元素掺杂是一种有效改善电极性能的手段.为了提高钛基锡系形稳阳极的催化活性,La被作为一种改性剂掺杂在Ti/Sb-SnO2电极的涂层中.掺杂改性后电极涂层的形貌通过SEM及XRD进行了检测;并通过EDS检测了涂层中各元素的组成比例;利用电化学阳极极化曲线(LSV)测试了电极的电化学性能.利用掺杂改性后的电极和未改性电极电解处理模拟对硝基苯酚(p-NP)废水,在相同条件下,掺杂La改性后电极处理废水的降解率为92.8%,远高于未改性电极处理废水的降解率(72%).实验表明,稀土La改性后的Ti/Sb-SnO2电极在处理p-NP废水的优越性相当明显.
参考文献
[1] | ZhuXB;TianJP;LiuR;ChenLJ .Optimization of Fenton and electro-Fenton oxidation of biologically treated coking wastewater using response surface methodology[J].Separation and Purification Technology,2011,81(05):444. |
[2] | Martínez-Huitle C A;Brillas E .Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods:A general review[J].Applied Catalysis B:Environmental,2009,87(09):105. |
[3] | Nidheesh P V;Gandhimathi R .Trends in electro-Fen-ton process for water and wastewater treatment:An overview[J].Desalination,2012,299(0):1. |
[4] | Fornazari A L T;Malpass G R P;Miwa D W;Motheo A J .Application of electrochemical degradation of wastewater composed of mixtures of phenol-formaldehyde[J].Water,Air & Soil Pollution,2012,223(05):4895. |
[5] | Chen F T;Yu S C;Dong X P;Zhang S S .High-effi-cient treatment of wastewater contained the carcinogen naphthylamine by electrochemical oxidation with γ-Al2 O3supported MnO2 and Sb-doped SnO2 catalyst[J].Journal of Hazardous Materials,2012,227-228(04):474. |
[6] | Lacasa E;Llanos J;C(a)nizares P;Rodrigo M A .Electrochemical denitrificacion with chlorides using DSA and BDD anodes[J].Chemical Engineering Journal,2012,184(08):66. |
[7] | Brinzila C;Pacheco M J;Ciríaco L;Ciobanu R C Lopes A .Electrodegradation of tetracycline on BDD anode[J].Chemical Engineering Journal,2012,209(02):54. |
[8] | 李善评,胡振,曹翰林.钕改性钛基SnO2/Sb电催化电极的制备及表征[J].中国稀土学报,2008(03):291-297. |
[9] | 王静,冯玉杰,刘正乾.稀土Gd掺杂对SnO2电催化电极性能影响的研究[J].功能材料,2005(06):877-880. |
[10] | 吕彦玲,邵光杰,赵北龙,吴伟.稀土镧掺杂MnO2电极的制备及性能研究[J].中国稀土学报,2009(05):652-656. |
[11] | 刘余九.中国稀土产业现状及发展的主要任务[J].中国稀土学报,2007(03):257-263. |
[12] | Wang M J;Chen L;Wang Z X;Bao E .Effect of rare earth addition on continuous heating transformation of a high speed steel for rolls[J].Journal of Rare Earths,2012,30(09):84. |
[13] | 范洪富,王磊,关杰,张翼.稀土掺杂PbO2电极的制备及催化性能研究[J].中国稀土学报,2007(03):299-304. |
[14] | 张招贤.钛电极学导论[M].北京:冶金工业出版社,2008:9. |
[15] | Liu Y K;Feng Y J;Wu X W;Han X G .Microwave absorption properties of La doped barium titanate in Xband[J].Journal of Alloys and Compounds,2009,472(1-2):441. |
[16] | Costa C R;Botta M R;Espindola L G;livi P .Electrochemical treatment of tannery wastewater using DSA electrodes[J].Journal of Hazardous Materials,2008,153(09):616. |
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