以USY为载体制备了一系列不同Cu和MgO负载量的酸碱双功能催化剂Cu-MgO/USY用于甘油氢解制丙二醇反应,并采用X射线粉末衍射、透射电镜、傅里叶红外光谱、NH3程序升温脱附等手段对该催化剂进行了表征.结果表明,负载后的USY载体其Y沸石特征峰保持完整,且MgO的加入提高了Cu在载体表面的分散度.在200oC,3.5 MPa H2下反应10 h以及6%催化剂0.2Cu-MgO/USY (0.2 g Cu与1.0 g MgO负载于1.0 g USY上面)用量的条件下,甘油转化率达到83.6%,1,2-丙二醇及1,3-丙二醇的选择性分别为40%和19.4%.
A series of acid-base bifunctional catalysts composed of USY with different Cu and MgO loadings were prepared, characterized, and tested for the hydrogenolysis of glycerol. The USY support re-tained the Y zeolite structure, and the introduction of MgO enhanced the dispersion of Cu in the support. At 200 °C, 3.5 MPa H2, 10 h and with a 6%0.2Cu-MgO/USY catalyst, 83.6%conversion of glycerol with 40%selectivity to 1,2-propanediol (1,2-PDO) and 19.4%selectivity to 1,3-propanediol (1,3-PDO) was achieved.
参考文献
| [1] | Zhang X Y;Ma Q;Cheng B B;Wang J Li J S Nie F D .[J].Journal of Natural Gas Chemistry,2012,21:774. |
| [2] | Kiss, A.A.;Bildea, C.S. .A review of biodiesel production by integrated reactive separation technologies[J].Journal of Chemical Technology & Biotechnology,2012(7):861-879. |
| [3] | Pagliaro M;Ciriminna R;Kimura H;Rossi M Della Pina C .[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2007,46:4434. |
| [4] | Huang Z W;Cui F;Xue J J;Zuo J L Chen J Xia C G .[J].Catalysis Today,2012,183:42. |
| [5] | Selembo P A;Perez J M;Lloyd W A;Logan B E .[J].Biotechnology and Bioengineering,2009,104:1098. |
| [6] | Li Z G;Teng H;Xiu Z L .[J].Process Biochemistry,2011,46:586. |
| [7] | Behr A;Eilting J;Irawadi K;Leschinski J;Lindner F .Improved utilisation of renewable resources: New important derivatives of glycerol[J].Green chemistry,2008(1):13-30. |
| [8] | Zhou C H;Beltramini J N;Fan Y X;Lu G Q .[J].CHEMICAL SOCIETY REVIEWS,2008,37:527. |
| [9] | Sun L H;Song Z Y;Sun Y Q;Xiu Z L .[J].World Journal of Microbiology and Biotechnology,2010,26:1401. |
| [10] | Sanchez T;Salagre P;Cesteros Y;Bueno-Lopez A .[J].CHEMICAL ENGINEERING JOURNAL,2012,179:302. |
| [11] | Vasiliadou E S;Lemonidou A A .[J].Organic Process Research and Development,2011,15:925. |
| [12] | Wang, S;Liu, HC .Selective hydrogenolysis of glycerol to propylene glycol on Cu-ZnO catalysts[J].Catalysis Letters,2007(1/2):62-67. |
| [13] | Yuan Z L;Wang J H;Wang L N;Xie W H Chen P Hou Z Y Zheng X M .[J].Bioresource Technology,2010,101:7088. |
| [14] | Zhou J X;Zhang J;Guo X W;Mao J B Zhang S G .[J].Green Chemistry,2012,14:156. |
| [15] | Xia S X;Yuan Z L;Wang L N;Chen P Hou Z Y .[J].Bioresource Technology,2012,104:814. |
| [16] | Xia S X;Yuan Z L;Wang L N;Chen P Hou Z Y .[J].Applied Catalysis A:General,2011,403:173. |
| [17] | Nakagawa, Y.;Shinmi, Y.;Koso, S.;Tomishige, K. .Direct hydrogenolysis of glycerol into 1,3-propanediol over rhenium-modified iridium catalyst[J].Journal of Catalysis,2010(2):191-194. |
| [18] | Kurosaka T;Maruyama H;Naribayashi I;Sasaki Y .[J].CATALYSIS COMMUNICATIONS,2008,9:1360. |
| [19] | Zhu S H;Zhu Y L;Hao S L;Chen L G Zhang B Li Y W .[J].Catalysis Letters,2012,142:267. |
| [20] | Nakagawa Y;Tomishige K .[J].Catal Sci Technol,2011,1:179. |
| [21] | Li B D;Wang J;Yuan Y Z;Ariga H Takakusagi S Asakura K .[J].ACS Catal,2011,1:1521. |
| [22] | Xia S X;Nie R F;Lu X Y;Wang L N Chen P Hou Z Y .[J].Journal of Catalysis,2012,296:1. |
| [23] | Guo L Y;Zhou J X;Mao J B;Guo X W Zhang S G .[J].Applied Catalysis A:General,2009,367:93. |
| [24] | Yuan Z L;Wang L N;Wang J H;Xia S X,Chen P,Hou Z Y,Zheng X M .[J].Applied Catalysis B:Environmental,2011,101:431. |
| [25] | Chaminand J;Djakovitch L;Gallezot P;Marion P;Pinel C;Rosier C .Glycerol hydrogenolysis on heterogeneous catalysts[J].Green chemistry,2004(8):359-361. |
| [26] | Gandarias I;Arias P L;Requies J;Guemez M B Fierro J L G .[J].Applied Catalysis B:Environmental,2010,97:248. |
| [27] | Miyazawa T;Kusunoki Y;Kunimori K;Tomishige K .Glycerol conversion in the aqueous solution under hydrogen over Ru/C plus an ion-exchange resin and its reaction mechanism[J].Journal of Catalysis,2006(2):213-221. |
| [28] | Alhanash A;Kozhevnikova E F;Kozhevnikov I V .[J].Catalysis Letters,2008,120:307. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%