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在超高真空磁控溅射仪上,制备了一系列具有相同调制周期不同层厚比的Cr/CrN涂层.用X射线衍射仪分析了涂层的相组成,通过扫描电镜观察了涂层形貌,采用显微硬度计测试了涂层硬度,在划痕仪上确定涂层和基体间的结合力,并利用磨损仪测量涂层的摩擦磨损性能.结果表明:调制周期为400nm时,当层厚比由2.0减小到0.2,Cr/CrN多层涂层始终由Cr和CrN两相组成,涂层择优取向为CrN(200),且涂层变得愈加致密,硬度从1550HV增大到2300HV,磨损率从2.4×10-8mm3·N-1·m-1减小为0.6×10-8mm3·N-1·m-1,涂层和基体结合性能优良.

参考文献

[1] Shuyong Tan;Xuhai Zhang;Xiangjun Wu;Feng Fang;Jianqing Jiang .Comparison of chromium nitride coatings deposited by DC and RF magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2011(7):2116-2120.
[2] 潘应晖,许晓静.Ti6Al4V表面磁控溅射高硬SiC薄膜的摩擦磨损性能[J].材料工程,2013(06):63-66.
[3] 谈淑咏,张旭海,李纪宏,吴湘君,蒋建清.基底负偏压对直流磁控溅射CrN薄膜择优取向及表面形貌的影响[J].功能材料,2010(06):1015-1018.
[4] Wang, L;Nie, X;Housden, J;Spain, E;Jiang, JC;Meletis, EI;Leyland, A;Matthews, A .Material transfer phenomena and failure mechanisms of a nanostructured Cr-Al-N coating in laboratory wear tests and an industrial punch tool application[J].Surface & Coatings Technology,2008(5/7):816-821.
[5] 喻利花,苑彩云,许俊华.磁控溅射NbSiN复合膜的微结构和性能[J].材料工程,2013(07):35-39.
[6] Qimin Wang;In-Wook Park;Kwangho Kim .Influence of N_(2) gas pressure and negative bias voltage on the microstructure and properties of Cr-Si-N films by a hybrid coating system[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,2008(5):1188-1194.
[7] 周小军,易健宏,倪成林,徐成竹,黄峰,张学东,徐英.VC/Ni纳米叠层薄膜的制备及力学性能[J].航空材料学报,2014(01):39-45.
[8] Del Re, M;Dauchot, JP;Hecq, M .Study of the moisture and thermal resistance of AlN/ZrN/AlN multilayers coating[J].Surface & Coatings Technology,2005(1/4):94-99.
[9] CHU X;BARNETT S A .Model of superlattice yield stress and hardness enhancement[J].Journal of Applied Physics,1995,77:4403-4441.
[10] JLANKOWSKI A F .Measurement of lattice strain in Au-Ni multilayer and correlation with biaxial modulus effect[J].Jour-nal of Applied Physics,1992,71:1782-1789.
[11] Mohles V. .Orowan process controlled dislocation glide in materials containing incoherent particles[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(0):265-269.
[12] Kim YJ;Byun TJ;Han JG .Bilayer period dependence of CrN/CrAlN nanoscale multilayer thin films[J].Superlattices and microstructures,2009(2):73-79.
[13] Rahman, M;Haider, J;Dowling, DP;Duggan, P;Hashmi, MSJ .Deposition of magnetron sputtered TiN+MoSx coating with Ti-TiN graded interlayer[J].Surface & Coatings Technology,2005(1/4):1071-1075.
[14] Haider, J;Rahman, M;Corcoran, B;Hashmi, MSJ .Deposition and characterization of hard-solid lubricant coating by closed-field magnetron sputtering[J].Surface & Coatings Technology,2005(1/4):1080-1083.
[15] 谈淑咏,张旭海,吴湘君,蒋建清.氮流量比对直流反应磁控溅射制备氮化铬涂层组织和性能的影响[J].机械工程材料,2010(07):34-37.
[16] 谈淑咏,张旭海,吴湘君,蒋建清.Si基底磁控溅射制备CrN薄膜的表面形貌与生长机制[J].中国有色金属学报,2011(06):1367-1372.
[17] 钟彬,徐小连,陈义庆,艾芳芳,胡绍伟,王永,李国卿.Cr/CrN多层膜的结构及腐蚀性能研究[J].真空,2009(05):22-25.
[18] 王静 .反应磁控溅射金属/TiN多层膜及金属掺杂TiN薄膜的制备与特性[D].延吉:延边大学,2012.
[19] Romero J;Esteve J;Lousa A .Period dependence of hardness and microstructure on nanometric Cr/CrN multilayers[J].Surface & Coatings Technology,2004(0):338-343.
[20] 蔡志海,牛庆银,底月兰,张平.调制周期对Cr/CrN纳米多层膜的结构与性能的影响[J].金属热处理,2011(01):29-32.
[21] 王全宏 .Ti/TiN/Zr/ZrN多层膜及Al薄膜对钢基体疲劳性能的影响[D].中南大学,2012.
[22] M. Berger;U. Wiklund;M. Eriksson;H. Engqvist;S. Jacobson .The multilayer effect in abrasion -- optimising the combination of hard and tough phases[J].Surface & Coatings Technology,1999(0):1138-1144.
[23] 宋贵宏,娄茁,熊光连,陈立佳.铜合金表面Ti/TiN多层膜的制备、结构及其性能[J].沈阳工业大学学报,2012(04):391-396.
[24] 杜军,付永辉,田林海,朱晓东,何家文.碳膜与CrN-Cu膜的摩擦学性能对比[J].有色金属,2004(02):19-21.
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