中空 ZnO 微球具有密度低、比表面积大、渗透性好、光电性能优异等特点,受到科研工作者的广泛关注。综述了中空 ZnO 微球的制备方法及其应用领域,首先,主要阐述了硬模板法、软模板法、自模板法和无模板法4大类制备方法的研究进展,其次,介绍了中空 ZnO 微球在光催化、太阳能电池、气体传感器及生物医药等领域的应用进展,最后,对中空 ZnO 结构材料的发展前景进行了展望。
ZnO hollow spheres with nanometer to micrometer dimensions exhibit low density,large specific surface area,good surface permeability and excellent photoelectric properties,so they have attracted a great deal of at-tentions.The preparation methods and application fields of ZnO hollow microspheres are reviewed.Firstly,the pro-gress of the preparation methods of ZnO hollow microspheres,such as hard-template method,soft-template method, self-template method and template-free method,is summarized.Secondly,the application research and development of ZnO hollow microspheres in photocatalysis,solar cells,gas sensors,biological medicine and other areas are intro-duced.Finally,perspectives on the future research and development of ZnO hollow microspheres are discussed.
参考文献
[1] | Wang Y L;Cai L;Xia Y N .Monodisperse spherical colloids particles[J].Advanced Materials,2005,17:473. |
[2] | Peng Q;Dong Y J;Li Y D .Zn/Se semiconductor hollow microspheres[J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2003,32:3027. |
[3] | Zhu Y F;Fan D H;Shen W Z .Template-free synthesis of temperature[J].J Phys Chem C,2007,111:18629. |
[4] | Lai X Y;Li J;Dong Z H et al.General synthesis and gas-crospheres[J].Angewandte Chemie,2011,123:2790. |
[5] | Lai X Y;Halpert J E;Wang D .Recent advances in micro-/nano-structured hollow spheres for energy applications:From simple to complex systems[J].Energy Environ Sci,2012,5:5604. |
[6] | Jamil Elias;Claude Levy-Clement;Mikhael Bechelany;Johann Michler;Guillaume-Yangshu Wang;Zhao Wang;Laetitia Philippe .Hollow Urchin-like ZnO thin Films by Electrochemical Deposition[J].Advanced Materials,2010(14):1607-1612. |
[7] | Caruso F;Caruso R A;M?hwald H .Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating[J].SCIENCE,1998,282(5391):1111. |
[8] | Ashoka S;Kumarappa V T;Gujjarahalli T C .Simple non-spheres[J].PHYSICA E,2012,44:1346. |
[9] | Zeng H B;Cai W P;Liu P S et al.ZnO-based hollow na-noparticles by selective etching:Elimination and reconstruc-tion of metal semiconductor interface,improvement of blue emission and photocatalysis[J].ACS Nano,2008,2(8):1661. |
[10] | Wang X;Liao M Y;Zhong Y T et al.ZnO hollow spheres catalysts and photodetectors[J].Advanced Materials,2012,24:3421. |
[11] | Shen G Z;Bando Y;Lee C J .Synthesis and evolution of no-process[J].Journal of Physical Chemistry B,2005,109:10578. |
[12] | Polymer-controlled Crystallization Of Dumbbell-like Zno Hollow Architectures[J].Materials Letters,2009(13/14):1217-1220. |
[13] | Yang G Z;Cui H;Wang C X .A strategy to synthesize hol-low micro/nanospheres with tunable shell thickness[J].CHEMPHYSCHEM,2014,15:374. |
[14] | Wang Y Q;Wang G Z;Wang H Q et al.One-pot synthe-spheres[J].Chemistry Communications,2008,11:6555. |
[15] | Du N;Zhang H;Chen J et al.Metal oxide and sulfide hol-low spheres:Layer-by-layer synthesis and their application in lithium-ion battery[J].Journal of Physical Chemistry B,2008,112:14836. |
[16] | Deng Z W;Chen M;Gu G X et al.A facile method to fab-ricate ZnO hollow spheres and their photocatalytic property[J].Journal of Physical Chemistry B,2008,112:16. |
[17] | Wang X;Peng H;Yuan F L et al.Preparation and charac-materials using colloidal carbon spheres as templates[J].J terization of ZnO hollow spheres and ZnO-carbon composite Phys Chem C,2007,111:6706. |
[18] | Matsuyama K;Mishima K;Kato T et al.Preparation of hollow ZnO microspheres using poly(methyl methacrylate)as a template with supercritical CO2-ethanol solution[J].Industrial and Engineering Chemistry Research,2010,49:8510. |
[19] | Ja J G;Yu X X .Hydrothermal synthesis and photocatalytic activity of zinc oxide hollow spheres[J].Environmental Science and Technology,2008,42:4902. |
[20] | Cheng S;Yan D;Chen J T et al.Soft-template synthesis and characterization of ZnO2 and ZnO hollow spheres[J].J Phys Chem C,2009,113:13630. |
[21] | Yan Y X;Liu Q;Wang J et al.Synthesis of ZnO hollow microspheres via an in-situ gas growth method[J].Powder Techn,2012,232:134. |
[22] | Carolin S;Ralf T;Christian N et al.Synthesis of small hollow ZnO nanospheres from the gas phase[J].Partical Partical Systems Characterization,2013,30:434. |
[23] | Cheng LH;Zheng LY;Li GR;Yin QR;Jiang KL .Synthesis of sealed sponge ZnO nanospheres through a novel NH3-evaporation method[J].Nanotechnology,2008(7):75605-1-75605-6-0. |
[24] | Cong HP;Yu SH .Hybrid ZnO-Dye hollow spheres with new optical properties from a self-assembly process based on Evans blue dye and cetyltrimethylammonium bromide[J].Advanced functional materials,2007(11):1814-1820. |
[25] | Zhou, H;Fan, TX;Zhang, D .Hydrothermal synthesis of ZnO hollow spheres using spherobacterium as biotemplates[J].Microporous and Mesoporous Materials,2007(1/3):322-327. |
[26] | Zhang, H.;Xu, C.;Sheng, P.;Chen, Y.;Yu, L.;Li, Q..Synthesis of ZnO hollow spheres through a bacterial template method and their gas sensing properties[J].Sensors and Actuators, B. Chemical,2013:99-103. |
[27] | Zhu Y F;Fan D H;Shen W Z .Template-free synthesis of zinc oxide hollow microspheres in aqueous solution at low temperature[J].J Phys Chem C,2007,111:18629. |
[28] | Nirmalya T;Rafiq A;Jeong H S et al.Time-dependent control of hole-opening degree of porous ZnO hollow micro-sphere[J].Inorganic Chemistry,2012,51:1104. |
[29] | Chen ZT;Gao L .A new route toward ZnO hollow spheres by a base-erosion mechanism[J].Crystal growth & design,2008(2):460-464. |
[30] | Yan C L;Xue D F .Room temperature fabrication of hollow ZnS and ZnO architectures by a sacrificial template route[J].Journal of Physical Chemistry B,2006,110:7102. |
[31] | Lo, S.-S.;Huang, D. .Morphological variation and Raman spectroscopy of Zno hollow microspheres prepared by a chemical colloidal process[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(9):6762-6766. |
[32] | Wang WW;Zhu YJ;Yang LX .ZnO-SnO2 hollow spheres and hierarchical nanosheets: Hydrothermal preparation, formation mechanism, and photocatalytic properties[J].Advanced functional materials,2007(1):59-64. |
[33] | Pradhan D;Leung K T .Template-free single-step electro-chemical synthesis of ZnO hollow nanospheres:Self-assem-bly of hollow nanospheres from nanoparticles[J].Journal of Materials Chemistry,2009,19:4902. |
[34] | Music' S;?aric' A .Formation of hollow ZnO particles by simple hydrolysis of zinc acetylacetonate[J].CERAMICS INTERNATIONAL,2012,38:6047. |
[35] | 杨合情,李丽,宋玉哲,贺萍,杨文玉,马军虎,陈迪春,房喻.ZnO纳米片自组装空心微球的无模板水热法制备与发光性质[J].中国科学B辑,2007(05):417-425. |
[36] | Li Q Y;Wang C L;Ju M L et al.Polyoxometalate-assisted their photocatalytic properties[J].Microp Mesop Mater, electrochemical deposition of hollow ZnO nano-spheres and,2011,138:132. |
[37] | Chen M;Ye C Y;Zhou S X et al.Recent advances in ap-vices[J].Advanced Materials,2013,25:5343. |
[38] | Zhu Q Y;Chen J;Zhu Q et al.Monodispersed hollow mi-crosphere of ZnO mesoporous nanopieces:Preparation,growth mechanism and photocatalytic performance[J].Ma-ter Res Bull,2010,45:2024. |
[39] | Zhang C;Yin L W;Zhang L Y et al.Preparation and pho-spheres[J].Materials Letters,2012,67:303. |
[40] | Chen X B;Liu L;Yu P Y et al.Increasing solar absorption nanocrystals for photocatalysis with black hydrogenated titanium dioxide[J].SCIENCE,2011,331:746. |
[41] | Zheng J;Jiang Z Y;Qin K et al.Shape-controlled fabrica-properties[J].Journal of Solid State Chemistry,2009,182:115. |
[42] | Wang Y X;Li X Y;Lu G et al.Synthesis and photocata-ferent morphology[J].Materials Letters,2008,62:2359. |
[43] | Liu G;Li G S;Qiu X Q et al.Synthesisi of ZnO/titanale sible light irradiation[J].Journal of Alloys and Compounds,2009,481:492. |
[44] | Mukesh A;Smrati G;Andrij P et al.A facile approach to fabrication of ZnO-TiO2 hollow spheres[J].CHEMISTRY OF MATERIALS,2009,21:5343. |
[45] | Zhu C Q;Lu B G;Su Q et al.A simple method for the performance photocatalyst[J].Nanoscale,2012,4:3060. |
[46] | He C X;Lei B X;Wang Y F et al.Sonochemical prepara-sitized solar cells[J].Chemistry-A European Journal,2010,16:8757. |
[47] | Chou T P;Zhang Q;Fryxell G E et al.Hierarchically hanced energy conversion efficiency[J].Advanced Materials,2007,19:2588. |
[48] | Chou T P;Zhang Q F;Cao G Z .Effects of dye loading con-dye-sensitized solar cells[J].J Phys Chem C,2007,111 |
[49] | Masaru Saito;Shinobu Fujihara .Large photocurrent gene-ration in dye-sensitized ZnO solar cells[J].Energy Environ Sci,2008,1:280. |
[50] | Nafiseh Memarian;Isabella Concina;Antonio Braga .Hierarchically Assembled ZnO Nanocrystallites for High-Efficiency Dye-Sensitized Solar Cells[J].Angewandte Chemie,2011(51):12321-12325. |
[51] | 王湘艳,王治强,田汉民,张继远,于涛,于振涛,邹志刚.分级微纳结构ZnO空心球的制备及其光电转换性能[J].无机化学学报,2009(11):1893-1897. |
[52] | Dong Z H;Lai X Y;Halpert J E et al.Accurate control of multishelled ZnO hollow microspheres for dye-sensitized so-lar cells with high efficiency[J].Advanced Materials,2012,24:1046. |
[53] | Lu X H;Zheng Y Z;Bi S Q et al.Multidimensional ZnO architecture for dye-sensitized solar cells with high-efficiency up to 7.35%[J].Adv Energy Mater,2014,4(9):1301802. |
[54] | Yin M L;Liu S Z .Preparation of ZnO hollow spheres with different surface roughness and their enhanced gas sensing property[J].Sensors Actuators B:Chem,2014,197:58. |
[55] | Tian Y;Li J C;Xiong H et al.Controlled synthesis of ZnO hollow microspheres via precursor-template method and its gas sensing property[J].Applied Surface Sinence,2012,258:8431. |
[56] | Rao J;Yu A;Shao C L et al.Construction of hollow and mesoporous ZnO microsphere:A facile synthesis and sen-sing property[J].ACS Appl Mater Interfaces,2012,4:5346. |
[57] | Zhang, J;Wang, SR;Wang, Y;Xu, MJ;Xia, HJ;Zhang, SM;Huang, WP;Guo, XZ;Wu, SH .ZnO hollow spheres: Preparation, characterization, and gas sensing properties[J].Sensors and Actuators, B. Chemical,2009(2):411-417. |
[58] | Li X W;Sun P;Yang T L et al.Template-free microwave-assisted synthesis of ZnO hollow microspheres and their ap-plication in gas sensing[J].Cryst Eng Comm,2013,15:2949. |
[59] | Ge L;Jing X Y;Wang J et al.Trisodium citrate assisted route and their application as gas sensor[J].J Mater Chem, synthesis of ZnO hollow spheres via a facile precipitation,2011,21:10750. |
[60] | Wang L L;Lou Z;Fei T et al.Templating synthesis of their enhanced gas sensing properties[J].J Mater Chem, ZnO hollow nanospheres loaded with Au nanoparticles and,2012,22:4767. |
[61] | Zhao M G;Zhou Y;Cai B et al.The application of porous high sensitive biosensors[J].CERAMICS INTERNATIONAL,2013,39:9319. |
[62] | Tan L C;Liu J;Zhou W H et al.A novel thermal and pH hybrid nanoparticles[J].MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS,2014,45:524. |
[63] | Yuan Q;Hein S;Misra RD .New generation of chitosan-encapsulated ZnO quantum dots loaded with drug: synthesis, characterization and in vitro drug delivery response.[J].Acta biomaterialia,2010(7):2732-2739. |
[64] | Chang F Q;Huang X B;Wei H et al.Intrinsically fluores-polyphosphazene material:Synthesis and application in drug cent hollow spheres based on organic-inorganic hybrid release[J].Materials Letters,2014,125:128. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%