采用熔融共混法制备高密度聚乙烯(HDPE)/膨胀石墨(EG)/石蜡导热定形相变材料(PCM),并对其渗漏率、微观形貌、导热性能和相变潜热进行研究.结果表明:导热定形相变材料中,HDPE,EG和石蜡三种组分具有较好的相容性;PCM中添加EG时渗漏率有所提高,但渗漏率随EG含量的增加而降低;EG含量为15%(质量分数)时,PCM渗漏率低于0.6%;PCM热导率随EG含量的增加而增加,EG含量为15%时,热导率达到1.265W/(m·K);PCM的相变潜热随EG含量的增加变化不大.
参考文献
[1] | HADJIEVA M;KANEV S;ARGIROV J .Thermophysical properties of some paraffins applicable to thermal energy storage[J].Solar Energy Storage Materials & Solar Cells,1992,27(02):181-187. |
[2] | Atul Sharma;V.V. Tyagi;C.R. Chen;D. Buddhi .Review On Thermal Energy Storage With Phase Change Materials And Applications[J].Renewable & sustainable energy reviews,2009(2):318-345. |
[3] | Zhang, Y.;Wang, S.;Rao, Z.;Xie, J. .Experiment on heat storage characteristic of microencapsulated phase change material slurry[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2011(10):2726-2733. |
[4] | Molefi, JA;Luyt, AS;Krupa, I .Comparison of LDPE, LLDPE and HDPE as matrices for phase change materials based on a soft Fischer-Tropsch paraffin wax[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2010(1/2):88-92. |
[5] | SARI A .Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage:preparation and thermal properties[J].Energy Conversion Management,2004,45(13-14):2033-2042. |
[6] | 秦鹏华,杨睿,张寅平,林坤平.定形相变材料的热性能[J].清华大学学报(自然科学版),2003(06):833-835. |
[7] | Zhengguo Zhang;Ni Zhang;Jing Peng;Xiaoming Fang;Xuenong Gao;Yutang Fang .Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material[J].Applied energy,2012(1):426-431. |
[8] | ZHANG Z G;FANG X M .Study on paraffin/expanded graphite composite phase change thermal energy storage material[J].Energy Conversion & Management,2006,47(03):303-310. |
[9] | Ahmet Sari;Ali Karaipekli .Thermal conductivity and latent heat thermal energy storage characteristics of paraffin/expanded graphite composite as phase change material[J].Applied thermal engineering: Design, processes, equipment, economics,2007(8-9):1271-1277. |
[10] | 张秀荣,朱冬生,高进伟,吴淑英.石墨/石蜡复合相变储热材料的热性能研究[J].材料研究学报,2010(03):332-336. |
[11] | Liwu Fan;J.M.Khodadadi .Thermal conductivity enhancement of phase change materials for thermal energy storage: A review[J].Renewable & sustainable energy reviews,2011(1):24-46. |
[12] | Ping Zhang;Yuan Hu;Lei Song;Jianxiong Ni;Weiyi Xing;Jian Wang .Effect of expanded graphite on properties of high-density polyethylene/paraffin composite with intumescent flame retardant as a shape-stabilized phase change material[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2010(2):360-365. |
[13] | Pincemin S;Olives R;Py X;Christ M .Highly conductive composites made of phase change materials and graphite for thermal storage[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(6):603-613. |
[14] | 丁剑红,张寅平,王馨,杨睿,林坤平.掺杂对定形相变材料导热系数的影响[J].太阳能学报,2005(06):853-856. |
[15] | 汪向磊,郭全贵,王立勇,魏兴海,刘朗.高导热定形聚乙烯/石蜡/膨胀石墨相变复合材料的研究[J].功能材料,2013(23):3401-3404. |
[16] | Aiping Yu;Palanisamy Ramesh;Xiaobo Sun;Elena Bekyarova;Mikhail E. Itkis;Robert C Haddon .Enhanced Thermal Conductivity In A Hybrid Graphite Nanoplatelet - Carbon Nanotube Filler For Epoxy Composites[J].Advanced Materials,2008(24):4740-4744. |
[17] | 夏莉,张鹏,周圆,王如竹.石蜡与石蜡/膨胀石墨复合材料充/放热性能研究[J].太阳能学报,2010(05):610-614. |
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