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采用化学气相沉积法制备了高纯度的叠杯状碳纳米管薄膜.生长15 min后,薄膜厚度可达~300 μm.热重分析表明薄膜的纯度高达99.9%.透射电镜表征表明碳纳米管中石墨烯片层与轴向存在一定偏角呈叠杯状排列,其直径为80 nm~230 nm.通过对催化剂与叠杯状碳纳米管的结构分析,提出其根部生长机制.该叠杯状碳纳米管薄膜易于转移且具有良好的柔性.疏水性测试表明其具有超疏水表面,接触角约为155°,因而有望作为防水和自清洁保护层.

参考文献

[1] Li S S;Luo Y H;Lv W et al.Vertically aligned carbon nanotubes grown on graphene paper as electrodes in Lithium-Ion batteries and Dye-Sensitized solar cells[J].Adv Energy Mater,2011,1:486-490.
[2] Gong K P;Du F;Xia Z H et al.Nitrogen-Doped carbon nanorube arrays with high electrocatalytic activity for oxygen reduction[J].Science,2009,323:760-764.
[3] Rufan Zhang;Qian Wen;Weizhong Qian;Dang Sheng Su;Qiang Zhang;Fei Wei .Superstrong Ultralong Carbon Nanotubes for Mechanical Energy Storage[J].Advanced Materials,2011(30):3387-3391.
[4] T. Durkop;S. A. Getty;Enrique Cobas;M. S. Fuhrer .Extraordinary Mobility in Semiconducting Carbon Nanotubes[J].Nano letters,2004(1):35-39.
[5] Liu K;Sun Y H;Lin X Y et al.Scratch-Resistant,highly conductive,and High-Strength carbon Nanotube-Based composite yams[J].ACS,2010,4:5827-5834.
[6] M. Endo;Y. A. Kim;T. Hayashi;Y. Fukai;K. Oshida;M. Terrones;T. Yanagisawa;S. Higaki;M. S. Dresselhaus .Structural characterization of cup-stacked-type nanofibers with an entirely hollow core[J].Applied physics letters,2002(7):1267-1269.
[7] Kenji Saito;Masataka Ohtani;Shunichi Fukuzumi .Electron-Transfer Reduction of Cup-Stacked Carbon Nanotubes Affording Cup-Shaped Carbons with Controlled Diameter and Size[J].Journal of the American Chemical Society,2006(44):14216-14217.
[8] Takahashi, K;Ito, Y;Ikuta, T;Zhang, X;Fujii, M .Experimental and numerical studies on ballistic phonon transport of cup-stacked carbon nanofiber[J].Physica, B. Condensed Matter,2009(16):2431-2434.
[9] Qingfeng Liu;Wencai Ren;Zhi-Gang Chen .Semiconducting properties of cup-stacked carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(3):731-736.
[10] Morinobu Endo;Yoong Ahm Kim;Masay Ezaka;Koji Osada;Takashi Yanagisawa;Takuya Hayashi;Marucio Terrones;Mildred S. Dresselhaus .Selective and Efficient Impregnation of Metal Nanoparticles on Cup-Stacked-Type Carbon Nanofibers[J].Nano letters,2003(6):723-726.
[11] Wenzhen Li;Mahesh Waje;Zhongwei Chen .Platinum nanopaticles supported on stacked-cup carbon nanofibers as electrocatalysts for proton exchange membrane fuel cell[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(4):995-1003.
[12] Chan Kim;Yong Jung Kim;Yoong Am Kim;Takashi Yanagisawa;Ki Chul Park;Morinobu Endo;Mildred S. Dresselhaus .High performance of cup-stacked-type carbon nanotubes as a Pt-Ru catalyst support for fuel cell applications[J].Journal of Applied Physics,2004(10):5903-5905.
[13] Farrow, B;Kamat, PV .CdSe Quantum Dot Sensitized Solar Cells. Shuttling Electrons Through Stacked Carbon Nanocups[J].Journal of the American Chemical Society,2009(31):11124-11131.
[14] Young-Kuk Choi;Yasuo Gotoh;Koh-ichi Sugimoto;Sung-Moo Song;Takashi Yanagisawa;Morinobu Endo .Processing and characterization of epoxy nanocomposites reinforced by cup-stacked carbon nanotubes[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(25):11489-11498.
[15] Tomohiro Yokozeki;Yutaka Iwahori;Shin Ishiwata .Mechanical properties of CFRP laminates manufactured from unidirectional prepregs using CSCNT-dispersed epoxy[J].Composites, Part A. Applied science and manufacturing,2007(10):2121-2130.
[16] Tatsuo NODA;Tadao Ukai;Toshio Yao .Nano-Molar Level Hydrogen Peroxide Detection by Horseradish Peroxidase Adsorbed Cup-Stacked Carbon Nanotube Electrodes and Applications to L-Glutamate Detection[J].Analytical Sciences: The International Journal of The Japan Society for Analytical Chemistry,2010(6):675-679.
[17] D. Y. Zhong;G. Y. Zhang;S. Liu;E. G. Wang;Q. Wang;H. Li;X. J. Huang .Lithium storage in polymerized carbon nitride nanobells[J].Applied physics letters,2001(21):3500-3502.
[18] J. Mauricio Rosolen;E.Y. Matsubara;Marcel S. Marchesin .Carbon nanotube/felt composite electrodes without polymer binders[J].Journal of Power Sources,2006(1):620-628.
[19] Qingfeng Liu;Wencai Ren;Bilu Liu;Zhi-Gang Chen;Feng Li;Hongtao Cong;Hui-Ming Cheng .Synthesis, Purification and Opening of Short Cup-Stacked Carbon Nanotubes[J].Journal of nanoscience and nanotechnology,2009(8):4554-4560.
[20] Li S S;Hou P X;Liu C et al.Wall-Number selective growth of vertically aligned carbon nanotubes from FePt catalyst:A comparative study with Fe catalyst[J].Journal of Materials Chemistry,2012,22:14149-14154.
[21] Bennett R D;Hart A J;Cohen R E .Controlling the morphology of carbon nanotnbe films by varying the areal density of catalyst nanoclusters using block-copolymer micellar thin films[J].Advanced Materials,2006,18:2274-2279.
[22] J.-C.Charlier .Defects in carbon nanotubes[J].Accounts of Chemical Research,2002(12):1063-1069.
[23] Tang, YF;Allen, BL;Kauffman, DR;Star, A .Electrocatalytic Activity of Nitrogen-Doped Carbon Nanotube Cups[J].Journal of the American Chemical Society,2009(37):13200-13201.
[24] Mizuno K;Ishii J;Kishida H et al.A black body absorber from vertically aligned single-walled carbon nanotubes[J].P Natl Acad Sci,2009,106:6044-6047.
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