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石墨烯以其优异的物理化学性能,近年来受到了学术和产业界的广泛关注.将石墨烯进行功能化,可改善石墨烯的分散性,并且能根据需求对石墨烯的物理化学性能进行针对性地优化,因而赋予石墨烯更广泛的用途,因此,功能化石墨烯成为石墨烯研究领域的热点之一.综述功能化石墨烯的最新进展,从共价结合和非共价结合两个方面阐述了其制备的方法,叙述近年来功能化石墨烯在复合材料、储能材料、光电材料、催化材料、环境净化、生物及传感材料等领域的应用研究进展.总结出功能化石墨烯的特点,即大多数活性基团搭载到石墨烯的表面上都能活跃地展现其应用性能.功能化石墨烯未来的研究方向主要是判定和控制石墨烯表面引入功能化物质的量的“定量”问题和精确在石墨烯表面选择功能化的位点并进行精细化学结构设计的“定位”问题..

参考文献

[1] Geim AK;Novoselov KS.The rise of graphene[J].Nature materials,20073(3):183-191.
[2] Miaomiao Li;Wang Ni;Bin Kan.Graphene quantum dots as the hole transport layer material for high-performance organic solar cells[J].Physical chemistry chemical physics: PCCP,201343(43):18973-18978.
[3] Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff.Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,201035(35):3906-3924.
[4] Ruben Mas-Balleste;Cristina Gomez-Navarro;Julio Gomez-Herrero.2D materials: to graphene and beyond[J].Nanoscale,20111(1):20-30.
[5] Ponomarenko,LA;Schedin,F;Katsnelson,MI;Yang,R;Hill,EW;Novoselov,KS;Geim,AK.Chaotic Dirac billiard in graphene quantum dots.[J].Science,20085874(5874):356-358.
[6] Georgakilas, V.;Otyepka, M.;Bourlinos, A.B.;Chandra, V.;Kim, N.;Kemp, K.C.;Hobza, P.;Zboril, R.;Kim, K.S..Functionalization of graphene: Covalent and non-covalent approaches, derivatives and applications (Review)[J].Chemical Reviews,201211(11):6156-6214.
[7] Park, S;Ruoff, RS.Chemical methods for the production of graphenes[J].Nature nanotechnology,20094(4):217-224.
[8] Bekyarova, E;Itkis, ME;Ramesh, P;Berger, C;Sprinkle, M;de Heer, WA;Haddon, RC.Chemical Modification of Epitaxial Graphene: Spontaneous Grafting of Aryl Groups[J].Journal of the American Chemical Society,20094(4):1336-1338.
[9] Zhong Jin;Jay R. Lomeda;B. Katherine Price.Mechanically Assisted Exfoliation and Functionalization of Thermally Converted Graphene Sheets[J].Chemistry of Materials: A Publication of the American Chemistry Society,200914(14):3045-3047.
[10] Jay R. Lomeda;Condell D. Doyle;Dmitry V. Kosynkin;Wen-Fang Hwang;James M. Tour.Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets[J].Journal of the American Chemical Society,200848(48):16201-16206.
[11] Sharma, R;Baik, JH;Perera, CJ;Strano, MS.Anomalously Large Reactivity of Single Graphene Layers and Edges toward Electron Transfer Chemistries[J].Nano letters,20102(2):398-405.
[12] Hossain, M.Z.;Walsh, M.A.;Hersam, M.C..Scanning tunneling microscopy, spectroscopy, and nanolithography of epitaxial graphene chemically modified with aryl moieties[J].Journal of the American Chemical Society,201043(43):15399-15403.
[13] Georgakilas, V;Bourlinos, AB;Zboril, R;Steriotis, TA;Dallas, P;Stubos, AK;Trapalis, C.Organic functionalisation of graphenes[J].Chemical communications,201010(10):1766-1768.
[14] Bourlinos, AB;Georgakilas, V;Zboril, R;Steriotis, TA;Stubos, AK.Liquid-Phase Exfoliation of Graphite Towards Solubilized Graphenes[J].Small,200916(16):1841-1845.
[15] Carta Cioffi;Stephane Campidelli;Fulvio G.Brunetti;Moreno Meneghetti;Maurizio Prato.Functionalisation of carbon nanohorns[J].Chemical communications,200620(20):2129-2131.
[16] Georgakilas V;Bourlinos A;Gournis D;Tsoufis T;Trapalis C;Mateo-Alonso A;Prato M.Multipurpose organically modified carbon nanotubes: From functionalization to nanotube composites[J].Journal of the American Chemical Society,200827(27):8733-8740.
[17] 马文石;周俊文;林晓丹.乙醇胺功能化石墨烯的制备与表征[J].化学学报,2011(12):1463-1468.
[18] Sasha Stankovich;Richard D. Finer;SonBinh T. Nguyen.Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon: An International Journal Sponsored by the American Carbon Society,200615(15):3342-3347.
[19] Mukesh Kumar;Kuldeep Singh;Sundeep K. Dhawan.Synthesis and characterization of covalently-grafted graphene-polyaniline nanocomposites and its use in a supercapacitor[J].Chemical engineering journal,2013:397-405.
[20] Jeon, I.-Y.;Choi, H.-J.;Jung, S.-M.;Seo, J.-M.;Kim, M.-J.;Dai, L.;Baek, J.-B..Large-scale production of edge-selectively functionalized graphene nanoplatelets via ball milling and their use as metal-free electrocatalysts for oxygen reduction reaction[J].Journal of the American Chemical Society,20134(4):1386-1393.
[21] Sun, Z.;Kohama, S.-I.;Zhang, Z.;Lomeda, J.R.;Tour, J.M..Soluble graphene through edge-selective functionalization[J].Nano Research,20102(2):117-125.
[22] Ming Fang;Kaigang Wang;Hongbin Lu.Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200938(38):7098-7105.
[23] Potts, J.R.;Dreyer, D.R.;Bielawski, C.W.;Ruoff, R.S..Graphene-based polymer nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,20111(1):5-25.
[24] Raquel Verdejo;M. Mar Bernal;Laura J. Romasanta.Graphene filled polymer nanocomposites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201110(10):3301-3310.
[25] Lee, SH;Dreyer, DR;An, JH;Velamakanni, A;Piner, RD;Park, S;Zhu, YW;Kim, SO;Bielawski, CW;Ruoff, RS.Polymer Brushes via Controlled, Surface-Initiated Atom Transfer Radical Polymerization (ATRP) from Graphene Oxide[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,20103(3):281-288.
[26] Yu, D.;Yang, Y.;Durstock, M.;Baek, J.-B.;Dai, L..Soluble P3HT-grafted graphene for efficient bilayer-heterojunction photovoltaic devices[J].ACS nano,201010(10):5633-5640.
[27] Henry Kuo Feng Cheng;Nanda Gopal Sahoo;Yan Pei Tan.Poly(vinyl alcohol) Nanocomposites Filled with Poly(vinyl alcohol)-Grafted Graphene Oxide[J].ACS applied materials & interfaces,20125(5):2387-2394.
[28] Konghua Liu;Shilong Chen;Yuanfang Luo;Demin Jia;Hong Gao;Guojun Hu;Lan Liu.Noncovalently functionalized pristine graphene/metal nanoparticle hybrid for conductive composites[J].Composites science and technology,2014Apr.9(Apr.9):1-7.
[29] Zhu, G.;Liu, Y.;Xu, Z.;Jiang, T.;Zhang, C.;Li, X.;Qi, G..Flexible magnetic nanoparticles-reduced graphene oxide composite membranes formed by self-assembly in solution[J].Chemphyschem: A European journal of chemical physics and physical chemistry,201011(11):2432-2437.
[30] De, S;King, PJ;Lotya, M;O'Neill, A;Doherty, EM;Hernandez, Y;Duesberg, GS;Coleman, JN.Flexible, Transparent, Conducting Films of Randomly Stacked Graphene from Surfactant-Stabilized, Oxide-Free Graphene Dispersions[J].Small,20103(3):458-464.
[31] Parviz, D.;Das, S.;Ahmed, H.S.T.;Irin, F.;Bhattacharia, S.;Green, M.J..Dispersions of non-covalently functionalized graphene with minimal stabilizer[J].ACS nano,201210(10):8857-8867.
[32] Feng Zhang;Bin Zheng;Jiali Zhang.Horseradish Peroxidase Immobilized on Graphene Oxide: Physical Properties and Applications in Phenolic Compound Removal[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201018(18):8469-8473.
[33] Bai, H;Li, C;Wang, XL;Shi, GQ.A pH-sensitive graphene oxide composite hydrogel[J].Chemical communications,201014(14):2376-2378.
[34] Zhang, Yong;Han, Haoxue;Wang, Nan;Zhang, Pengtu;Fu, Yifeng;Murugesan, Murali;Edwards, Michael;Jeppson, Kjell;Volz, Sebastian;Liu, Johan.Improved Heat Spreading Performance of Functionalized Graphene in Microelectronic Device Application[J].Advanced functional materials,201528(28):4430-4435.
[35] Li, Zheng;Liu, Zheng;Sun, Haiyan;Gao, Chao.Superstructured Assembly of Nanocarbons: Fullerenes, Nanotubes, and Graphene[J].Chemical Reviews,201515(15):7046-7117.
[36] Zhiqiang Niu;Lili Liu;Li Zhang;Qi Shao;Weiya Zhou;Xiaodong Chen;Sishen Xie.A Universal Strategy to Prepare Functional Porous Graphene Hybrid Architectures[J].Advanced Materials,201422(22):3681-3687.
[37] Xiaowei Yang;Junwu Zhu;Ling Qiu;Dan Li.Bioinspired Effective Prevention of Restacking in Multilayered Graphene Films: Towards the Next Generation of High-Performance Supercapacitors[J].Advanced Materials,201125(25):2833-2838.
[38] Bingna Zheng;Tieqi Huang;Liang Kou.Graphene fiber-based asymmetric micro-supercapacitors[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201425(25):9736-9743.
[39] Bong Gill Choi;Sung-Jin Chang;Hyun-Wook Kang.High performance of a solid-state flexible asymmetric supercapacitor based on graphene films[J].Nanoscale,201216(16):4983-4988.
[40] Ronghua Wang;Chaohe Xu;Jing Sun.Free-standing and binder-free lithium-ion electrodes based on robust layered assembly of graphene and C03O4 nanosheets[J].Nanoscale,201315(15):6960-6967.
[41] Wang, Z.-L.;Xu, D.;Wang, H.-G.;Wu, Z.;Zhang, X.-B..In situ fabrication of porous graphene electrodes for high-performance energy storage[J].ACS nano,20133(3):2422-2430.
[42] Xiangke Guo;Qi Fan;Liang Yu.Sandwich-like LiFePO4/graphene hybrid nanosheets: in situ catalytic graphitization and their high-rate performance for lithium ion batteries[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201338(38):11534-11538.
[43] Lamuel David;Romil Bhandavat;Gurpreet Singh.MoS_2/Graphene Composite Paper for Sodium-Ion Battery Electrodes[J].ACS nano,20142(2):1759-1770.
[44] Yanfei Xu;Zhibo Liu;Xiaoliang Zhang;Yan Wang;Jianguo Tian;Yi Huang;Yanfeng Ma;Xiaoyan Zhang;Yongsheng Chen.A Graphene Hybrid Material Covalently Functionalized With Porphyrin: Synthesis And Optical Limiting Property[J].Advanced Materials,200912(12):1275-1279.
[45] Zunfeng Liu;Qian Liu;Yi Huang;Yanfeng Ma;Shougen Yin;Xiaoyan Zhang;Wei Sun;Yongsheng Chen.Organic Photovoltaic Devices Based on a Novel Acceptor Material: Graphene[J].Advanced Materials,200820(20):3924-3930.
[46] Bae, S.;Kim, H.;Lee, Y.;Xu, X.;Park, J.-S.;Zheng, Y.;Balakrishnan, J.;Lei, T.;Ri Kim, H.;Song, Y.I.;Kim, Y.-J.;Kim, K.S.;?zyilmaz, B.;Ahn, J.-H.;Hong, B.H.;Iijima, S..Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature nanotechnology,20108(8):574-578.
[47] Supur, Mustafa;Kawashima, Yuki;Mase, Kentaro;Ohkubo, Kei;Hasobe, Taku;Fukuzumi, Shunichi.Broadband Light Harvesting and Fast Charge Separation in Ordered Self-Assemblies of Electron Donor-Acceptor-Functionalized Graphene Oxide Layers for Effective Solar Energy Conversion[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201524(24):13488-13495.
[48] Si Y;Samulski ET.Synthesis of water soluble graphene[J].Nano letters,20086(6):1679-1682.
[49] Chao Xu;Xin Wang;Junwu Zhu.Graphene—Metal Particle Nanocomposites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,200850(50):19841-19845.
[50] Wang, Min;Wu, Zhanpeng;Dai, Liming.Graphitic carbon nitrides supported by nitrogen-doped graphene as efficient metal-free electrocatalysts for oxygen reduction[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2015:16-20.
[51] Hassan Valizadeh;Ashkan Shomali;Saideh Nourshargh.Carboxyl and nitrite functionalized graphene quantum dots as a highly active reagent and catalyst for rapid diazotization reaction and synthesis of azo-dyes under solvent-free conditions[J].Dyes and Pigments,2015:522-528.
[52] Peng, Li;Zheng, Yaochen;Li, Jiachen;Jin, Yu;Gao, Chao.Monolithic Neat Graphene Oxide Aerogel for Efficient Catalysis of S -> O Acetyl Migration[J].ACS catalysis,20156(6):3387-3392.
[53] Sitko, R.;Turek, E.;Zawisza, B.;Malicka, E.;Talik, E.;Heimann, J.;Gagor, A.;Feist, B.;Wrzalik, R..Adsorption of divalent metal ions from aqueous solutions using graphene oxide[J].Dalton transactions: An international journal of inorganic chemistry,201316(16):5682-5689.
[54] Yari, Mohammad;Rajabi, Mostafa;Moradi, Omid;Yari, Ali;Asif, M.;Agarwal, Shilpi;Gupta, Vinod Kumar.Kinetics of the adsorption of Pb(II) ions from aqueous solutions by graphene oxide and thiol functionalized graphene oxide[J].Journal of Molecular Liquids,2015:50-57.
[55] Zhao, Zhiwei;Li, Jiaxing;Wen, Tao;Shen, Chongchong;Wang, Xiangke;Xu, Anwu.Surface functionalization graphene oxide by polydopamine for high affinity of radionuclides[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2015:258-266.
[56] Sun, Yubing;Yang, Shubin;Chen, Yue;Ding, Congcong;Cheng, Wencai;Wang, Xiangke.Adsorption and Desorption of U(VI) on Functionalized Graphene Oxides: A Combined Experimental and Theoretical Study[J].Environmental Science & Technology: ES&T,20157(7):4255-4262.
[57] Qi, Zhenhui;Bharate, Priya;Lai, Chian-Hui;Ziem, Benjamin;Boettcher, Christoph;Schulz, Andrea;Beckert, Fabian;Hatting, Benjamin;Muelhaupt, Rolf;Seeberger, Peter H.;Haag, Rainer.Multivalency at Interfaces: Supramolecular Carbohydrate-Functionalized Graphene Derivatives for Bacterial Capture, Release, and Disinfection[J].Nano letters,20159(9):6051-6057.
[58] Liu Z;Robinson JT;Sun XM;Dai HJ.PEGylated nanographene oxide for delivery of water-insoluble cancer drugs[J].Journal of the American Chemical Society,200833(33):10876-10877.
[59] Agustin G. Crevillen;Martin Pumera;M. Cristina Gonzalez;Alberto Escarpa.The preferential electrocatalytic behaviour of graphite and multiwalled carbon nanotubes on enediol groups and their analytical implications in real domains[J].The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry,20094(4):657-662.
[60] Choi, B.G.;Park, H.;Park, T.J.;Yang, M.H.;Kim, J.S.;Jang, S.-Y.;Heo, N.S.;Lee, S.Y.;Kong, J.;Hong, W.H..Solution chemistry of self-assembled graphene nanohybrids for high-performance flexible biosensors[J].ACS nano,20105(5):2910-2918.
[61] Su, Pi-Guey;Lu, Zhang-Mao.Flexibility and electrical and humidity-sensing properties of diamine-functionalized graphene oxide films[J].Sensors and Actuators, B. Chemical,2015:157-163.
[62] Yang, Linlin;Li, Xi;Yan, Songling;Wang, Mengmeng;Liu, Peng;Dong, Yulin;Zhang, Chaocan.Single-walled carbon nanotubes-carboxyl-functionalized graphene oxide-based electrochemical DNA biosensor for thermolabile hemolysin gene detection[J].Analytical methods,201512(12):5303-5310.
[63] Xue, Qiong;Liu, Zhiguang;Guo, Yujing;Guo, Shaojun.Cyclodextrin functionalized graphene-gold nanoparticle hybrids with strong supramolecular capability for electrochemical thrombin aptasensor[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2015:429-436.
[64] Pandey, P.A.;Wilson, N.R.;Covington, J.A..Pd-doped reduced graphene oxide sensing films for H2 detection[J].Sensors and Actuators, B. Chemical,2013:478-487.
[65] Stefano Prezioso;Francesco Perrozzi;Luca Giancaterini.Graphene Oxide as a Practical Solution to High Sensitivity Gas Sensing[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201320(20):10683-10690.
[66] Tran Quang Trung;Subramanian Ramasundaram;Seok Won Hong;Nae-Eung Lee.Flexible and Transparent Nanocomposite of Reduced Graphene Oxide and P(VDF-TrFE) Copolymer for High Thermal Responsivity in a Field-Effect Transistor[J].Advanced functional materials,201422(22):3438-3445.
[67] Jiajie Liang;Yan Wang;Yi Huang.Electromagnetic interference shielding of graphene/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,20093(3):922-925.
[68] Kim, Jeong Yun;Grossman, Jeffrey C..High-Efficiency Thermoelectrics with Functionalized Graphene[J].Nano letters,20155(5):2830-2835.
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