磁稳定床反应器

催化学报 , 2013, 34(1): 61-68. doi: 10.1016/S1872-2067(11)60476-2

磁稳定床反应器

宗保宁 ^1, , 孟祥堃 ^2, , 慕旭宏 ^3, , 张晓昕 ^4,

1.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

2.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

3.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

4.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

基金项目: the National Basic Research Program of China (2012CB224806).国家重点基础研究发展计划(973计划,2012CB224806)

关键词：磁稳定床 , 磁性催化剂 , 选择性加氢 , 一氧化碳甲烷化 , 烯烃叠合 , 工业化

Magnetically stabilized bed reactors

ZONG Baoning ^1, , MENG Xiangkun ^2, , MU Xuhong ^3, , ZHANG Xiaoxin ^4,

1.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

2.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

3.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

4.中国石油化工股份有限公司石油化工科学研究院,催化材料和反应工程国家重点实验室,北京100083

Keywords： Magnetically stabilized bed , Magnetic catalyst , Selective hydrogenation , Carbon monoxide methanation , Olefin oligomerization , Industrialization

介绍了磁稳定床反应器在国际上的首次工业应用,它集成了浆态床、固定床、移动床和流化床等反应器的优点.通过调整线圈间距、在反应器内设置磁隔栅构件,实现了均匀磁场的放大；绘制出磁稳定床反应器链式操作相图.将非晶态Ni优异的加氢性能和磁性与磁稳定床反应器反应过程强化性能相结合,实现了在己内酰胺加氢精制过程的工业应用,并建成5套20～40万吨/年工业装置.磁性催化剂与磁稳定床反应器相结合,强化了甲烷化、乙炔选择性加氢和烯烃叠合等反应过程,形成了新技术生长点.

参考文献

[1]	Dudukovic M P .[J].Science,2009,325:698.
[2]	Filippov M V .[J].Prik Magnit Lat SSR,1960,12:215.
[3]	Rosensweig R E .[J].Science,1979,204:57.
[4]	Liu Y A;Hamby R K;Colberg R D .[J].Powder Technology,1991,64:3.
[5]	Saxena S C;Shrivastava S .[J].Powder Technology,1991,64:57.
[6]	Sikavitsas V I;Yang R T;Burns M A;Langenmayr E J .[J].Industrial and Engineering Chemistry Research,1995,34:2873.
[7]	Wu W Y;Navada A;Saxena S C .[J].Powder Technology,1997,90:39.
[8]	Ganzha VL.;Saxena SC. .Hydrodynamic behavior of magnetically stabilized fluidized beds of magnetic particles[J].Powder Technology,2000(1/2):31-35.
[9]	Hristov J Y .[J].Powder Technology,1998,97:35.
[10]	Chen C M;Leu L P .[J].Powder Technology,2001,117:198.
[11]	Miura H;Takahashi T;Ichikawa J;Kawase Y .[J].Powder Technology,2001,117:239.
[12]	Hu T T;Wu J Y .[J].Chemical engineering Research and Design,1987,65:238.
[13]	Kwauk M S;Ma X H;Ouyang F;Wu Y X Weng D C Cheng L N .[J].Chemical Engineering Science,1992,47:3467.
[14]	Thompson V S;Worden R M .[J].Chemical Engineering Science,1997,52:279.
[15]	Zong B N;Min E Z;Zhu Y S .[P].CN 91111807.1,1993.
[16]	Mu X H;Zong B N;Min E Z;Wang X,Wang Y,Zhang X X,Shu X T .[P].US 6368996,2002.
[17]	Mu X H;Min E Z .[J].Journal of Chemical Industry and Engineering(China),1996,47:746.
[18]	Mu X H;Zong B N;Min E Z .[J].Chem React Eng Technol,1997,13(02):198.
[19]	Mu X H;Zong B N;Min E Z .[J].Acta Petrol Sin (Petrol Process Sec),1998,14:41.
[20]	Min E Z;Meng X K;Wen L Y .[J].Petrol Process Petrochem,2001,32(09):1.
[21]	Meng X K;Zhang X X;Zong B N;Min E Z .[J].Petrol Process Petrochem,2002,33(01):1.
[22]	Meng X K;Mu X H;Jiang Y S;Zong BN Min E Z Li B X Zhu H J Chen X B Fu S B Zhu Z H .[J].Journal of Chemical Industry and Engineering(China),2004,55:134.
[23]	Zhang J L;Zhang M;Li W;Li X F Meng X K Zong B N .[J].Particuology,2011,9:44.
[24]	Li W;Zong B N;Li X F;Meng X K Zhang J L .[J].China Particuology,2007,5(1-2):116.
[25]	Meng X K;Zong B N;Mu X H;Min E Z Zhu Z H Fu S B Zhu H J Li B X .[J].Chem React Eng Technol,2002,18:26.
[26]	Meng X K;Mu X H;Zong B N;Min E Z Zhu Z H Fu S B Luo Y B .[J].Catalysis Today,2003,79-80:21.
[27]	Pan ZY;Dong MH;Meng XK;Zhang XX;Mu XH;Zong BN .Integration of magnetically stabilized bed and amorphous nickel alloy catalyst for CO methanation[J].Chemical Engineering Science,2007(10):2712-2717.
[28]	Yu G B;Sun B;Pei Y;Xie S H Yan S R Qiao M H Fan K N Zhang X X Zong B N .[J].Journal of the American Chemical Society,2010,132:935.
[29]	Peng Y;Dong M H;Men X K;Zong B N Zhang J L .[J].AICHE Journal,2009,55:717.
[30]	Dong M H;Pan Z Y;Peng Y;Meng X K Mu X H Zong B N Zhang J L .[J].AICHE Journal,2008,54(05):1358.
[31]	Zong B N.[J].Catalysis Surveys From Asia,2007(1-2):87.
[32]	Zong B N;Mu X H;Meng X K;Zhang X X Min E Z .[J].Acta Petrol Sin (Petrol Process Sec),2006,22(02):1.
[33]	Sun S H;Murray C B;Weller D;Folks L Moser A .[J].Science,2000,287:1989.
[34]	Redl FX.;Cho KS.;Murray CB.;O'Brien S. .Three-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots[J].Nature,2003(6943):968-971.
[35]	Mao C B;Solis D J;Reiss B D;Kottrnann S T Sweeney R Y Hayhurst A Georgiou G Iverson B Belcher A M .[J].Science,2004,303:213.
[36]	Yavuz CT;Mayo JT;Yu WW;Prakash A;Falkner JC;Yean S;Cong LL;Shipley HJ;Kan A;Tomson M .Low-field magnetic separation of monodisperse Fe3O4 nanocrystals[J].Science,2006(5801):964-967.
[37]	Lu A H;Salabas E L;Schüth F .[J].Angewandte Chemie International Edition,2007,46:1222.
[38]	Latham A H;Williams M E .[J].Accounts of Chemical Research,2008,41:411.
[39]	Shylesh S;Schünemann V;Thiel W R .[J].Angewandte Chemie International Edition,2010,49:3428.
[40]	Tsang 5 C;Caps V;Paraskevas I;Chadwick D,Thompsett D .[J].Angewandte Chemie International Edition,2004,43:5645.
[41]	Abu-Reziq R;Alper H;Wang D S;Post M L .[J].Journal of the American Chemical Society,2006,128:5279.
[42]	Panella B;Vargas A;Baiker A .Magnetically separable Pt catalyst for asymmetric hydrogenation[J].Journal of Catalysis,2009(1):88-93.
[43]	Jin M J;Lee D H .[J].Angewandte Chemie International Edition,2010,49:1119.
[44]	Polshettiwar, V.;Luque, R.;Fihri, A.;Zhu, H.;Bouhrara, M.;Basset, J.-M. .Magnetically recoverable nanocatalysts[J].Chemical Reviews,2011(5):3036-3075.
[45]	Lai D M;Deng L;Guo Q X;Fu Y .[J].Energy Enivron Sci,2012,4:3552.

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