Novel polystyrene-anchored zinc complex:Efficient catalyst for phenol oxidation

催化学报 , 2014, (10): 1701-1708. doi: 10.1016/S1872-2067(14)60113-3

Alekha Kumar Sutar a ^1, , Yasobanta Das ab ^2, , Sasmita Pattnaik a ^3, , Anita Routaray a ^4, , Nibedita Nath a ^5, , Prasanta Rath b ^6, , Tungabidya Maharana c ^7,

1.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

2.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

3.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

4.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

5.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

6.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

7.a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, 0disha, India b School of Applied Sciences Chemistry, KIIT University, Bhubaneswar, 0disha, India c Department of Chemistry, National Institute of Technology, Raipur, India

Novel polystyrene-anchored zinc complex:Efficient catalyst for phenol oxidation

Keywords： Polystyrene

The novel recyclable free -ONNO- tetradentate Schiff base ligand N,N′-bis(2-hydroxy-3-methox-ybenzaldehyde)4-methylbenzene-1,2-diamine (3-MOBdMBn) was synthesized. Complexation of this ligand with zinc (3-MOBdMBn-Zn) was performed, and the catalytic activity of the complex was evaluated. The polymer-supported analog of this complex (P-3-MOBdMBn-Zn) was synthesized, and its catalytic activity was studied. These free and polymer-anchored zinc complexes were prepared by the reactions of metal solutions with one molar equivalent of unsupported 3-MOBdMBn or P-3-MOBdMBn in methanol under nitrogen. The catalytic activity of 3-MOBdMBn-Zn and P-3-MOBdMBn-Zn was evaluated in phenol oxidation. The activity of P-3-MOBdMBn-Zn was signif-icantly affected by the polymer support, and the rate of phenol conversion was around 50%for polystyrene-supported 3-MOBdMBn. The experimental results indicated that the reaction rate was affected by the polymer support, and the rate of phenol conversion was 1.64 μmol/(L·s) in the presence of polystyrene-supported 3-MOBdMBn.

参考文献

[1]	Gupta K C;Sutar A K .[J].Coordination Chemistry Review,2008,252:1420.
[2]	Chang Y;Zha F;Su BT;Wang YP .Oxidation of styrene with molecular oxygen catalyzed by polymer-supported O-aminobenzoic acid salicylaldehyde Schiff-base copper(II) complex[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2006(6):923-931.
[3]	Ding KL;Wang Z;Wang XW;Liang YX;Wang XS .Self-supported chiral catalysts for heterogeneous enantioselective reactions[J].Chemistry: A European journal,2006(20):5188-5197.
[4]	Reger T S;Janda K D .[J].Journal of the American Chemical Society,2000,122:6929.
[5]	Sutar A K;Maharana T;Dutta S;Chen C T Lin C C .[J].CHEMICAL SOCIETY REVIEWS,2010,39:1724.
[6]	Vatankhah-Varnoosfaderani M;Pourmahdian S;Afshar-Taromi F .[J].IRANIAN POLYMER JOURNAL,2011,20:897.
[7]	Grivani G;Akherati A .[J].Inorganic Chemistry Communications,2013,28:90.
[8]	Gupta K C;Sutar A K;Lin C C .[J].Coordination Chemistry Review,2009,253:1926.
[9]	Islam S M;Mondal P;Tuhina K;Roy A S Mondal S Hossain D .[J].J In-org Organomet Polym Mater,2010,20:264.
[10]	Zhang L;Xu Y;Cui Y C .[J].IRANIAN POLYMER JOURNAL,2011,20:769.
[11]	Tamami B;Allahyari H;Farjadian F;Ghasem S .[J].IRANIAN POLYMER JOURNAL,2011,20:699.
[12]	Kowalak S;Weiss R C;Balkus K J Jr.[J].Journal of the Chemical Society Chemical Communications,1991:57.
[13]	Kumar A;Srinivas D .[J].Journal of Molecular Catalysis A:Chemical,2013,368-369:112.
[14]	Keav S;de los Monteros A E;Barbier J Jr;Duprez D .[J].Applied Catalysis B:Environmental,2014,150-151:402.
[15]	Bellardita M;Augugliaro V;Loddo V;Megna B Palmisano G Palmisano L Puma M A .[J].Applied Catalysis A:General,2012,441-442:79.
[16]	Henmert C;Renz M;Meunier B .[J].Journal of Molecular Catalysis A:Chemical,1999,137:205.
[17]	Walling C .[J].Accounts of Chemical Research,1975,8:125.
[18]	Salem I A;El-Maazawi M;Zaki A B .[J].International Journal of Chemical Kinetics,2000,32:643.
[19]	Fraile JM.;Royo AJ.;Salvador RV.;Altava B.;Luis SV. Burguete MI.;Mayoral JA. .SUPPORTED CHIRAL AMINO ALCOHOLS AND DIOLS FUNCTIONALIZED WITH ALUMINIUM AND TITANIUM AS CATALYSTS OF DIELS-ALDER REACTION[J].Tetrahedron,1996(29):9853-9862.
[20]	Kobayashi S;Nagayama S.[J].SYNLETT,1997:653.
[21]	Pu L .[J].Chemistry-A European Journal,1999,5:2227.
[22]	Randl S.;Connon SJ.;Blechert S.;Buschmann N. .Highly efficient and recyclable polymer-bound catalyst for olefin metathesis reactions[J].Synlett,2001(10):1547-1550.
[23]	De Blasio N.;Kaddouri A.;Mazzocchia C.;Cole-Hamilton DJ.;Tempesti E. .Activity and stability of two polymer-supported rhodium-based catalysts for the vapour phase carbonylation of methanol[J].Journal of Catalysis,1998(1):253-259.
[24]	Moghadam M;Tangestaninejad S;Habibi M H;Mirkhani V .[J].Journal of Molecular Catalysis A:Chemical,2004,217:9.
[25]	Buijsman R C;van Vuuren E;Sterrenburg J G .[J].Organic Letters,2001,3:3785.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
Alekha Kumar Sutar a Yasobanta Das ab Sasmita Pattnaik a Anita Routaray a Nibedita Nath a Prasanta Rath b Tungabidya Maharana c
在百度学术搜索
Alekha Kumar Sutar a Yasobanta Das ab Sasmita Pattnaik a Anita Routaray a Nibedita Nath a Prasanta Rath b Tungabidya Maharana c
在万方数据库搜索
Alekha Kumar Sutar a Yasobanta Das ab Sasmita Pattnaik a Anita Routaray a Nibedita Nath a Prasanta Rath b Tungabidya Maharana c
在CNKI搜索
Alekha Kumar Sutar a Yasobanta Das ab Sasmita Pattnaik a Anita Routaray a Nibedita Nath a Prasanta Rath b Tungabidya Maharana c

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Novel polystyrene-anchored zinc complex:Efficient catalyst for phenol oxidation

参考文献