纳米 TiO2光催化材料在环境土壤修复中的应用研究进展?

材料导报, 2015, (11): 49-54. doi: 10.11896/j.issn.1005-023X.2015.011.008

纳米 TiO2光催化材料在环境土壤修复中的应用研究进展?

张文通 ^1, , 陈勇 ^2, , 陈超 ^3, , 陈昌兵 ^4, , 刘欣伟 ^5,

1.后勤工程学院国防建筑规划与环境工程系,重庆,401311

2.后勤工程学院国防建筑规划与环境工程系,重庆,401311

3.后勤工程学院国防建筑规划与环境工程系,重庆,401311

4.后勤工程学院国防建筑规划与环境工程系,重庆,401311

5.后勤工程学院国防建筑规划与环境工程系,重庆,401311

基金项目: 重庆市自然科学基金(CSTC,2008BB7139)

关键词：纳米 TiO2 光催化材料 , 土壤污染 , 有机物 , 重金属离子

Utilizing Nano-TiO2 as Photocatalytic Materials for Environmental Soil Remediation

Keywords： nano-TiO2 photocatalytic materials , soil pollution , organic compounds , heavy metal ions

近年来对土壤污染的综合治理和修复已经成为环保领域的一个研究热点，光催化技术修复污染土壤是一种操作简便、费用低廉、无二次污染和具有广阔发展前景的新兴技术。分析了光催化技术修复污染土壤的原理，并综述了近年来纳米 TiO2光催化材料在土壤有机物污染物(农药、芳香族类和石油类等)的降解以及重金属离子(Ag+、Cr6+等)的光催化还原研究进展，并提出了未来的发展方向和建议。

In recent years,the comprehensive management of soil pollution and remediation has become a re-search hotspot in the field of environmental protection.Photocatalytic technology which is used to remedy polluted soil is an emerging technology with easy operating,low cost,no secondary pollution and has broad development prospects. The principles of remedying soil pollution by photocatalytic technology are analyzed,and research progresses of photo-catalytic materials in soil organic pollutants (pesticides,aromatic and petroleum etc.)degradation and heavy metal ions (Ag+ ,Cr6 + etc.)reduction photocatalyzed by nano-TiO2 are reviewed.Besides,development direction and sug-ession for the future are also pointed out.

参考文献

[1]	刘然,薛向欣,杨合,姜涛,董学文.光催化材料在环保领域中的应用进展[J].能源环境保护,2004(04):5-8,17.
[2]	谢磊,林正迎.二氧化钛光催化净化环境研究进展[J].广州化工,2014(11):38-41.
[3]	江海军,张瑾,奚丽荷,朱忠其,柳清菊.TiO2半导体光催化剂在污水处理中的研究进展[J].材料导报,2007(z1):54-57,63.
[4]	吴亚西,陈烈贤.光催化氧化分解空气挥发性有机污染物的研究[J].卫生研究,2002(05):384-385.
[5]	陈勇,陈鹏,陈超,谷科成.La、Fe共掺杂TiO 2/活性炭纤维的制备及其光催化性能[J].功能材料,2014(03):03135-03140.
[6]	陈勇,谷锦,陈鹏,张静静,陈超.La、Fe共掺杂TiO2/膨润土的制备及其光催化性能[J].功能材料,2013(20):3003-3006,3011.
[7]	艾毅宁,陈勇,周德平,谷锦.La掺杂TiO2/有机改性膨润土对TNT弹药废水的光催化降解性能研究[J].四川环境,2013(05):31-37.
[8]	李慧,陈勇,查忠勇,晏华,胡庆林.纳米TiO2催化剂催化降解含酚废水的动力学[J].后勤工程学院学报,2008(02):71-74.
[9]	Fujishima A;Rao T N;Tryk D A .Titanium dioxide photo-catalysis[J].Photochem Rev,2000,1:1.
[10]	Farrauto R;Heck R M .Environmental catalysis into the 21st century[J].Catalysis Today,2000,55:179.
[11]	Mills A;Lehuntes S .An overview of semiconductor photo-catalysis[J].Photochemistry and Photobiology A:Chemistry,1997,108:1.
[12]	韩世同,习海玲,史瑞雪,付贤智,王绪绪.半导体光催化研究进展与展望[J].化学物理学报,2003(05):339-349.
[13]	付宏祥,吕功煊,李新勇.重金属离子的光催化还原研究进展[J].感光科学与光化学,1995(04):325.
[14]	陈丹;郎朗;季宇彬.TiO2 光催化降解农药的研究进展[A].北京:中国环境科学出版社,2013:3543.
[15]	陈建秋,王志良,王铎,高从堦.纳米TiO2光催化降解乐果溶液的影响因素研究[J].中国给水排水,2007(19):98-102.
[16]	何娟,张宗祥,丁金美.土壤中有机磷农药的测定及光催化降解的研究[J].四川环境,2014(4):58-61.
[17]	汪东,王敬国,慕康国.TiO2对几种农药在土壤中光降解的催化作用[J].环境污染与防治,2010(08):10-13.
[18]	汪东,王敬国,慕康国.苯线磷在表面土壤中的光催化降解研究[J].华南农业大学学报,2010(03):36-39.
[19]	徐悦华,古国榜,李新军.光催化降解甲胺磷影响因素的研究[J].华南理工大学学报(自然科学版),2001(05):68-71.
[20]	Dai K;Peng TY;Chen H;Zhang RX;Zhangi YX .Photocatalytic degradation and mineralization of commercial methamidophos in aqueous Titania suspension[J].Environmental Science & Technology: ES&T,2008(5):1505-1510.
[21]	岳永德,王如意,汤锋,刘坤.毒死蜱在土壤中的光催化降解[J].安徽农业大学学报,2002(01):1-3.
[22]	Zhao X;Quan M;Zhao HM;Chen S;Zhao YZ;Chen JW .Different effects of humic substances on photodegradation of p,p'-DDT on soil surfaces in the presence of TiO2 under UV and visible light[J].Journal of Photochemistry and Photobiology, A. Chemistry,2004(2/3):177-183.
[23]	Quan X;Zhao X;Chen S et al.Enhancement of P,P′DDT photodegradation on soil surfaces using TiO2 induced by UV-light[J].CHEMOSPHERE,2005,60:266.
[24]	潘淑颖,高宝玉,岳钦艳,辛佳,于洪艳,冯秀娟.光催化降解表土层中DDT的影响因素研究[J].中国农学通报,2008(10):515-520.
[25]	潘淑颖,徐保民,索秋魁,孙长青,郭青,殷碧秋.纳米TiO2与过渡金属协同作用光催化氧化土壤渗出液中DDT的研究[J].安徽农业科学,2006(21):5601-5602.
[26]	潘淑颖 .土壤中有机氯农药DDT原位降解研究[D].山东大学,2009.
[27]	刘汝英,孙长春,潘淑颖,孙长青,郭青.土壤渗出液中DDT的光催化氧化降解反应条件研究[J].山东农业科学,2006(05):37-39.
[28]	叶新强,鲁岩,张恒.除草剂阿特拉津的使用与危害[J].环境科学与管理,2006(08):95-97.
[29]	Higarashi M M;Jardim W E .Remediation of pesticide con-taminated soil using TiO2 mediated by solar light[J].Catalysis Today,2002,76(2-4):201.
[30]	Davezza M;Fabbri D;Pramauro E et al.Photocatalytic degradation of bentazone in soil washing wastes containing alkylpolyoxyethylene surfactants[J].CHEMOSPHERE,2012,86:335.
[31]	Tang H;Berger H;Schmid P E et al.Photoluminescence in TiO2 anatase single crystals[J].Solid State communications,1993,87(9):847.
[32]	罗东卫.掺杂型TiO2光催化剂对土壤中有机污染物的分解[J].工业催化,2014(01):76-80.
[33]	熊佰炼 .表面活性剂增溶微生物—光催化联合降解污染土壤中的硫丹[D].西南大学,2013.
[34]	周武艺,曹庆云,庞永洪,陈凤钟,杨卓鸿.光催化技术修复污染土壤的研究进展[J].材料导报,2009(z1):75-78.
[35]	Zhang Lihong;Li Peijun;Gong Zongqiang et al.Photocataly-tic degradation of polycyclic aromatic hydrocarbons on soil surfaces using TiO2 under UV light[J].Journal of Hazardous Materials,2008,158:478.
[36]	张利红,李培军,徐成斌,陈忠林,李雪梅.纳米TiO2催化光降解土壤中PAHs效果[J].辽宁工程技术大学学报（自然科学版）,2010(01):162-165.
[37]	张利红,李培军,李雪梅,陈忠林.纳米TiO2催化下表层土壤中BaP的紫外光降解[J].农业环境科学学报,2009(04):649-652.
[38]	张利红,陈忠林,徐成斌,李雪梅,李培军.太阳光照射土壤中多环芳烃化合物（PAHs）光催化降解动力学[J].环境化学,2010(03):486-490.
[39]	张利红,李雪梅,陈忠林,李培军.紫外辐射强度对土壤中PAHs催化降解的影响[J].农业环境科学学报,2008(05):1711-1715.
[40]	Investigation on the photocatalytic degradation of pyrene on soil surfaces using nanometer anatase TiO_2 under UV irradiation[J].Journal of hazardous materials,2010(1/3):859.
[41]	Gu Jiali;Dong Dianbo;Kong Lingxue .Photocatalytic degra-dation of phenanthrene on soil surfaces in the presence of pnanometer anatase TiO2 under UV-light[J].Journal of Environmental Sciences,2012,24(12):2122.
[42]	Aguer JP;Richard C .TRANSFORMATION OF FENURON INDUCED BY PHOTOCHEMICAL EXCITATION OF HUMIC ACIDS[J].Pesticide Science,1996(2):151-155.
[43]	Krauss M;Wilcke W .Photochemical oxidation of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in soils - a tool to assess their degradability?[J].Journal of plant nutrition and soil science,2002(2):173-178.
[44]	Huang Qingdong;Chia-Swee Hong .TiO2 photocatalytic deg-radation of PCBs in soil-water systems containing fluoro sur-factant[J].CHEMOSPHERE,2000,41(3):871.
[45]	肖宁 .二氯苯污染土壤修复技术初步研究[D].山西大学,2013.
[46]	JINGXIAN WANG;SHUO CHEN;XIE QUAN;HUIMIN ZHAO;YAZHI ZHAO .Enhanced Photodegradation of PNP on Soil Surface under UV Irradiation with TiO_2[J].Soil & Sediment Contamination,2007(4):413-421.
[47]	王敬贤 .土壤中部分酚类污染物的光化学行为研究[D].大连理工大学,2006.
[48]	Zhang Yaxin;Wu Huayong;Zhang Jing .Enhanced photo-degradation of pentachlorophenol by single and mixed catio-nic and nonionic surfactants[J].Journal of Hazardous Materials,2012,221-222:92.
[49]	Zheng Shan;Jiang Wenjun;Cai Yong .Adsorption and pho-tocatalytic degradation of aromatic organoarsenic compounds in TiO2 suspension[J].Catalysis Today,2014,224:83.
[50]	Maurizio D'Auria;Lucia Emanuele;Rocco Racioppi;Vincenzina Velluzzi .Photochemical Degradation Of Crude Oil: Comparison Between Direct Irradiation, Photocatalysis, And Photocatalysis On Zeolite[J].Journal of Hazardous Materials,2009(1):32-38.
[51]	Otidene Rossiter Sá da Rocha .Oil sludge treatment by pho-tocatalysis applying black and white light[J].CHEMICAL ENGINEERING JOURNAL,2010,157:80.
[52]	徐荣 .改性漂浮型光催化材料修复有机污染环境的研究[D].扬州大学,2013.
[53]	张元,许婧文,梁巍,薛爱芳,陈浩.磺胺二甲嘧啶在土壤中的吸附和光催化降解作用[J].湖北农业科学,2011(20):4163-4165.
[54]	Maroga V et al.Assessment of the efficiency of photocataly-sis on tetracycline biodegradation[J].Journal of Hazardous Materials,2012,209-210:35.
[55]	ZHAO Xu;QUAN Xie;CHEN Shuo .Photocatalytic remediation of gamma-hexachlorocyclohexane contaminated soils using TiO2 and montmorillonite composite photocatalyst[J].Journal of Environmental Sciences,2007(3):358-361.
[56]	鲍长利,周波,刘淑霞,蒋引姗,方送生.沸石负载TiO2的制备及其对农药敌敌畏的光降解性能[J].应用化学,2003(12):1222-1224.
[57]	K. T. Ranjit;H. Cohen .Lanthanide oxide-doped titanium dioxide: Effective photocatalysts for the degradation of organic pollutants[J].Journal of Materials Science,1999(21):5273-5280.
[58]	李静谊,斯琴高娃,刘丽娜.TiO2/膨润土光催化降解有机污染物[J].物理化学学报,2007(01):16-20.
[59]	LinsebigIer A L;Lu G;Yates J T .Photocatalysis on TiO2 surfaces:Principles,mechanisms and selected results[J].Chem Rev,1,995,95:735.
[60]	李川,古国榜,柳松.TiO2光催化处理废水中贵重金属的研究进展[J].环境污染治理技术与设备,2003(11):6-11.
[61]	蒋文新,张天胜.纳米二氧化钛光催化降解无机污染物的研究进展[J].天津科技大学学报,2004(02):14-17.
[62]	刘守新,孙承林.金属离子的光催化去除研究进展[J].化学通报,2004(12):898-903.
[63]	Gonghu Li;Shannon Ciston;Zoran V.Saponjic .Synthesizing mixed-phase TiO2 nanocomposites using a hydrothermal method for photo-oxidation and photoreduction applications[J].Journal of Catalysis,2008(1):105-110.
[64]	林龙利 .TiO2纳米管光催化同步去除水体中重金属和有机物的协同作用及其机理[D].广东工业大学,2012.
[65]	Gao Y M;Lee W;Trehan R et al.Improvement of photoca-talytic activity of titanium(Ⅳ)oxide by dispersion of Au on TiO2[J].Materials Research Bulletin,1991,26(12):1247.
[66]	Krishnan Rajeshwar;C. R. Chenthamarakshan;Scott Goeringer;Miljana Djukic .Titania-based heterogeneous photocatalysis. Materials, mechanistic issues, and implications for environmental remediation[J].Pure and Applied Chemistry,2001(12):1849-1860.
[67]	于兵川,吴洪特,张万忠.光催化纳米材料在环境保护中的应用[J].石油化工,2005(05):491-495.
[68]	Wang X L;Pehkonen S O;Ray A K .Removal of aqueous Cr(Ⅵ)by a combination of photocatalytic reduction and copre-cipitation[J].Industrial and Engineering Chemistry Research,2004,43:1665.
[69]	杨俊,徐仁扣.纳米TiO2协助下As（Ⅲ）在可变电荷土壤中的光催化氧化和吸附[J].环境科学,2008(11):3219-3224.
[70]	刘义新;孟丽;华齐帅.利用纳米二氧化钛原位固定土壤重金属的可行性探讨[A].,2008:1104.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网