Ni2P纳米材料的可控合成及催化性能研究进展

材料导报, 2014, 28(17): 15-35. doi: 10.11896/j.issn.1005-023X.2014.17.003

Ni2P纳米材料的可控合成及催化性能研究进展

潘原 ^1, , 贾蓉蓉 ^2, , 李景锋 ^3, , 柳云骐 ^4, , 刘晨光 ^5,

1.中国石油大学重质油国家重点实验室CNPC催化重点实验室,青岛,266580

2.中国石油大学重质油国家重点实验室CNPC催化重点实验室,青岛,266580

3.中国石油大学重质油国家重点实验室CNPC催化重点实验室,青岛,266580

4.中国石油大学重质油国家重点实验室CNPC催化重点实验室,青岛,266580

5.中国石油大学重质油国家重点实验室CNPC催化重点实验室,青岛,266580

基金项目: 国家973项目(2010CB226905) 国家自然科学基金(21006128,U1162203)

关键词： Ni2P , 纳米材料 , 可控合成 , 催化性能 , 加氢 , 脱氢

Research Progress on Controllable Synthesis and Catalytic Performance of Ni2 P Nanomaterials

Keywords： Ni2P , nanomaterials , controllable synthesis , catalytic performance , hydrogenation , dehydrogenation

Ni2P纳米材料特殊的结构使其在催化领域显示出优异的活性和稳定性.作为催化材料,Ni2P的催化性能主要依赖于其结构、形貌及尺寸大小,实现Ni2P纳米材料的可控合成将是催化材料领域研究的热点.综述了Ni2P纳米材料的控制合成方法、合成机理及其在催化性能方面的研究进展,讨论了Ni2P纳米材料的应用前景,并从电子结构层次对Ni2P催化性能做了定性解释.Ni2P结构中由于P原子的掺入使得“d空穴”增多,费米能级附近的态密度增加,表现出类贵金属的特性,具有很好的催化性能.Ni2P纳米材料的催化脱氢性能将是继加氢性能之后又一个崭新的应用领域.

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