Buckypaper/聚合物复合材料中碳纳米管团聚较少,且含量较高,使得碳纳米管的优异性能得以更加充分的发挥,显著提升了复合材料的各项性能.由于Buckypaper结构紧密,传统的滤渗浸渍方法不能满足制备高质量Buckypaper/环氧复合材料的要求.为提高环氧树脂在Buckypaper中的浸渍效率和质量,开发了Buckypaper的“加压滤渗”浸渍工艺,将环氧树脂溶液通过Buckypaper进行加压过滤,实现对Buckypaper的有效、均匀和完全浸渍.Buckypaper/环氧复合材料微观形貌表征结果表明,“加压滤渗”浸渍工艺制备的Buckypaper/环氧复合材料表面质量良好,且环氧树脂在Buckypaper内部充分浸渍,且分布均匀.与溶液浸渍法制备的Buckypaper/环氧复合材料对比,“加压滤渗”浸渍工艺制备的复合材料具有更加优异的力学性能,更加充分地发挥了Buckypaper的增强效率.
参考文献
[1] | Yu MF.;Arepalli S.;Ruoff RS.;Files BS..Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties[J].Physical review letters,200024(24):5552-5555. |
[2] | Hone J.;Piskoti C.;Zettl A.;Whitney M..Thermal conductivity of single-walled carbon nanotubes[J].Physical Review.B.Condensed Matter,19994(4):R2514-R2516. |
[3] | Wolfgang Bauhofer;Josef Z. Kovacs.A review and analysis of electrical percolation in carbon nanotube polymer composites[J].Composites science and technology,200910(10):1505-1515. |
[4] | Zhidong Han;Alberto Fina.Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review[J].Progress in Polymer Science,20117(7):914-944. |
[5] | Erik T. Thostenson;C. Li;Tsu-Wei Chou.Nanocomposites in context[J].Composites science and technology,20053/4(3/4):491-516. |
[6] | Zhi Wang;Zhiyong Liang;Ben Wang.Processing and property investigation of single-walled carbon nanotube (SWNT) buckypaper/epoxy resin matrix nanocomposites[J].Composites, Part A. Applied science and manufacturing,200410(10):1225-1232. |
[7] | High CNT content composites with CNT Buckypaper and epoxy resin matrix: Impregnation behaviour composite production and characterization[J].Composite structures,20106(6):1291. |
[8] | J.Hone;M.C.Llaguno;M.J.Biercuk;A.T.Johnson;B.Batlogg;Z.Benes.Thermal properties of carbon nanotubes and nanotube-based materials[J].Applied physics, A. Materials science & processing,20023(3):339-343. |
[9] | Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives[J].Applied physics letters,200311(11):1682-1684. |
[10] | Frizzell CJ;in het Panhuis M;Coutinho DH;Balkus KJ;Minett AI;Blau WJ;Coleman JN.Reinforcement of macroscopic carbon nanotube structures by polymer intercalation: The role of polymer molecular weight and chain conformation[J].Physical review, B. Condensed matter and materials physics,200524(24):5420-1-5420-8-0. |
[11] | Jianwei Zhang;Dazhi Jiang.Interconnected multi-walled carbon nanotubes reinforced polymer-matrix composites[J].Composites science and technology,20114(4):466-470. |
[12] | Jianwei Zhang;Dazhi Jiang;Hua-Xin Peng.A pressurized filtration technique for fabricating carbon nanotube buckypaper: Structure, mechanical and conductive properties[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2014:127-133. |
[13] | Jianwei Zhang;Dazhi Jiang;Hua-Xin Peng.Enhanced mechanical and electrical properties of carbon nanotube buckypaper by in situ cross-linking[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:125-132. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%