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以商业的氧化硅球为载体,采用化学气相沉积的方法将碳纳米管均匀地固载在宏观氧化硅球表面,成功地制备出一种新型的碳纳米管/氧化硅整体式复合材料,并考察了该复合材料在乙苯氧化脱氢制苯乙烯反应中的催化性能.与商业的粉末碳管相比,该复合材料能够有效地克服粉末碳管在固定床反应器中使用时产生的压力降.该整体式复合材料在乙苯氧化脱氢制苯乙烯反应中,具有较高的稳定性和苯乙烯收率,在催化领域中具有潜在的应用价值.

参考文献

[1] Baughman R H;Zakhidov A A;de Heer W A .Carbon nanotubes-the route toward applications[J].Science,2002,297:787-792.
[2] A Ishaq,Shahid Iqbal,Naveed Ali,A A Khurram,A U Akrajas,C F Dee,Shahzad Naseem,H M Rafique,Yan Long.H+,N+和Ar+离子束辐射诱导碳纳米结构的变化[J].新型炭材料,2013(02):81-87.
[3] Su D S;Schl(o)gl R .Nanostructured carbon and carbon nanocomposites for electrochemical energy storage applications[J].ChemSusChem,2010,3:136-168.
[4] Philippe Serp;Massimiliano Corrias;Philippe Kalck .Carbon nanotubes and nanofibers in catalysis[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2003(2):337-358.
[5] Su D S;Zhang J;Frank B et al.Metal-free heterogeneous catalysis for sustainable chemistry[J].ChemSusChem,2010,3:169-180.
[6] Jian Zhang;Dangsheng Su;Aihua Zhang;Di Wang;Robert Schlogl;Cécile Hébert .Nanocarbon as Robust Catalyst: Mechanistic Insight into Carbon-Mediated Catalysis[J].Angewandte Chemie,2007(38):7319-7323.
[7] Zhang J;Liu X;Blume R;Zhang A et al.Surface-modified carbon nanotubes catalyze oxidative dehydrogenation of n-butane[J].Science,2008,322:73-77.
[8] Xi Liu;Dang Sheng Su;Robert Schlogl .Oxidative dehydrogenation of 1-butene to butadiene over carbon nanotube catalysts[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(3):547-549.
[9] Benjamin Frank;Jian Zhang;Raoul Blume .Heteroatoms Increase the Selectivity in Oxidative Dehydrogenation Reactions on Nanocarbons[J].Angewandte Chemie,2009(37):6913-6917.
[10] Frank B;Morassutto M;Schomaecker R et al.Oxidative dehydrogenation of ethane over multiwalied carbon nanotubes[J].ChemCatChem,2010,2:644-648.
[11] Aurore Morancais;Brigitte Caussat;Yolande Kihn .A parametric study of the large scale production of multi-walled carbon nanotubes by fluidized bed catalytic chemical vapor deposition[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(3):624-635.
[12] Colomer J.-F. .Large-scale synthesis of single-wall carbn nanotubes by catalytic chemical vapor deposition (CCVD)method[J].Chemical Physics Letters,2000(1/2):83-89.
[13] Ramesh P;Okazaki T;Sugai T;Kimura J;Kishi N;Sato K;Ozeki Y;Shinohara H .Purification and characterization of double-wall carbon nanotubes synthesized by catalytic chemical vapor deposition on mesoporous silica[J].Chemical Physics Letters,2006(4-6):408-412.
[14] Shaoming Huang .Growing carbon nanotubes on patterned submicron-size SiO_2 spheres[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(12):2347-2352.
[15] Qiang Zhang;Meng-Qiang Zhao;Jia-Qi Huang .Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(11):2600-2610.
[16] Zhao M Q;Zhang Q;Huang J Q et al.Advanced materials from natural materials:synthesis of aligned carbon nanotubes on wollastonites[J].Chem Sus Chem,2010,3:453-459.
[17] R. Vieira;C. Pham-Huu;N. Keller;M. J. Ledoux .New carbon nanofiber/graphite felt composite for use as a catalyst support for hydrazine catalytic decomposition[J].Chemical communications,2002(9):954-955.
[18] Hitoshi Ogihara;Masahiro Sadakane;Qiang Wn .Immobilization of nanofibrous metal oxides on microfibers:A macrostructured catalyst system functionalized with nanoscale fibrous metal oxides[J].Chemical communications,2007(39):4047-4049.
[19] Jarrah NA;Li FH;van Ommen JG;Lefferts L .Immobilization of a layer of carbon nanofibres (CNFs) on Ni foam: A new structured catalyst support[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(19):1946-1953.
[20] Gu, LJ;Ma, D;Yao, SD;Wang, CL;Shen, WJ;Bao, XH .Structured zeolites catalysts with hierarchical channel structure[J].Chemical communications,2010(10):1733-1735.
[21] Enrique Garcia-Bordeje;Ingvar Kvande;De Chen;Magnus Ronning .Carbon Nanofibers Uniformly Grown on γ-Alumina Washcoated Cordierite Monoliths[J].Advanced Materials,2006(12):1589-1592.
[22] Worsley, M.A.;Stadermann, M.;Wang, Y.M.;Satcher Jr., J.H.;Baumann, T.F. .High surface area carbon aerogels as porous substrates for direct growth of carbon nanotubes[J].Chemical communications,2010(48):9253-9255.
[23] J.J. Delgado;D.S. Su;G. Rebmann .Immobilized carbon nanofibers as industrial catalyst for ODH reactions[J].Journal of Catalysis,2006(1):126-129.
[24] Xiao-Wei Chen;Dang Sheng Su;Sharifah B.A. Hamid .The morphology, porosity and productivity control of carbon nanofibers or nanotubes on modified activated carbon[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(4):895-898.
[25] Dang Sheng Su;Xiaowei Chen;Xi Liu;Juan Jose Delgado;Robert Schloegl;Andreja Gajovic .Mount-Etna-Lava-Supported Nanocarbons for Oxidative Dehydrogenation Reactions[J].Advanced Materials,2008(19):3597-3600.
[26] Yuan H;Sun Z;Liu H Y.Immobilizing carbon nanotubes on SiC foam as a monolith catalyst for oxidative dehydrogenation reactions[J].Chem Cat Chem,2013
[27] Rinaldi A;Zhang J;Frank B et al.Oxidative purification of carbon nanotubes and its impact on catalytic performance in oxidative dehydrogenation reactions[J].Chem Sus Chem,2010,3:254-260.
[28] Gerhard Mestl;Nadezhda I. Maksimova;Nicolas Keller;Vladimir V. Roddatis;Robert Schlogl .Carbon Nanofilaments in Heterogeneous Catalysis: An Industrial Application for New Carbon Materials?[J].Angewandte Chemie International Edition,2001(11):2066-2068.
[29] Su D S;Maksimova N;Delgado J J et al.Nanoearbons in selective oxidative dehydrogenation reaction[J].Catalysis Today,2005,102-103:110-114.
[30] J.A.Macia-Agullo;D.Cazorla-Amoros;A.Linares-Solano;U.Wild;D.S.Su .Oxygen functional groups involved in the styrene production reaction detected by quasi in situ XPS[J].Catalysis Today,2005(0):248-253.
[31] Jian Zhang;Rui Wang;Enze Liu .Spherical Structures Composed of Multiwalled Carbon Nanotubes: Formation Mechanism and Catalytic Performance[J].Angewandte Chemie,2012(30):7581-7585.
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