对载钛羟基磷灰石(TiHAP)进行了透射电镜、X射线衍射、紫外-可见光谱和Zeta电位表征,并应用液相色谱-质谱技术对比了TiHAP和P25 TiO2对环境内分泌干扰物双酚A(BPA)的吸附和光催化降解性能,探讨了富里酸和Fe3+对TiHAP薄膜光催化性能的影响.结果表明,TiHAP和TiO2粉体对BPA的吸附符合Langmuir吸附等温方程,且前者吸附性能更大.TiHAP薄膜光催化降解BPA的性能优于TiO2薄膜;富里酸和Fe3+对TiHAP和TiO2薄膜光催化性能的影响趋势不同,从能带结构、电子转移和吸光性等角度分析了性能不同的原因.本结果可以为应用TiHAP降解环境内分泌干扰物提供依据.
参考文献
| [1] | Nagel SC.;Thayer KA.;Dhar MG.;Boechler M.;Welshons WV.;Vomsaal FS. .RELATIVE BINDING AFFINITY SERUM MODIFIED ACCESS (RBA-SMA) ASSAY PREDICTS THE RELATIVE IN VIVO BIOACTIVITY OF THE XENOESTROGENS BISPHENOL A AND OCTYLPHENOL[J].Environmental Health Perspectives,1997(1):70-76. |
| [2] | Garoma T;Matsumoto S A;Wu Y;Klinger R .[J].OZONE-SCIENCE & ENGINEERING,2010,32:338. |
| [3] | Staples C A;Dome P B;Klecka G M;Oblock S T Harris L R .[J].CHEMOSPHERE,1998,36:2149. |
| [4] | Fromme H;Küchler T;Otto T;Pilz K Müller J Wenzel A .[J].Water Research,2002,36:1429. |
| [5] | 张海峰,胡建英,常红,王秀丽,高建峰,董民强.SPE-LC-MS法检测杭州地区饮用水水源及自来水中的双酚A[J].环境化学,2004(05):584-586. |
| [6] | 杜兵,张彭义,张祖麟,余刚.北京市某典型污水处理厂中内分泌干扰物的初步调查[J].环境科学,2004(01):114-116. |
| [7] | Kang JH;Kondo F;Katayama Y .Human exposure to bisphenol A.[J].Toxicology: An International Journal Concerned with the Effects of Chemicals on Living Systems,2006(2/3):79-89. |
| [8] | Katsumata H;Kawabe S;Kaneco S;Suzuki T Ohta K .[J].Journal of Photochemistry and Photobiology A: Chemistry,2004,162:297. |
| [9] | Rosenfeldt EJ;Linden KG .Degradation of endocrine disrupting chemicals bisphenol A, ethinyl estradiol, and estradiol during UV photolysis and advanced oxidation processes[J].Environmental Science & Technology: ES&T,2004(20):5476-5483. |
| [10] | Chen PJ;Linden KG;Hinton DE;Kashiwada S;Rosenfeldt EJ;Kullman SW .Biological assessment of bisphenol A degradation in water following direct photolysis and UV advanced oxidation[J].Chemosphere: Environmental toxicology and risk assessment,2006(7):1094-1102. |
| [11] | Korshin G V;Kim J;Gan L .[J].Water Research,2006,40:1070. |
| [12] | YangJ;Dai J;Li J T .[J].Applied Surface Science,2011,257:8965. |
| [13] | Kuruto-Niwa R;Terao Y;Nozawa R .[J].Environmental Toxicology and Pharmacology,2002,12:27. |
| [14] | Ohko Y;Ando I;Niwa C;Tatsuma T Yamamura T Nakashima T Kubota Y Fujishima A .[J].Environmental Science & Technology,2001,35:2365. |
| [15] | Torres R A;Nieto J I;Combet E;Pétrier C Pulgarin C .[J].Applied Catalysis B: Environmental,2008,80:168. |
| [16] | 贺艳,段海静,王广华,郭昌胜,王玉秋.3D介孔TiO_2微米球的制备及其光催化降解双酚A的研究[J].环境科学学报,2011(10):2179-2184. |
| [17] | Kuo C Y;Wu C H;Lin H Y .[J].DESALINATION,2010,256:37. |
| [18] | Xie Y B;Li X Z .[J].Journal of Hazardous Materials,2006,138:526. |
| [19] | Kandori K;Toshima S;Wakamura M;Fukusumi M Morisada Y .[J].Journal of Physical Chemistry B,2010,114:2399. |
| [20] | Wakamura M.;Hashimoto K.;Watanabe T. .Photocatalysis by calcium hydroxyapatite modified with Ti(IV): Albumin decomposition and bactericidal effect[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(8):3428-3431. |
| [21] | Tsukada M;Wakamura M;Yoshida N;Watanabe T .[J].Journal of Molecular Catalysis A: Chemical,2011,338:18. |
| [22] | Kandori, K.;Kuroda, T.;Wakamura, M. .Protein adsorption behaviors onto photocatalytic Ti(IV)-doped calcium hydroxyapatite particles[J].Colloids and Surfaces, B. Biointerfaces,2011(2):472-479. |
| [23] | Li S;Sun W L .[J].Journal of Hazardous Materials,2011,197:70. |
| [24] | Miyauchi M;Ikezawa A;Tobimatsu H;Irie H Hashimoto K .[J].Physical Chemistry Chemical Physics,2004,6:865. |
| [25] | Liao, DL;Wu, GS;Liao, BQ .Zeta potential of shape-controlled TiO2 nanoparticles with surfactants[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2009(1/3):270-275. |
| [26] | Chadwick MD.;Goodwin JW.;Lawson EJ.;Mills PDA.;Vincent B. .Surface charge properties of colloidal titanium dioxide in ethylene glycol and water[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(1/3):229-236. |
| [27] | Wakamura M.;Ishikawa T.;Kandori K. .Surface structure and composition of calcium hydroxyapatites substituted with Al(III), La(III) and Fe(III) ions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2000(2/3):297-305. |
| [28] | 王后锦,吴晓婧,王亚玲,焦自斌,颜声威,黄浪欢.二氧化钛纳米管阵列光电催化同时降解苯酚和Cr（VI）[J].催化学报,2011(04):637-642. |
| [29] | 尚静,薛莲,李佳,赵凤伟.全固态平面型ITO/Fe3+-TiO2/ITO光电催化器件的制备和催化性能[J].催化学报,2008(10):1037-1042. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%