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  4. 低温燃料电池非铂催化剂研究进展

催化学报 , 2013, 34(6): 1051-1065. doi: 10.1016/S1872-2067(12)60588-9

低温燃料电池非铂催化剂研究进展

张洁 1, , 唐水花 2, , 廖龙渝 3, , 郁卫飞 4,

1.西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500;西南石油大学材料科学与工程学院,四川成都610500;中国工程物理研究院化工材料研究所,四川绵阳621900

2.西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500

3.中国工程物理研究院化工材料研究所,四川绵阳621900

4.中国工程物理研究院化工材料研究所,四川绵阳621900

基金项目:   四川省教育厅科技项目(13ZA0193).This work was supported by the Technology Project of Education Department of Sichuan Province (13ZA0193)  

关键词： 燃料电池 , 非铂催化剂 , 甲醇氧化 , 氧还原反应

Progress in non-platinum catalysts with applications in low temperature fuel cells

ZHANG Jie 1, , TANG Shuihua 2, , LIAO Longyu 3, , YU Weifei 4,

1.西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500;西南石油大学材料科学与工程学院,四川成都610500;中国工程物理研究院化工材料研究所,四川绵阳621900

2.西南石油大学油气藏地质及开发工程国家重点实验室,四川成都610500

3.中国工程物理研究院化工材料研究所,四川绵阳621900

4.中国工程物理研究院化工材料研究所,四川绵阳621900

Keywords： Fuel cell , Non-platinum catalyst , Methanol oxidation , Oxygen reduction reaction

简要综述了近年来低温燃料电池阳极和阴极催化剂的研究进展.阳极催化剂主要介绍了金属碳化物、Pd合金以及钙钛矿型氧化物三种,讨论了阳极催化剂对燃料氧化过程的催化活性和抗CO中毒能力;阴极催化剂则重点介绍了过渡金属大环化合物、氮化物以及氧化物,并较详细地阐述了过渡金属大环化合物的反应活性中心、金属-载体相互作用以及化合物制备条件.由于阴极非铂催化剂存在制备过程较复杂、中间产物过氧化物易破坏催化剂结构等问题,仍需探索新型的非铂催化剂.

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