以CNFs膜为基材,采用层层自组装法制备CNFs/RGOn膜,通过原位聚合法在膜表面聚合PANI,制备复合导电CRGP膜电极并组成超级电容器S-RGP.研究采用UV-vis光谱、XRD、SEM等对CRGP膜的吸光度、结晶特性与形态进行测试表征,同时系统测试了S-RGPCV曲线、GCD、EIS等电化学性能.结果表明:原位聚合法得到CRGP膜表面不均匀,PANI层与基材间存在间隙,存有活性物质,导致S-RGP内阻较小;S-RGP的ESR低、柔性良好;由于原位聚合的PANI层较厚,电容器S-RGP具有一定的电致变色特征.
参考文献
| [1] | Guohai Chen;Don N. Futaba;Shunsuke Sakurai.Interplay of wall number and diameter on the electrical conductivity of carbon nanotube thin films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:318-325. |
| [2] | 杨田林;许心光 .磁控溅射法在柔性衬底上制备ZnO:Al透明导电薄膜[J].山东大学学报:自然科学版,1998,33(3):271-275. |
| [3] | Rongjin Li;Khaled Parvez;Felix Hinkel .Bioinspired Wafer-Scale Production of Highly Stretchable Carbon Films for Transparent Conductive Electrodes[J].Angewandte Chemie,2013(21):5535-5538. |
| [4] | WELSER R E;SOOD A W;CHO J.Nanostructured transparent conductive oxides for photovoltaic applications[A].,2013:1493-1496. |
| [5] | Mortimer, R.J.;Varley, T.S..Electrochromic devices based on surface-confined Prussian blue or Ruthenium purple and aqueous solution-phase di-n-heptyl viologen[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2013:275-279. |
| [6] | WADE C R;LI Min-yuan;FACILE M .Deposition of multicolored electrochromic metal-organic framework thin films[J].Angewandte Chemie,2013,125(50):13619-13623. |
| [7] | Satyananda Barik;Daminda Navarathne;Maxence LeBorgnef .Conjugated thiophenoazomethines: electrochromic materials exhibiting visible-to-near-IR color changes[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(35):5508-5519. |
| [8] | M. B. Sreedhara;H. S. S. Ramakrishna Matte;A. Govindaraj;C. N. R. Rao .Synthesis, Characterization, and Properties of Few-Layer MoO_3[J].Chemistry, an Asian journal,2013(10):2430-2435. |
| [9] | Navas Illyaskutty;Heinz Kohler;Thomas Trautmann .Enhanced ethanol sensing response from nanostructured MoO3:ZnO thin films and their mechanism of sensing[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(25):3976-3984. |
| [10] | TASHTOUSH N M;KASASBEH O .Optical properties of vanadium pentoxide thin films prepared by thermal evaporation method[J].Journal of Physics,2018,6(1):7-15. |
| [11] | LIU Chen-cheng;LIU Kuang;CHANG Chiung-wen et al.Investigation of vanadium oxide thin film deposited by sputtering for electrochromic applications[J].Advanced Materials Engineering and Technology,2012,626:215-218. |
| [12] | GARDU(N)O W I;ALONSO J C .Hydrogen sensors fabricated with sprayed NiO,NiO:Li and NiO:Li,Pt thin films original research article[J].International Journal of Hydrogen Energy,2013,38(10):4213-4219. |
| [13] | 张官理,伍建华,霍钟祺,张晓锋.丙烯酸树脂涂层对透明导电薄膜整体性能的影响[J].材料工程,2011(08):48-51. |
| [14] | 唐劲松;詹瑞云;倪少儒 等.聚苯胺导电机理的探讨[J].化学物理学报,1989(2):140-145. |
| [15] | 涂亮亮,贾春阳.导电聚合物超级电容器电极材料[J].化学进展,2010(08):1610-1618. |
| [16] | 徐建华,杨亚杰,蒋亚东,于军胜.导电聚合物纳米线的制备及气敏性能研究[J].功能材料,2009(01):71-74. |
| [17] | GAO Ke-zheng;SHAO Zi-qiang;WANG Xi .Cellulose nanofibers/multi-walled carbon nanotubenanohybrid aerogel for all-solid-state flexible supercapacitors[J].RSC Advances,2013,3(35):15058-15064. |
| [18] | Kezheng Gao;Ziqiang Shao;Xue Wu .Paper-based transparent flexible thin film supercapacitors[J].Nanoscale,2013(12):5307-5311. |
| [19] | Kezheng Gao;Ziqiang Shao;Jia Li .Cellulose nanofiber-graphene all solid-state flexible supercapacitors[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(1):63-67. |
| [20] | Xi Wang;Kezheng Gao;Ziqiang Shao;Xiaoqing Peng;Xue Wu;Feijun Wang .Layer-by-Layer assembled hybrid multilayer thin film electrodes based on transparent cellulose nanofibers paper for flexible supercapacitors applications[J].Journal of Power Sources,2014(Mar.1):148-155. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%