近年来,超级电容器以其优异的性能引起了研究者的广泛兴趣.其中以石墨烯为基质的电极材料占研究的绝大部分,同时质子化的聚苯胺也是一种高比电容的电极材料,将石墨烯与聚苯胺复合,利用二者的协同作用可以有效提高电容器的性能.主要介绍了二者的复合方式及复合材料的电容性能,总结了石墨烯/聚苯胺电极材料电容器的研究进展,最后对该领域的发展进行了展望.
参考文献
[1] | 方静 .超级电容器用聚苯胺纳米纤维的制备、改性和电容特性研究[D].中南大学,2012. |
[2] | Li Li Zhang;Rui Zhou;X. S. Zhao .Graphene-based materials as supercapacitor electrodes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(29):5983-5992. |
[3] | 刘玉荣.碳材料在超级电容器中的应用[M].北京:国防工业出版社,2013 |
[4] | Kroto H W et al.Smalley,Buckminsterfullerence[J].NATURE,1985,318:162. |
[5] | Lijima S .Helical microtubules of graphitic carbon[J].NATURE,1991,354(7):56. |
[6] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666. |
[7] | Xia, JL;Chen, F;Li, JH;Tao, NJ .Measurement of the quantum capacitance of graphene[J].Nature nanotechnology,2009(8):505-509. |
[8] | Stoller MD;Park SJ;Zhu YW;An JH;Ruoff RS .Graphene-Based Ultracapacitors[J].Nano letters,2008(10):3498-3502. |
[9] | Li D;Muller MB;Gilje S;Kaner RB;Wallace GG .Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,2008(2):101-105. |
[10] | Yongchao Si;Edward T. Samulski .Exfoliated Graphene Separated by Platinum Nanoparticles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(21):6792-6797. |
[11] | Yan Wang;Zhiqiang Shi;Yi Huang .Supercapacitor Devices Based on Graphene Materials[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(30):13103-13107. |
[12] | Hualan Wang;Qingli Hao;Xujie Yang;Lude Lu;Xin Wang .Graphene oxide doped polyaniline for supercapacitors[J].Electrochemistry communications,2009(6):1158-1161. |
[13] | Basnayaka P A;Ram M K;Stefanakos E K et al.Supercapacitors based on graphene polyaniline derivative nanocomposite electrode materials[J].Electrochimica Acta,2013,92:376. |
[14] | Jim Yan;Tong Wei;Bo Shao .Preparation of a graphene nanosheet/polyaniline composite with high specific capacitance[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(2):487-493. |
[15] | Jing Li;Huaqing Xie;Yang Li;Jie Liu;Zhuxin Li .Electrochemical properties of graphene nanosheets/polyaniline nanofibers composites as electrode for supercapacitors[J].JOURNAL OF POWER SOURCES,2011(24):10775-10781. |
[16] | Basavaraja C;Kim W J;Thinh P X et al.Electrical and magnetic properties of polyaniline-2-naphthalene sulfonic acid/gold nanoparticle reduced graphite oxide composites[J].Materials Letters,2012,77:41. |
[17] | Sawangphruk M;Suksomboon M;Kongsupornsak K et al.High-performance supercapacitors based on silver nanoparticle-polyaniline-graphene nanocomposites coated on flexible carbon fiber paper[J].J Mater Chem A,2013,34(1):9630. |
[18] | Wang Q;Yan J;Fan Z et al.Mesoporous polyaniline film on ultra-thin graphene sheets for high performance super capacitors[J].Journal of Power Sources,2014,247:197. |
[19] | Xiao-Miao Feng;Rui-Mei Li;Yan-Wen Ma;Run-Feng Chen;Nai-En Shi;Qu-Li Fan;Wei Huang .One-Step Electrochemical Synthesis of Graphene/ Polyaniline Composite Film and Its Applications[J].Advanced functional materials,2011(15):2989-2996. |
[20] | Liwen Hu;Jiguo Tu;Shuqiang Jiao .In situ electrochemical polymerization of a nanorod-PANI-Graphene composite in a reverse micelle electrolyte and its application in a supercapacitor[J].Physical chemistry chemical physics: PCCP,2012(45):15652-15656. |
[21] | Gao Z;Yang W;Wang J et al.Electrochemical synthesis of layer by layer reduced graphene oxide sheets/polyaniline nanofibers composite and its electrochemical performance[J].Electrochimica Acta,2013,91:185. |
[22] | Chen F;Liu P;Zhao Q .Well defined graphene/poyaniline flake composites for high performance supercapacitors[J].Electrochimica Acta,2012,76:62. |
[23] | Marappan Sathish;Satoshi Mitani;Takaaki Tomai .MnO2 assisted oxidative polymerization of aniline on graphene sheets: Superior nanocomposite electrodes for electrochemical supercapacitors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(40):16216-16222. |
[24] | Wu, Q.;Xu, Y.;Yao, Z.;Liu, A.;Shi, G. .Supercapacitors based on flexible graphene/polyaniline nanofiber composite films[J].ACS nano,2010(4):1963-1970. |
[25] | Yan Liu;Ruijie Deng;Zan Wang .Carboxyl-functionalized graphene oxide-polyaniline composite as a promising supercapacitor material[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(27):13619-13624. |
[26] | Kumar, N.A.;Choi, H.-J.;Shin, Y.R.;Chang, D.W.;Dai, L.;Baek, J.-B. .Polyaniline-grafted reduced graphene oxide for efficient electrochemical supercapacitors[J].ACS nano,2012(2):1715-1723. |
[27] | Liu Jianhua;An Junwei;Zhou Yecheng .Preparation of an Amide Group-Connected Graphene-Polyaniline Nanofiber Hybrid and Its Application in Supercapacitors[J].ACS applied materials & interfaces,2012(6):2870-2876. |
[28] | Junwei An;Jianhua Liu;Yecheng Zhou .Polyaniline-Grafted Graphene Hybrid with Amide Groups and Its Use in Supercapacitors[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2012(37):19699-19708. |
[29] | Ki-Seok Kim;Soo-Jin Park .Synthesis of carbon-coated graphene electrodes and their electrochemical performance[J].Electrochimica Acta,2011(18):6547-6553. |
[30] | Xiaomiao Feng;Zhenzhen Yan;Ningna Chen .Synthesis of a graphene/polyaniline/MCM-41 nanocomposite and its application as a supercapacitor[J].New Journal of Chemistry,2013(7):2203-2209. |
[31] | Xiong P;Huang H;Wang X .Design and synthesis of ternary cobalt ferrite/graphene/polyaniline hierarchical nanocomposites for high performance super capacitors[J].Journal of Power Sources,2014,245:937. |
[32] | Belanger D.;Ren X. .Characterization and Long-Term Performance of Polyaniline-Based Electrochemical Capacitors[J].Journal of the Electrochemical Society,2000(8):2923-2929. |
[33] | Pei-Jan Hung;Kuo-Hsin Chang;Ying-Feng Lee;Chi-Chang Hu;Kuo-Min Lin .Ideal asymmetric supercapacitors consisting of polyaniline nanofibers and graphene nanosheets with proper complementary potential windows[J].Electrochimica Acta,2010(20):6015-6021. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%