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The spectroscopic properties of lithium borate glasses as a function of Nd3+ions concentration were reported. Optical ab-sorption spectra of these glasses showed a number of absorption bands in ultra violet and visible region. Optical absorption edge was found to shift towards the longer wavelength (red shift) with increase in Nd2O3. Luminescence spectra revealed three major bands at 902, 1063 and 1334 nm which was due to 4F3/2→4I9/2, 11/2&13/2 transitions of Nd3+ions. Luminescence intensity was maximum for 1 mol.%Nd2O3 and further increase in Nd2O3 resulted in luminescence quenching. The luminescence quenching behavior at higher concentration of Nd2O3 was attributed to the Nd3+-Nd3+interaction in the glass matrix. An absorption and emission property of these glasses suggested that these glasses could be useful for 1.06 μm infrared laser applications.

参考文献

[1] Levasseur A;Menetrier M .Borate based lithium conduct-ing glasses[J].Mater Chem Phys,1989,23:1.
[2] Zwanziger J W;Youngman R E;Braun M.High-resolu-tion NMR studies of borate glass structure[A].Sheffield,UK:Society of Glass Technology,1997:21.
[3] Gedam R S;Ramteke D D .Electrical and optical proper-ties of lithium borate glasses doped with Nd2O3[J].J RareEarths,2012,30(08):758.
[4] Efflatal FH;Selim MS;Marzouk SY;Azooz MA .UV-vis absorption of the transition metal-doped SiO2-B2O3-Na2O glasses[J].Physica, B. Condensed Matter,2007(1):126-134.
[5] Yousef ES;El-Adawy A;El-KheshKhany N .Effect of rare earth (Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3 and Er2O3) on the acoustic properties of glass belonging to bismuth-borate system[J].Solid State Communications,2006(3):108-113.
[6] Gedam, R.S.;Ramteke, D.D. .Electrical, dielectric and optical properties of La_2O _3 doped lithium borate glasses[J].The journal of physics and chemistry of solids,2013(7):1039-1044.
[7] Gedam, R.S.;Ramteke, D.D. .Influence of CeO_2 addition on the electrical and optical properties of lithium borate glasses[J].The journal of physics and chemistry of solids,2013(10):1399-1402.
[8] Ramteke D D;Gedam R S .Study of Li2O-B2O3-Dy2O3 glasses by impedance spectroscopy[J].Solid State Ionics,2014,258:82.
[9] Dejneka M;Samson B .Rare-earth-doped fibers for tele-communications applications[J].Mater Res Soc Bull,1999,24:39.
[10] Weber M J .Glass for neodymium fusion lasers[J].J Non-Cryst Solids,1980,42:189.
[11] Yamane Y A M.Glasses for Photonics[M].Cambridge,United Kingdom:Cambridge University Press,2004
[12] Donald IW.;Taylor RNJ.;Metcalfe BL. .THE IMMOBILIZATION OF HIGH LEVEL RADIOACTIVE WASTES USING CERAMICS AND GLASSES [Review][J].Journal of Materials Science,1997(22):5851-5887.
[13] Sobczyk, M..Temperature-dependent luminescence and temperature-stimulated NIR-to-VIS up-conversion in Nd3+-doped La_2O_3-Na_2O-ZnO-TeO_2 glasses[J].Journal of Quantitative Spectroscopy & Radiative Transfer,2013:128-136.
[14] Kumar S., S.;Khatei, J.;Kasthurirengan, S.;Rao, K.S.R.K.;Ramesh, K.P. .Optical absorption and photoluminescence studies of Nd~(3+) doped alkali boro germanate glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2011(3):842-846.
[15] Sontakke A D;Biswas K;Mandal A K;Annapurna K .Concentration quenched luminescence and energy transfer analysis of Nd3+ ion doped Ba-Al-metaphosphate laser glasses[J].Appl Phys B,2010,101:235.
[16] Kumar K V;Kumar A S .Spectroscopic properties of Nd3+doped borate glasses[J].Opt Mater,2012,35:12.
[17] Balda R;Fernández J;Sanz M;de Pablos A Fdez-Navarro J M Mugnier J .Laser spectroscopy of Nd3+ions in GeO2-PbO-Bi2O3 glasses[J].Phys Rev B,2000,61:3384.
[18] Sontakke A D;Annapurna K .Spectroscopic properties and concentration effects on luminescence behavior of Nd3+doped zinc-boro-bismuthate glasses[J].Mater Chem Phys,2013,137:916.
[19] Nie Q H;Li X J;Dai S X;Xu T F Chen Y F Zhang X H .Investigation of 1.3 μm emission in Nd3+-doped bis-muth-based oxide glasses[J].Phys B Condens Matter,2007,400:88.
[20] Chimalawong, P.;Kaewkhao, J.;Kedkaew, C.;Limsuwan, P. .Optical and electronic polarizability investigation of Nd~3-doped soda-lime silicate glasses[J].The journal of physics and chemistry of solids,2010(7):965-970.
[21] Carnall W T;Fields P R;Rajnak K .Electronic energy lev-els in the trivalent lanthanide aquo ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+[J].J Chem Phys,1968,49:4424.
[22] Jlassi, I.;Elhouichet, H.;Ferid, M. .Thermal and optical properties of tellurite glasses doped erbium[J].Journal of Materials Science,2011(3):806-812.
[23] Ozdanova J;Ticha H;Tichy L .Remark on the optical gap in ZnO-Bi2O3-TeO2 glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2007(29):2799-2802.
[24] Ozdanova, J;Ticha, H;Tichy, L .Optical band gap and Raman spectra in some (Bi2O3)(x)(WO3)(y)(TeO2)(100-x-y) and (PbO)(x)(WO3)(y)(TeO2)(100-x-y) glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2009(45/47):2318-2322.
[25] Shakeri, M.S.;Rezvani, M. .Optical band gap and spectroscopic study of lithium alumino silicate glass containing Y~(3+) ions[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2011(5):1920-1925.
[26] Kamitsos E I;Karakassides M A .Far-infrared spectra of binary alkali borate glasses[J].Solid State Ionics,1988,28-30:687.
[27] Padmaja G;Kistaiah P .Infrared and Raman spectroscopic studies on alkali borate glasses:evidence of mixed alkali effect[J].J Phys Chem A,2009,113:2397.
[28] Gautam C;Yadav A K;Singh A K.A review on infrared spectroscopy of borate glasses with effects of different ad-ditives[M].ISRN Ceramics,2012
[29] Krogh-Moe J .Interpretation of the infrared spectra of bo-ron oxide and alkali borate glasses[J].Phys Chem Glasses,1965,6:46.
[30] Berkemeier F;Voss S;Imre AW;Mehrer H .Molar volume, glass-transition temperature, and ionic conductivity of Na- and Rb-borate glasses in comparison with mixed Na-Rb borate glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2005(52/54):3816-3825.
[31] Reddy R R;Ahammed Y N;Azeem P A;Gopal K R .Absorption and emission spectral studies of Sm3+and Dy3+doped alkali fluoroborate glasses[J].J Quant Spectrosc Ra-diat Transf,2003,77:149.
[32] Arun kumar S;Marimuthu K .Concentration effect of Sm3+ions in B2O3-PbO-PbF2-Bi2O3-ZnO glasses-Struc-tural and luminescence investigations[J].J Alloys Compd,2013,565:104.
[33] Jacinto C;Oliveira SL;Nunes LAO;Myers JD;Myers MJ;Catunda T .Normalized-lifetime thermal-lens method for the determination of luminescence quantum efficiency and thermo-optical coefficients: Application to Nd3+-doped glasses[J].Physical review, B. Condensed matter and materials physics,2006(12):5107-1-5107-9-0.
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