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采用共沉淀法制备了Mg/Al水滑石,研究了不同Mg/Al物质的量比、材料用量、不同pH条件下Mg/Al水滑石吸附除磷的动力学特征,从而对吸附速率的控制过程进行分析.结果表明水滑石对磷的吸附能较好地符合准二级动力学方程、Elovich动力学方程和内扩散模型.n(Mg)/n(Al) =3是水滑石最理想配比,水滑石投加量越大,外扩散过程越慢;一定范围内pH的升高能促进水滑石对磷吸附速率和吸附容量的提升.

参考文献

[1] Chengjin Cao,Binghui Zheng,Zhenlou Chen,Minsheng Huang,Jialei Zhang.Eutrophication and algal blooms in channel type reservoirs: A novel enclosure experiment by changing light intensity[J].环境科学学报(英文版),2011(10):1660-1670.
[2] Maher W.;Woo L. .Procedures for the storage and digestion of natural waters for the determination of filterable reactive phosphorus, total filterable phosphorus and total phosphorus [Review][J].Analytica chimica acta,1998(1/2):5-47.
[3] 罗世田,毛艳丽.水体富营养化的危害及综合防治对策[J].平顶山师专学报,2003(05):46-48.
[4] Xiao L L;Ma W et al.The influence of ferric iron in calcined nano-Mg/Al hydrotalcite on adsorption of Cr (Ⅵ) from aqueous solution[J].Journal of Hazardous Materials,2011,186:690.
[5] Li, YJ;Gao, BY;Wu, T;Chen, WS;Li, X;Wang, BA .Adsorption kinetics for removal of thiocyanate from aqueous solution by calcined hydrotalcite[J].Colloids and Surfaces. A, Physicochemical and Engineering Aspects,2008(1/2):38-43.
[6] Yang Y Q;Gao N Y et al.Adsorption of perchlorate from aqueous solution by the calcination product of Mg/(Al-Fe) hydrotalcite-like compounds[J].Journal of Hazardous Materials,2012,209-210:318.
[7] Kuzawa K;Jung YJ;Kiso Y;Yamada T;Nagai M;Lee TG .Phosphate removal and recovery with a synthetic hydrotalcite as an adsorbent[J].Chemosphere: Environmental toxicology and risk assessment,2006(1):45-52.
[8] Pavlovic I;Barriga C et al.Adsorption of acidic pesticides 2,4-D,clopyralid and picloram on calcined hydrotalcite[J].Applied Clay Seience,2005,30:125.
[9] Wang Z D;Yin P et al.Adsorption kinetics,thermodynamics and isotherm of Hg (Ⅱ) from aqueous solutions using buckwheat hulls from Jiaodong of China[J].Food Chemistry,2013,136:1508.
[10] 张增强,孟昭福,张一平.对Elovich方程的再认识[J].土壤通报,2000(05):208-209,212.
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