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石墨烯是碳原子以sp2杂化连接而成的单原子层结构,这一独特的二维结构使得石墨烯具有优异的光电性能、热稳定性以及化学性能.石墨烯复合材料的制备、性能和应用成为近年的研究热点.本文综述了石墨烯复合材料的制备方法,包括石墨烯/高分子复合材料、石墨烯/金属(金属氧化物)复合材料、石墨烯三元复合材料,以及石墨烯复合材料在锂电池、电容器、光伏材料、传感器等方面的应用研究进展,指出了石墨烯复合材料研究的重要方向.

参考文献

[1] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al .Electric field effect in atomically thin carbon films[J].Science,2004,306(5296):666-669.,2004.
[2] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al .Two-dimensional gas of massless Dirac fermions in graphene[J].Nature,2005,438(7065):197-200.,2005.
[3] GEIM A K,NOVOSELOV K S .The rise of graphene[J].Nature Materials,2007,6(3):183-191.,2007.
[4] BALANDIN A A,GHOSH S,BAO W,et al .Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.,2008.
[5] CHAE H K,SIBERIO-PEREZ D Y,KIM J,et al .A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature,2004,427(6974):523-527.,2004.
[6] LEE C G,WEI X D,KYSAR J W,et al .Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321(5887):385-388.,2008.
[7] KIM H,MIURA Y,MACOSKO C W .Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity[J].ChemMater,2010,22(11):3441-3450.,2010.
[8] WAKABAYASHI K,PIERRE C,DIKIN D A,et al .Polymergraphite nanocomposites:effective dispersion and major property enhancement via solid-state shear pulverization[J].Macromolecules,2008,41(6):1905-1908.,2008.
[9] YANG Y,WANG J,ZHANG J,et al .Exfoliated graphite oxide decorated by PDMAEMA chains and polymer particles[J].Langmuir,2009,25(19):11808-11814.,2009.
[10] KIM H,MACOSKO C W .Processing-property relationships of polycarbonate/graphene composites[J].Polymer,2009,50(15):3797-3809.,2009.
[11] LIANG J,HUANG Y,ZHANG L,et al .Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites[J].Adv Fun Mater,2009,19(14):2297-2302.,2009.
[12] ZHAO X,ZHANG Q,CHEN D,et al .Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites[J].Macromolecules,2010,43(5):2357-2363.,2010.
[13] WU Q,XU Y,YAO Z,et al .Supercapacitors based on flexible graphene/polyaniline nanofiber composite films[J].ACS Nano,2010(4):1963-1970.,2010.
[14] WANG H,HAO Q,YANG X,et al .Effect of graphene oxide on the properties of its composite with polyaniline[J].ACS Appl Mate Inter,2010,2(3):821-828.,2010.
[15] GLOVER A J,CAI M,OVERDEEP K R,et al .In situ reduction of graphene oxide in polymers[J].Macromolecules,2011,44(24):9821-9829.,2011.
[16] TANG Y,WU N,LUO S,et al .One-step electrodeposition to layer-by-layer graphene-conducting-polymer hybrid films[J].Macromol Rapid Comm,2012,33(20):1780-1786.,2012.
[17] STANKOVICH S,DIKIN D A,DOMMETT G H B,et al .Graphene-based composite materials[J].Nature,2006,442(7100):282-286.,2006.
[18] BAE S,KIM H,LEE Y,et al .Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nat Nanotechol,2010,5(8):574-578.,2010.
[19] CHEN Z,REN W,GAO L,et al .Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nat Mater,2011,10(6):424-428.,2011.
[20] 燕绍九,杨程,洪起虎,陈军洲,刘大博,戴圣龙.石墨烯增强铝基纳米复合材料的研究[J].材料工程,2014(04):1-6.
[21] BAI S,SHEN X,ZHONG X,et al .One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal[J].Carbon,2012,50(6):2337-2346.,2012.
[22] TIAN J,LIU S,ZHANG Y,et al .Environmentally friendly,one-pot synthesis of Ag nanoparticle-decorated reduced graphene oxide composites and their application to photocurrent generation[J].InorgChem,2012,51(8):4742-4746.,2012.
[23] LIANG J,WEI W,ZHONG D,et al .One-step in situ synthesis of SnO2/graphene nanocomposites and its application as an anode material for Li-ion batteries[J].ACS Appl Mater Inter,2011,4(1):454-459.,2011.
[24] DONG X,XU H,WANG X,et al .3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucosedetection[J].ACSNano,2012,6(4):3206-3213.,2012.
[25] WU J,SHEN X,JIANG L,et al .Solvothermal synthesis and characterization of sandwich-like graphene/ZnO nanocomposites[J].ApplSurfSci,2010,256(9):2826-2830.,2010.
[26] SHEN J F,YAN B,SHI M,et al .One step hydrothermal synthesis of TiO2-reduced graphene oxide sheets[J].J Mater Chem,2011,21(10):3415-3421.,2011.
[27] WANG H W,HU Z A,CHANG Y Q,et al .Facile solvothermal synthesis of a graphene nanosheet-bismuth oxide composite and its electrochemical characteristics[J].Electrochim Acta,2010,55(28):8974-8980.,2010.
[28] ZHU J X,ZHU T,ZHOU X Z,et al .Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability[J].Nanoscale,2011(3):1084-1089.,2011.
[29] DAI Y,CAI S,YANG W,et al .Fabrication of self-binding noble metal/flexible graphene composite paper[J].Carbon,2012,50(12):4648-4654.,2012.
[30] ADHIKARI B,BISWAS A,BANERJEE A .Graphene oxidebased supramolecular hydrogels for making nanohybrid systems withAu nanoparticles[J].Langmuir,2011,28(2):1460-1469.,2011.
[31] TIEN H,HUANG Y,YANG S,et al .The production of graphene nanosheets decorated with silver nanoparticles for use in transparent,conductive films[J].Carbon,2011,49(5):1550-1560.,2011.
[32] ZHOU X,HUANG X,QI X,et al .In situ synthesis of metal nanoparticles on single-layer graphene oxide and reduced graphene oxide surfaces[J].J Phys Chem C,2009,113(25):10842-10846.,2009.
[33] ZHANG Z,XU F,YANG W,et al .A facile one-pot method to high-quality Ag-graphene composite nanosheets for efficient surface-enhanced Raman scattering[J].Chem Commun,2011,47(22):6440-6442.,2011.
[34] ZHANG M,QU B,LEI D,et al .A green and fast strategy for the scalable synthesis of Fe2O3/graphene with significantly enhanced Li-ion storage properties[J].J Mater Chem,2012,22(9):3868-3874.,2012.
[35] VADAHANAMBI S,JUNG J,OH I .Microwave syntheses of graphene and graphene decorated with metal nanoparticles[J].Carbon,2011,49(13):4449-4457.,2011.
[36] LIN Y,BAGGETT D W,KIM J,et al .Instantaneous formation of metal and metal oxide nanoparticles on carbon nanotubes and graphene via solvent-free microwave heating[J].ACS Appl Mater Interf,2011,3(5):1652-1664.,2011.
[37] HASSAN H M A,ABDELSAYED V,KHDER A E R S,et al .Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media[J].J Mater Chem,2009,19(23):3832-3837.,2009.
[38] GUARDIA L,VILLAR-RODIL S,PAREDES J I,et al .UV light exposure of aqueous graphene oxide suspensions to promote their direct reduction,formation of graphene-metal nanoparticle hybrids and dye degradation[J].Carbon,2012,50(3):1014-1024.,2012.
[39] AKHAVAN O .Photocatalytic reduction of graphene oxides hy bridized by ZnO nanoparticles in ethanol[J].Carbon,2011,49(1):11-18.,2011.
[40] WILLIAMS G,SEGER B,KAMAT P V .TiO2-graphene nanocomposites.UV-assisted photocatalytic reduction of graphene oxide[J].ACSNano,2008,2(7):1487-1491.,2008.
[41] KARIM M R,SHINODA H,NAKAI M,et al .Electrical conductivity and ferromagnetism in a reduced graphene-metal oxide hybrid[J].Adv Fun Mater,2013,23(3):323-332.,2013.
[42] LIU X,MAO J,LIU P,et al .Fabrication of metal-graphene hybrid materials by electroless deposition[J].Carbon,2011,49(2):477-483.,2011.
[43] CAO X,SHI Y,SHI W,et al .Preparation of novel 3D graphene networks for supercapacitor applications[J].Small,2011,7(22):3163-3168.,2011.
[44] MANDAL S,SAHA S K .Ni/graphene/Ni nanostructures for spintronic applications[J].Nanoscale,2012,4(3):986-990.,2012.
[45] TUNG T T,FELLER J,KIM T,et al .Electromagnetic properties of Fe3O4-functionalized graphene and its composites with a conducting polymer[J].J Polym Sci Pol Chem,2012,50(5):927-935.,2012.
[46] KASSAEE M Z,MOTAMEDI E,MAJDI M .Magnetic Fe3O4-graphene oxide/polystyrene:fabrication and characterization of a promising nanocomposite[J].Chem Eng J,2011,172(1):540-549.,2011.
[47] WANG X,SONG L,YANG H,et al .Cobalt oxide/graphene composite for highly efficient CO oxidation and its application in reducing the fire hazards of aliphatic polyesters[J].J Mater Chem,2012,22(8):3426-3431.,2012.
[48] BIRROZZIA A,RACCICHINIB R,NOBILIA F,et al .Highstability graphene nano sheets/SnO2 composite anode for lithium ion batteries[J].Electrochimica Acta,2014,137(10):228-234.,2014.
[49] WANG H L,CUI L F,YANG Y A,et al .Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries[J].J AmChemSoc,2010,132(40):13978-13980.,2010.
[50] CHEN J S,WANG Z Y,DONG X C,et al .Graphene-wrapped TiO2 hollow structures with enhanced lithium storage capabilities[J].Nanoscale,2011,3(5):2158-2161.,2011.
[51] 丁翔,黄正宏,沈万慈,康飞宇.氧化铜/石墨烯的制备及其电化学性能[J].新型炭材料,2013(03):172-177.
[52] CHEN S,ZHU J,WU X,et al .Graphene oxide-MnO2 nanocomposites for supercapacitors[J].ACS Nano,2010,4(5):2822-2830.,2010.
[53] 曲江英,李雨佳,李传鹏,石琳,邵光华,高峰.还原氧化石墨烯/Mn3 O4纳米复合材料的合成及其在超级电容器中的应用[J].新型炭材料,2014(03):186-192.
[54] CHEN S,ZHANG L L,ZHAO X S,et al .Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J].Chem Mater,2010,22(4):1392-1401.,2010.
[55] LIU J,WANG Z,XIE X,et al .A rationally-designed synergetic polypyrrole/graphene bilayer actuator[J].J Mater Chem,2012,22(9):4015-4020.,2012.
[56] ZHAO Y,LIU J,HU Y,et al .Highly compression-tolerant supercapacitor based on polypyrrole-mediated graphene foam electrodes[J].Adv Mater,2013,25(4):591-595.,2013.
[57] WANG X,ZHI L J,MULLEN K,et al .Transparent,conductive graphene electrodes for dye-sensitized solar cells[J].Nano Letter,2008,8(1):323-327.,2008.
[58] BECERRIL H A,MAO J,LIU Z F,et al .Evaluation of solution-processed reduced graphene oxide films as transparent conductors[J].ACS Nano,2008,2(3):463-470.,2008.
[59] LI X L,ZHANG G Y,BAI X D,et al .Highly conducting graphene sheets and langmuir-blodgett films[J].Nat Nanotechnol,2008,3(9):538-542.,2008.
[60] ALWARAPPAN S,ERDEM A,LI C Z,et al .Probing the electrochemical properties of graphene nanosheets for biosensing applications[J].J PhysChemC,2009,113(20):8853-8857.,2009.
[61] WANG Y,YANG R,SHI Z,et al .Super elastic graphene ripples for flexible strain sensors[J].ACS Nano,2011(5):3645-3650.,2011.
[62] HONG W,BAI H,XU Y,et al .Preparation of gold nanoparticle/graphene composites with controlled weight contents and their application in biosensors[J].J Phys Chem C,2010,114(4):1822-1826.,2010.
[63] ROBINSON J T,PERKINS F K,SNOW E S,et al .Reduced graphene oxide molecular sensors[J].Nano Letter,2008,8(10):3137-3140.,2008.
[64] SCHEDIN F,GEIM A K,MOROZOV S V,et al .Detection of individual gas molecules adsorbed on graphene[J].Nat Mater,2007,6(9):652-655.,2007.
[65] DAN Y,LU Y,KYBERT N J,et al .Intrinsic response of graphenevapor sensors[J].Nano Letters,2009,9(4):1472-1475.,2009.
[66] KIM Y,NA H,MIND .Influence of surface functionalization on the growth of gold nanostructures on graphene thin films[J].Langmuir,2010,26(16):13065-13070.,2010.
[67] LIU H R,YANG W B,HE F F,et al .Graphene-based composite with microwave absorption property prepared by in situ reduction[J].PolymCompos,2014,35(3):461-467.,2014.
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