欢迎登录材料期刊网

材料期刊网

高级检索

Through a hydrothermal route, the Er3+and Tm3+co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3+ions centered at 474 nm (1G4→3H6), 679 nm (3F2→3H6), 699 nm (3F3→3H6), 803 nm (3H4→3H6) and emissions of Er3+ions centered at 522 nm (2H11/2→4I15/2), 543 nm (4S3/2→4I15/2), 654 nm (4F9/2→4I15/2) were observed. The upconversion emissions of Er3+ions were adjusted by the concentration of Tm3+ions. The energy transfer mechanisms among Er3+-Yb3+-Tm3+in SrYbF5 nanosheets were discussed.

参考文献

[1] Ouyang X.;Siegele R.;Kitai AH. .RARE-EARTH-DOPED TRANSPARENT YTTRIUM SILICATE THIN FILM PHOSPHORS FOR COLOUR DISPLAYS[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1995(1/2):268-272.
[2] CHEN Qijing,QIN Lianjie,FENG Zhiqiang,GE Ru,ZHAO Xiangjin,XU Huizhong.Upconversion luminescence of KGd(MoO4)2∶Er3+,yb3+ powder prepared by Pechini method[J].稀土学报(英文版),2011(09):843-848.
[3] Heer S;K?mpe K;Güdel H U;Haase M .Highly efficient multicolour upconversion emission in transparent colloids of lanthanide-doped NaYF4 nanocrystals[J].Advanced Materials,2004,16(23):2102.
[4] Holm B A;Bergey E J;De T;Rodman D J,Kapoor R,Levy L,Friend C S,Prasad P N .Nanotechnology in bio-Medical applications[J].Molecular Crystals and Liquid Crystals,2002,374(01):589.
[5] Ham BS;Shahriar MS;Kim MK;Hemmer PR;Univ S Florida Dept Phys Tampa FL 33620 USA.;Rome Lab Hanscom AFB MA 01731 USA. .Frequency-selective time-domain optical data storage by electromagnetically induced transparency in a rare-earth-doped solid[J].Optics Letters,1997(24):1849-1851.
[6] Teng, X.;Zhu, Y.;Wei, W.;Wang, S.;Huang, J.;Naccache, R.;Hu, W.;Tok, A.I.Y.;Han, Y.;Zhang, Q.;Fan, Q.;Huang, W.;Capobianco, J.A.;Huang, L. .Lanthanide-doped Na _xScF _(3+ x) nanocrystals: Crystal structure evolution and multicolor tuning[J].Journal of the American Chemical Society,2012(20):8340-8343.
[7] Sri Sivakumar;Frank C. J. M van Veggel;Mati Raudsepp .Bright White Light through Up-Conversion of a Single NiR Source from Sol-Gel-Derived Thin Film Made with Ln~(3+)-Doped LAF_3 Nanoparticles[J].Journal of the American Chemical Society,2005(36):12464-12465.
[8] Frangois Auzel .Upconversion and Anti-Stokes Processes with f and d Ions in Solids[J].Chemical Reviews,2004(1):139-173.
[9] Poizot P;Laruelle S;Grugeon S;Dupont L Tarascon J M .Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries[J].Nature,2000,407(6803):496.
[10] Konrad A;Fries T;Gahn A;Kummer F,Herr U,Tidecks R,Samwer K .Chemical vapor synthesis and luminescence properties of nanocrystalline cubic Y2O3[J].Eu J Appl Phys,1999,86(06):3129.
[11] Xiangfu Wang;Xiaohong Yan;Tao Wang .Shape-controlled tunable homochromatic luminescence and inner photoelectric effect of hexagonal Na_(1.23)Ca_(0.12)Y_(1.28)Er_(0.24)F6 phosphors[J].Physical chemistry chemical physics: PCCP,2012(19):7137-7144.
[12] T. Igarashi;M. Ihara;T. Kusunoki .Relationship between optical properties and crystallinity of nanometer Y_(2)O_(3):Eu phosphor[J].Applied physics letters,2000(12):1549-1551.
[13] Wakefield G.;Dobson PJ.;Hutchison JL.;Holland E. .Luminescence properties of nanocrystalline Y2O3 : Eu[J].Advanced Materials,2001(20):1557-0.
[14] Bhargava R;Gallagher D;Hong X .Optical properties of manganese-dopednanocrystals of ZnS[J].Physical Review Letters,1994,72(03):416.
[15] Jan W. Stouwdam;Frank C. J. M. van Veggel .Near-infrared Emission of Redispersible Er~(3+), Nd~(3+), and Ho~(3+) Doped LaF_3 Nanoparticles[J].Nano letters,2002(7):733-737.
[16] Yan RX;Li YD .Down/Up conversion in Ln(3+)-doped YF3 nanocrystals[J].Advanced functional materials,2005(5):763-770.
[17] Gong, L.;Yang, J.;Li, Y.;Ma, M.;Xu, C.;Ren, G.;Lin, J.;Yang, Q. .Solvothermal synthesis and upconversion emission of monodisperse ultrasmall SrYbF_5 nanocrystals[J].Journal of Materials Science,2013(10):3672-3678.
[18] Bednarkiewicz A.;Strek W. .Laser-induced hot emission in Nd3+/Yb3+: YAG nanocrystallite ceramics[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2002(20):2503-2507.
[19] Pollnau M;Gamelin D R;Lüthi S R;Güdel H U,Hehlen M P .Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J].Physical Review B,2000,61(05):3337.
[20] Shen SX;Jha A;Huang LH;Joshi P .980-nm diode-pumped Tm3+/Yb3+-codoped tellurite fiber for S-band amplification[J].Optics Letters,2005(12):1437-1439.
[21] Xu, Y.;Chen, D.;Zhang, Q.;Wang, W.;Zeng, H.;Shen, C.;Chen, G. .Two-photon excited red upconversion luminescence of thulium ions doped GeS_2-In_2S_3-CsI glass[J].Chemical Physics Letters,2009(1/3):104-106.
[22] Yunfeng Bai;Yuxiao Wang;Guanya Peng;Wang Zhang;Yueke Wang;Kun Yang;Xueru Zhang;Yinglin Song .Enhanced white light emission in Er/Tm/Yb/Li codoped Y_(2)O_(3) nanocrystals[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2009(9):1922-1924.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%