采用化学气相沉积法合成出氮原子掺杂的碳纳米管,再将其与铝基体进行复合制备出碳纳米管/铝基复合材料.运用TEM和XPS研究氮掺杂碳纳米管的结构形貌和掺杂形态,并对碳纳米管/铝基复合材料的力学和电学性能进行研究与分析.结果表明:碳纳米管呈现出竹节状周期性多层结构,且成功掺杂氮原子.与纯碳纳米管相比,基于氮掺杂碳纳米管的铝基复合材料具有更高的抗拉强度和电导率.由于氮原子的引入,改善了碳纳米管的分散度和浸润性,提升了其电子传递效率,从而更有利于其在金属基复合材料中的应用.
参考文献
[1] | S. R. Bakshi;D. Lahiri;A. Agarwal.Carbon nanotube reinforced metal matrix composites - a review[J].International Materials Reviews,20101(1):41-64. |
[2] | Benjamin Boesl;Debrupa Lahiri;Sadegh Behdad.Direct observation of carbon nanotube induced strengthening in aluminum composite via in situ tensile tests[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:79-85. |
[3] | O.Hjortstam;P.Isberg;S.Soderholm;H.Dai.Can we achieve ultra-low resistivity in carbon nanotube-based metal composites?[J].Applied physics, A. Materials science & processing,20048(8):1175-1179. |
[4] | Song, H.-Y.;Zha, X.-W..Influence of nickel coating on the interfacial bonding characteristics of carbon nanotube-aluminum composites[J].Computational Materials Science,20104(4):899-903. |
[5] | 曹茂盛;邱成军;朱静.碳纳米管表面修饰的研究进展[J].航空材料学报,2003(4):59-62. |
[6] | Tjong, S.C..Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets[J].Materials Science & Engineering, R. Reports: A Review Journal,201310(10):281-350. |
[7] | Kambiz Chizari;Uttandaraman Sundararaj.The effects of catalyst on the morphology and physicochemical properties of nitrogen-doped carbon nanotubes[J].Materials Letters,2014Feb.1(Feb.1):289-292. |
[8] | K.Kaneto;M.Tsuruta.Electrical conductivities of multi-wall carbon nano tubes[J].Synthetic Metals,19991/3(1/3):2543-2546. |
[9] | Wei J;Hu H;Zeng H;Zhou Z;Yang W;Peng P.Effects of nitrogen substitutional doping on the electronic transport of carbon nanotube[J].Physica, E. Low-dimensional systems & nanostructures,20083(3):462-466. |
[10] | Xiaowei Chen;Lei Wan;Jianmei Huang.Nitrogen-containing carbon nanostructures: A promising carrier for catalysis of ammonia borane dehydrogenation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:462-472. |
[11] | 张宇;温斌;宋肖阳;李廷举.不同氮掺杂浓度碳纳米管的制备及其成键特性分析[J].物理学报,2010(5):3583-3588. |
[12] | Hui Wei;Zhiqiang Li;Ding-Bang Xiong.Towards strong and stiff carbon nanotube-reinforced high-strength aluminum alloy composites through a microlaminated architecture design[J].Scripta materialia,2014:30-33. |
[13] | 李玲;林奎;张帆;崔兰;王慧;陈小平;张丽爽;Sayyar Ali Shah;崔屾.氮掺杂长竹节状碳纳米管的制备及其生长机理[J].无机化学学报,2014(5):1097-1103. |
[14] | Shang-Chou Chang;To-Sing Li;Tien-Chai Lin.Significant morphology dependence on nitrogen proportion in growing carbon nanotubes[J].Materials Letters,200812/13(12/13):1893-1895. |
[15] | Yu Zhang;Chenguang Liu;Bin Wen;Xiaoyang Song;Tingju Li.Preparation and electrochemical properties of nitrogen-doped multi-walled carbon nanotubes[J].Materials Letters,20111(1):49-52. |
[16] | 陈亚光;蔡晓兰;王开军;胡翠;孙鸿鹏;乐刚.高能球磨法制备的CNTs/Al-5%Mg复合材料的力学性能及断裂特性[J].材料工程,2014(11):55-61. |
[17] | Liu, Qian;Pu, Zonghua;Asiri, Abdullah M.;Sun, Xuping.Bamboo-like nitrogen-doped carbon nanotubes toward fluorescence recovery assay for DNA detection[J].Sensors and Actuators, B. Chemical,2015:37-42. |
[18] | Kambiz Chizari;Alexander Vena;Lars Laurentius.The effect of temperature on the morphology and chemical surface properties of nitrogen-doped carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:369-379. |
[19] | 李莉香;刘永长;耿新;安百刚.氮掺杂碳纳米管的制备及其电化学性能[J].物理化学学报,2011(2):443-448. |
[20] | A.M.K. Esawi;K. Morsi;A. Sayed;A. Abdel Gawad;P. Borah.Fabrication and properties of dispersed carbon nanotube-aluminum composites[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20091/2(1/2):167-173. |
[21] | 高伟洁;郭淑静;张洪波;潘秀莲;包信和.氮掺杂碳纳米管对其负载的Ru催化剂上合成氨的促进作用[J].催化学报,2011(8):1418-1423. |
[22] | Xu C.L.;Wei B.Q.;Ma R.Z;Liang J.;Ma X.K.;Wu D.H..Fabrication of aluminum-carbon nanotube composites and their electrical properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,19995(5):855-858. |
[23] | Sheikh M.Uddin;Tanvir Mahmud;Christoph Wolf;Carsten Glanz;Ivica Kolaric;Christoph Volkmer;Helmut Hoeller;Ulrich Wienecke;Siegmar Roth;Hans-Joerg Fecht.Effect of size and shape of metal particles to improve hardness and electrical properties of carbon nanotube reinforced copper and copper alloy composites[J].Composites science and technology,201016(16):2253-2257. |
[24] | Z.Y.Liu;B.L.Xiao;W.G.Wang;Z.Y.Ma.Tensile Strength and Electrical Conductivity of Carbon Nanotube Reinforced Aluminum Matrix Composites Fabricated by Powder Metallurgy Combined with Friction Stir Processing[J].材料科学技术(英文版),2014(7):649-655. |
[25] | Hamze Mousavi;Rostam Moradian.Nitrogen and boron doping effects on the electrical conductivity of graphene and nanotube[J].Solid state sciences,20118(8):1459-1464. |
[26] | 梁彤祥;刘娟;王晨.石墨烯的电子结构及其应用进展[J].材料工程,2014(6):89-96. |
[27] | 李静 .硼掺杂碳纳米管的制备及其在镁基复合材料中的应用[D].天津大学,2011. |
[28] | 王昆鹏;师春生;赵乃勤;杜希文.B(N)掺杂单壁碳纳米管的Al原子吸附性能的第一性原理研究[J].物理学报,2008(12):7833-7840. |
[29] | 赵素;刘政;张新兵.纳米碳管增强铝基复合材料的工艺及性能研究[J].铸造技术,2006(2):135-138. |
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