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  4. 复合钙钛矿太阳能电池电荷传输层材料研究进展

材料导报, 2015, 29(5): 1-7. doi: 10.11896/j.issn.1005-023X.2015.05.001

复合钙钛矿太阳能电池电荷传输层材料研究进展

陈建清 1, , 杨东辉 2, , 江静华 3, , 马爱斌 4, , 宋丹 5, , Chaoying Ni 6, , Michael Z Hu 7,

1.河海大学力学与材料学院,南京,210098

2.河海大学力学与材料学院,南京,210098

3.河海大学力学与材料学院,南京,210098

4.河海大学力学与材料学院,南京,210098

5.河海大学力学与材料学院,南京,210098

6.Department of Materials Science and Engineering, University of Delaware,Newark, DE 19716

7.Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6181

关键词： 有机无机复合钙钛矿 , 太阳能电池 , 光电转换效率 , 电子传输层材料(ETM) , 空穴传输层材料(HTM)

A Review on Charge Carriers Transport Materials Used in Organometal Halide Perovskite-based Solar Cells

Keywords： organometal perovskite , solar cell , power conversion efficiency , electron transport materials , hole transport materials

有机无机复合钙钛矿太阳能电池因具有适合的载流子扩散长度而成为备受关注的有望获得高效率的光伏器件.复合钙钛矿材料本身不含贵金属元素,可以采用液相法或物理气相法低温制备,成本低廉,但目前应用最多的电子传输层材料TiO2需400～500℃煅烧,与柔性基底及低温制备技术适应性差;空穴传输层材料SpiroOMeTAD合成工艺复杂,价格高昂,限制了复合钙钛矿太阳能电池的开发应用.开发和研究导电性好、成本低、稳定性好的电子和空穴传输层材料是复合钙钛矿太阳能电池研究中的一个非常重要的方面.综述了复合钙钛矿太阳能电池中电荷传输层材料的研究进展及发展方向.电子传输层材料方面通过对TiO2的改性以及与石墨烯的复合,采用ZnO、石墨烯或PCBM作为电子传输层材料,以与柔性基底及低温制备技术相适应.空穴传输层材料方面,采用其它低成本、导电性高的有机p型半导体替代spiro-OMeTAD;采用无机空穴传输层材料以避免有机空穴传榆层材料的老化问题,提高电池的长期稳定性;利用复合钙钛矿材料兼作吸收层与空穴传输层,制备无空穴传输层材料结构电池以降低成本,提高稳定性.

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