounds,1995,219:172.
[5] Perrin M A;Wimmer E .Color of pure and alkali-doped Ce2S3:A local-density-functional study[J].Physical Review B,1996,54(04):2425.
[6] Zhukov V;Mauricot R;Gressier P;Evain M .Band elec-tronic structure study of some doped and undopedγ-Ln2S3(Ln=La, Ce, Pr and Nd) rare earth sulfides through LMTO-TB calculations[J].Journal of Solid State Chemistry,1997,128:197.
[7] YUAN Haibin,ZHANG Jianhui,YU Ruijin,SU Qiang.Synthesis of rare earth sulfides and their UV-vis absorption spectra[J].稀土学报(英文版),2009(02):308-311.
[8] Stephane R;Christian T J .Method for preparing a rare earth sulphide comprising an alkaline element, resulting composition and application as colouring pigment[P].Austra-lian Patent,AU754720B2,2000.
[9] Mauricot R;Gressier P;Evain M;Brec R .Comparative study of some rare earth sulfides:dopedγ-[A]M2S3(M=La, Ce and Nd, A= Na, K and Ca) and undoped γ-M2S3(M=La, Ce and Nd)[J].Journal of Alloys and Compounds,1995,223:130.
[10] Wu L M;Seo Dong Kyun .New solid-gas metathetical synthesis of binary metal polysulfides and sulfides at in-termediate temperatures:utilization of boron sulfides[J].Journal of the American Chemical Society,2004,126:4676.
[11] Marrot F;Mosset A;Trombe J-C;Macaudiere P, Maestro P .The stabilization of γ-Ce2S3 at low temperature by heavy rare earths[J].Journal of Alloys and Compounds,1997,259:145.
[12] Shannon R D .Revised effective ionic radii and systematic studies of interatomic distances in halides and chalco-genides[J].Acta Crystallogr Sect A,1976,32:751.
[13] Romero S.;Trombe JC.;Mosset A. .Study of some ternary and quaternary systems based on gamma-Ce2S3 using oxalate complexes: stabilization and coloration[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):98-106.
[14] XU Dong,WU Jieting,JIAO Lei,XU Hongxing,ZHANG Peimei,YU Renhong,CHENG Xiaonong.Highly nonlinear property and threshold voltage of Sc2O3 doped ZnO-Bi2O3-based varistor ceramics[J].稀土学报(英文版),2013(02):158-163.
[15] Choon-Woo Nahm.Nonlinear behavior of Tb4O7-modified ZnO-Pr6O11-based ceramics with high breakdown field[J].稀土学报(英文版),2013(03):276-280.
[16] Thierry ChoPin;Dominique DuPuis .Rare earth metal sul-fide pigment compositions[P].United States Patent,US5401309A,1995.
[17] Stober W;Fink A;Bohn E .Controlled growth of mono-disperse silica spheres in the micron size Ragne[J].Journal of Colloid and Interface Science,1968,26:62.
[18] Zhao R Y;Dong P;Liang W J .Study of the hydrolysis ki-netics of tetraethylorthosilicate in the preparation of monodisperse silica system[J].Acta Physico-Chimica Sinica,1995,117:612.
[19] Wang X G;Zhao H;Zhang Q;Wu H Y .Research progress of hydrolysis of ethyl silicate[J].Inner Mongolin Petro-chemical Industry (in Chin ),2001,27:17.
[20] Wang H;Huang S L;Zuo Y J;Zhou T, Zhang L R .Corro-sion resistance of lamellar aluminium pigments coated by SiO2 by sol-gel method[J].Corrosion Science,2011,53:161.
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