以铜作为基底的化学气相沉积法(CVD)是目前制备石墨烯的重要方法和手段.简单介绍了石墨烯的几种主要制备方法,突出化学气相沉积法能够有效制备出大规模可控高质量的石墨烯,并阐述了铜基底上化学气相沉积石墨烯的生长机理,主要从基底材料、不同的工艺条件以及石墨烯转移技术出发评述了化学气相沉积法制备石墨烯的研究进展,指出由铜网基底材料替代铜箔基底的良好应用前景,最后展望了铜基底化学气相沉积石墨烯的发展方向.
参考文献
| [1] | Novoselov K S .Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666. |
| [2] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
| [3] | 朱龙秀,李英芝,赵昕,张清华.电化学法制备石墨烯及其导电特性[J].高等学校化学学报,2012(08):1804-1808. |
| [4] | Novoselov KS;Jiang Z;Zhang Y;Morozov SV;Stormer HL;Zeitler U;Maan JC;Boebinger GS;Kim P;Geim AK .Room-temperature quantum Hall effect in graphene.[J].Science,2007(5817):1379-0. |
| [5] | Novoselov K S et al.Two-dimensional gas of massless Drac fermions in graphene[J].NATURE,2005,438(7065):197. |
| [6] | Britnell L et al.Field-effect tunneling transistor based on vertical graphene heterostructures[J].SCIENCE,2012,335(6071):947. |
| [7] | Yan Wang;Zhiqiang Shi;Yi Huang .Supercapacitor Devices Based on Graphene Materials[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(30):13103-13107. |
| [8] | 史永胜,李雪红,宁青菊.石墨烯的制备及研究现状[J].电子元件与材料,2010(08):70-73. |
| [9] | 王霖,田林海,尉国栋,高凤梅,郑金桔,杨为佑.石墨烯外延生长及其器件应用研究进展[J].无机材料学报,2011(10):1009-1019. |
| [10] | 徐秀娟,秦金贵,李振.石墨烯研究进展[J].化学进展,2009(12):2559-2567. |
| [11] | Berger C .Epitaxial grapheme[J].Solid State communications,2007,143(1-2):92. |
| [12] | Sun Z et al.Growth of graphene from solid carbon sources[J].NATURE,2010,468(7323):549. |
| [13] | Reina A;Jia XT;Ho J;Nezich D;Son HB;Bulovic V;Dresselhaus MS;Kong J .Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition[J].Nano letters,2009(1):30-35. |
| [14] | Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong .Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,2009(7230):706-710. |
| [15] | Na Liu;Fang Luo;Haoxi Wu;Yinghui Liu;Chao Zhang;Ji Chen .One-Step Ionic-Liquid-Assisted Electrochemical Synthesis of Ionic-Liquid-Functionalized Graphene Sheets Directly from Graphite[J].Advanced functional materials,2008(10):1518-1525. |
| [16] | 张玮,满卫东,涂昕,林晓棋.衬底对 CVD生长石墨烯的影响研究[J].真空与低温,2013(04):195-202,213. |
| [17] | Li, XS;Cai, WW;Colombo, L;Ruoff, RS .Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling[J].Nano letters,2009(12):4268-4272. |
| [18] | 常全鸿 .化学气相沉积(CVD)生长高质量的石墨烯及其性能的研究[D].上海师范大学,2012. |
| [19] | 马秀芳,孙科举,李微雪.金属衬底上石墨烯生长机理研究进展[J].科学通报,2012(12):987-994. |
| [20] | Levendorf, MP;Ruiz-Vargas, CS;Garg, S;Park, J .Transfer-Free Batch Fabrication of Single Layer Graphene Transistors[J].Nano letters,2009(12):4479-4483. |
| [21] | 张艳锋,高腾,张玉,刘忠范.金属衬底上石墨烯的控制生长和微观形貌的STM表征[J].物理化学学报,2012(10):2456-2464. |
| [22] | Gao, L.;Guest, J.R.;Guisinger, N.P. .Epitaxial graphene on Cu(111)[J].Nano letters,2010(9):3512-3516. |
| [23] | 葛雯,吕斌.Cu箔衬底上石墨烯纳米结构制备[J].材料科学与工程学报,2013(04):489-494. |
| [24] | Wood, J.D.;Schmucker, S.W.;Lyons, A.S.;Pop, E.;Lyding, J.W. .Effects of polycrystalline Cu substrate on graphene growth by chemical vapor deposition[J].Nano letters,2011(11):4547-4554. |
| [25] | Ishihara M K Y et al.Direct evidence of advantage of Cu (111) for graphene synthesis by using Raman mapping and electron backscatter diffraction[J].Materials Letters,2011,65:2864. |
| [26] | Zhao, L.;Rim, K.T.;Zhou, H.;He, R.;Heinz, T.F.;Pinczuk, A.;Flynn, G.W.;Pasupathy, A.N. .Influence of copper crystal surface on the CVD growth of large area monolayer graphene[J].Solid State Communications,2011(7):509-513. |
| [27] | Hu B et al.Epitaxial growth of large-area single-layer graphene over Cu(111)/sapphire by atmospheric pressure CVD[J].CARBON,2012,50:57. |
| [28] | Luo Z T et al.Effect of substrate roughness and feedstock concentration on growth of wafer-scale graphene at atmospheric pressure[J].CHEMISTRY OF MATERIALS,2011,23:1441. |
| [29] | Han, G.H.;Güne?, F.;Bae, J.J.;Kim, E.S.;Chae, S.J.;Shin, H.-J.;Choi, J.-Y.;Pribat, D.;Lee, Y.H. .Influence of copper morphology in forming nucleation seeds for graphene growth[J].Nano letters,2011(10):4144-4148. |
| [30] | Murari Regmi;Matthew F. Chisholm;Gyula Eres .The effect of growth parameters on the intrinsic properties of large-area single layer graphene grown by chemical vapor deposition on Cu[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(1):134-141. |
| [31] | Kim, H.;Mattevi, C.;Calvo, M.R.;Oberg, J.C.;Artiglia, L.;Agnoli, S.;Hirjibehedin, C.F.;Chhowalla, M.;Saiz, E. .Activation energy paths for graphene nucleation and growth on Cu[J].ACS nano,2012(4):3614-3623. |
| [32] | 王文荣。,周玉修,李铁,王跃林,谢晓明.高质量大面积石墨烯的化学气相沉积制备方法研究[J].物理学报,2012(03):510-516. |
| [33] | Wu, P.;Wang, C.;Fan, X.;Zhang, W.;Zhai, X.;Zeng, C.;Li, Z.;Yang, J.;Hou, J. .Low-temperature growth of graphene by chemical vapor deposition using solid and liquid carbon sources[J].ACS nano,2011(4):3385-3390. |
| [34] | Wassei, J.K.;Mecklenburg, M.;Torres, J.A.;Fowler, J.D.;Regan, B.C.;Kaner, R.B.;Weiller, B.H. .Chemical vapor deposition of graphene on copper from methane, ethane and propane: Evidence for bilayer selectivity[J].Small,2012(9):1415-1422. |
| [35] | Hye Jin Park;Jannik Meyer;Siegmar Roth .Growth and properties of few-layer graphene prepared by chemical vapor deposition[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(4):1088-1094. |
| [36] | 师小萍,于广辉,王斌,吴渊文.Cu上石墨烯的化学气相沉积法生长研究[J].功能材料与器件学报,2011(05):486-490. |
| [37] | 任文才,高力波,马来鹏,成会明.石墨烯的化学气相沉积法制备[J].新型炭材料,2011(01):71-80. |
| [38] | 黄曼,郭云龙,武斌,刘云圻,付朝阳,王帅.化学气相沉积法合成石墨烯的转移技术研究进展[J].化学通报（网络版）,2012(01):1-6. |
| [39] | 李兴鳌,王博琳,刘忠儒.石墨烯的制备、表征与特性研究进展[J].材料导报,2012(01):61-65. |
| [40] | Li, XS;Zhu, YW;Cai, WW;Borysiak, M;Han, BY;Chen, D;Piner, RD;Colombo, L;Ruoff, RS .Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes[J].Nano letters,2009(12):4359-4363. |
| [41] | Lin, Y.-C.;Lu, C.-C.;Yeh, C.-H.;Jin, C.;Suenaga, K.;Chiu, P.-W. .Graphene annealing: How clean can it be?[J].Nano letters,2012(1):414-419. |
| [42] | Lee, W.H.;Park, J.;Sim, S.H.;Lim, S.;Kim, K.S.;Hong, B.H.;Cho, K. .Surface-directed molecular assembly of pentacene on monolayer graphene for high-performance organic transistors[J].Journal of the American Chemical Society,2011(12):4447-4454. |
| [43] | Wang, Y.;Zheng, Y.;Xu, X.;Dubuisson, E.;Bao, Q.;Lu, J.;Loh, K.P. .Electrochemical delamination of CVD-grown graphene film: Toward the recyclable use of copper catalyst[J].ACS nano,2011(12):9927-9933. |
| [44] | 闫景东 等.一种激光辅助无损转移化学气相沉积石墨烯的方法:中国,103132047[P].中国,103132047,2013-06-05. |
| [45] | Ismach, A.;Druzgalski, C.;Penwell, S.;Schwartzberg, A.;Zheng, M.;Javey, A.;Bokor, J.;Zhang, Y. .Direct chemical vapor deposition of graphene on dielectric surfaces[J].Nano letters,2010(5):1542-1548. |
| [46] | Su, C.-Y.;Lu, A.-Y.;Wu, C.-Y.;Li, Y.-T.;Liu, K.-K.;Zhang, W.;Lin, S.-Y.;Juang, Z.-Y.;Zhong, Y.-L.;Chen, F.-R.;Li, L.-J. .Direct formation of wafer scale graphene thin layers on insulating substrates by chemical vapor deposition[J].Nano letters,2011(9):3612-3616. |
| [47] | Li X et al.Multifunctional graphene woven fabrics[J].Scientific Reports,2012,2:1. |
| [48] | Yushi Z.Graphene woven fabric as high-resolution sensing element of contact-lens tonometer[A].Hyatt Regency,San Francisco,2014:624. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%