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材料工程, 2014, (8): 97-104. doi: 10.11868/j.issn.1001-4381.2014.08.018

单分散聚合物微球的合成方法进展

李光辉 1, , 张贵才 2, , 葛际江 3, , 申金伟 4, , 蒋平 5,

1.中国石油大学(华东),山东青岛,266580

2.中国石油大学(华东),山东青岛,266580

3.中国石油大学(华东),山东青岛,266580

4.中国石油大学(华东),山东青岛,266580

5.中国石油大学(华东),山东青岛,266580

关键词： 单分散 , 聚合物微球 , 共聚焦微流化 , 电流体动力学喷雾 , 自组装

Progress of Synthesis Method for Monodisperse Polymer Microspheres

Keywords： monodisperse , polymer microsphere , flow-focusing microfluidic method , electrohydrodynamic atomization , self-assembling

本文综述了近年来使用传统自由基聚合方法控制粒径单分散性的操作工艺特点.总结了新制备方法,包括膜乳化、共聚焦微流化、电流体动力学喷雾、喷墨打印法、气溶胶凝胶法、两亲聚合物的自组装及改进的St(o)ber方法等,介绍了其原理、特点和研究现状.最后,提出了关于单分散聚合物微球合成发展的建议.

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