采用阳极氧化法在不锈钢基体上制备了脂肪醇聚氧乙烯醚(AEO)改性PbO2电极.通过SEM图像和XRD图谱分别考察了电极的表面形貌和物相组成,采用稳态极化法和循环伏安法分析了电极在甲基橙模拟废液中的电化学特性,并对质量浓度为10mg·L-1的甲基橙模拟废水进行了电催化降解实验.结果表明,与未改性PbO2电极相比,改性PbO2电极表面平整致密,具有较高的析氧电位和较高的氧化峰电流,有利于有机物的降解.降解实验结果表明改性电极的电催化活性高于未改性电极和石墨电极.
参考文献
[1] | MUTHUKUMAR M,SARGUNAMANI D,SELVAKUMAR N,et al .Optimisation of ozone treatment for colour and COD removal of acid dye effluent using central composite design experiment[J].Dyes Pigments,2004,63(2):127-134.,2004. |
[2] | MERIC S,KAPTAN D,OLMEZ T .Color and COD removal from wastewater containing reactive black 5 using Fenton's oxidation process[J].Chemosphere,2004,54(3):435-441.,2004. |
[3] | 张艳霞,季晓彤,张朝红,沈曼莉,王杰,胥丹平,徐瑶,李芳轶.过氧化氢溶液改性活性炭催化微波照射降解结晶紫的研究[J].染料与染色,2011(04):47-51. |
[4] | PANIZZA M,CERISOLA G .Removal of colour and COD from wastewater containing acid blue 22 by electrochemical oxidation[J].Journal of Hazardous Materials,2008,153:83-88.,2008. |
[5] | ZHOU Ming-hua,SARKKA H,SILLANPAA M .A comparative experimental study on methyl orange degradation by electrochemical oxidation on BDD and MMO electrodes[J].Separation and Purification Technology,2011,78(3):290-297.,2011. |
[6] | TAHAR N B,SAVALL A .Electrochemical degradation of phenol in aqueous solution on bismuth doped lead dioxide:A comparison of the activities of various electrode formulations[J].Applied Electrochemistry,1999,29 |
[7] | ZHAO Guo-hua,ZHANG Yong-gang,LEI Yan-zhu,et al .Fabrication and electrochemical treatment application of a novel lead dioxide anode with superhydrophobic surfaces,high oxygen evolution potential,and oxidation capability[J].Environmental Science Technology,2010,44(5):1754-1759.,2010. |
[8] | 余峰,马香娟,吴祖成.电化学法处理含盐有机废水研究进展[J].水处理技术,2010(12):6-10. |
[9] | WANG Ying,SHEN Zhen-yao,LI Yang,et al .Electrochemical properties of the erbium-chitosan-fluorine-modified PbO2 electrode for the degradation of 2,4-dichlorophenol in aqueous solution[J].Chemosphere,2010,79(10):987-996.,2010. |
[10] | ZHOU Ming-hua,DAI Qi-zhou,LEI Le-cheng,et al .Long life modified lead dioxide anode for organic wastewater treatment:electrochemical characteristics and degradation mechanism[J].Environmental Science Technology,2005,39(1):363-370.,2005. |
[11] | HAMZA M,AMMAR S,ABDELHEDI R .Electrochemical oxidation of 1,3,5-trimethoxybenzene in aqueous solutions at gold oxide and lead dioxide electrodes[J].Electrochimica Acta,2011,56 |
[12] | 周明华,戴启洲,雷乐成,吴祖成,马淳安,汪大翚.新型二氧化铅阳极电催化降解有机污染物的特性研究[J].物理化学学报,2004(08):871-876. |
[13] | HAN Wei-qing,CHEN Yong,WANG Lian-jun,et al .Mechanism and kinetics of electrochemical degradation of isothiazolinones using Ti/SnO2-Sb/PbO2 anode[J].Desalination,2011,276 |
[14] | 韩国成,刘峥,王永燎.Co改性PbO2/Ti电催化电极处理模拟染料废水[J].桂林工学院学报,2008(03):375-380. |
[15] | AI Shi-yun,GAO Meng-nan,ZHANG Wen,st al .Preparation of Ce-PbO2 modified electrode and its application in detection of anilines[J].Talanta,2004,62(3):445-450.,2004. |
[16] | KONG Jiang-tao,SHI Shao-yuan,KONG Ling-cai,et al .Preparation and characterization of PbO2 electrodes doped with different rare earth oxides[J].Electrochimca Acta,2007,53(4):2048-2054.,2007. |
[17] | 杨卫华,付芳,杨武涛.聚乙烯吡咯烷酮对PbO2电极微结构和性能的影响[J].材料研究学报,2011(02):199-204. |
[18] | 宋曰海 .不锈钢基不溶性催化电极的制备——及其对难降解有机废水的电催化降解作用[D].北京化工大学,2007. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%