以油胺为还原剂和稳定剂,通过晶种生长法顺序还原HAuCl4·xH2O和H2PtCl6·6H2O,成功制备了Au-Pt树枝状杂聚体纳米颗粒.通过对Pt在Au颗粒表面沉积过程的研究,探讨了杂聚体结构的形成机理.研究发现油胺还原得到的Au纳米颗粒表面是由不同晶面组成的,随后还原的Pt会选择性地沉积到Au[111]表面处成核生长,形成Pt的纳米岛结构,当有足量的Pt前体时,Pt会在纳米岛的表面继续生长形成附着于Au颗粒表面的树枝状结构,研究表明树枝状Pt形貌的形成与油胺的使用有着重要关系.
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