对稀土铕离子掺杂聚合物基荧光材料的制备方法进行了分析归纳,介绍了稀土离子配位数及离子簇的存在对发光性能的影响,同时列举了聚合物基荧光复合材料在农业、生物医学、防伪鉴别等方面的应用.针对实践应用对物理性能的要求,分析提出了传统方法制得的材料在应用中存在的问题并对具有综合特性的方法进行了展望.总结认为针对不同应用制备镶嵌荧光物质的前体作为复合材料两相的桥梁这一框架方法,具有极大的应用前景.
参考文献
| [1] | Roel Decadt;Kristof Van Hecke;Diederik Depla et al.Synthesis,crystal structures,and luminescence properties of carboxylate based rare-earth coordination polymers[J].Inorganic Chemistry,2012,51:11623. |
| [2] | 刘光华.稀土材料及其应用技术[M].北京:化学工业出版社,2005:25. |
| [3] | 张技术,葛明桥.光谱指纹纤维的防伪特性[J].纺织学报,2013(04):12-16. |
| [4] | Liu GK;Jensen MP;Almond PM .Systematic behavior of charge-transfer transitions and energy level variation in soft donor complexes of the trivalent lanthanides[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2006(6):2081-2088. |
| [5] | Milena Marinovic-Cincovic;Zeljka Antic;Radenka Krsmanovic et al.Thermal and luminescence properties of nanoGd2O3:Eu3+/PMMA composite[J].JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS,2009,1(01):54. |
| [6] | Bem, D.B.;Luyt, A.S.;Dejene, B.F.;Swart, H.C. .Temperature-dependence of the structural and afterglow luminance properties of polymer/SrAl _xO _y:Eu ~(2+),Dy ~(3+) composites[J].Physica, B. Condensed Matter,2012(10):1556-1560. |
| [7] | Xie Li;Xingping Zhou;Xiaqin Wang .In-Situ Polymerization Approach for Preparation of Rare Earth Fluoride Phosphors Coated with PAA[J].Journal of nanoscience and nanotechnology,2011(11):9973-9979. |
| [8] | HAN Jing,LI Jie.Sensitization and Intra-molecular Energy Transfer of Eu3+ by Tb3+ in Eu-Tb Binuclear Complexes/PMMA[J].武汉理工大学学报（材料科学版）（英文版）,2011(03):398-402. |
| [9] | Back, M.;Boffelli, M.;Massari, A.;Marin, R.;Enrichi, F.;Riello, P. .Energy transfer between Tb~(3+) and Eu~(3+) in co-doped Y_2O_3 nanocrystals prepared by Pechini method[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2013(7):1753-1-1753-14. |
| [10] | 孙海珠,杨柏.原位法制备无机纳米粒子/聚合物复合材料[J].中国科学E辑,2009(02):193-205. |
| [11] | 陈少杰,张教强,郭银明.纳米复合材料制备方法的研究进展[J].玻璃钢/复合材料,2008(05):41-46. |
| [12] | Fu LS.;Zhang HJ.;Wang SB.;Yang KY.;Ni JZ.;Meng QG. .In situ synthesis of terbium-benzoic acid complex in sol-gel derived silica by a two-step sol-gel method[J].The journal of physics and chemistry of solids,2000(11):1877-1881. |
| [13] | Shen Jie;Li Zhiqiang;Cheng Rui et al.Eu3+-doped NaGdF4 nanocrystal down-converting layer for efficient dye-sensitized solar cells[J].Appl Mater Interf,2014,6(20):17454. |
| [14] | Mo Zunli;Niu Guiping;Chen Hong et al.Synthesis and characterization of hyperbranched poly(amine-ester)/lanthanum/montmorillonite nanocomposites[J].Materials Letters,2008,62(10-11):1743. |
| [15] | Wang Xianwen;Chen Fuping;Chen Liang et al.Crystal structure and fluorescence properties of a new ternary binuclear complex:Sm2 (C3H3O2)6 (phen)2[J].Z NaturforschB,2007,62(10):1267. |
| [16] | Ueba Y;Zhu K J;Banks E et al.Rare earth metal containing polymer.5.Synthesis,characterization,and fluorescence properties of Eu3+ polymer complex containing carboxylbenzoyl and cardoxylnaphthoyl legends[J].J Polym Sci Part A:Polym Chem Ed,1982,20:1271. |
| [17] | 胡显奎,刘振兴,陈竹筠,李添娣.离聚体结构的研究现状和进展[J].合成树脂及塑料,2000(02):49-52. |
| [18] | 陈晓波,李美仙,N.SAWANOBORI,曾哲,聂玉昕.掺Er3+氟氧化物玻璃陶瓷的直接上转换敏化发光[J].物理学报,2000(12):2482-2487. |
| [19] | 王军强;董汉国;纪国才.温室番茄培育采用生态转光膜实验[J].中国农技推广,2004(04):33. |
| [20] | 陆国军,俞刚翔.光转膜在大棚葡萄上应用试验总结[J].现代农业科技,2007(09):20. |
| [21] | Shen J;Sun LD;Yan CH .Luminescent rare earth nanomaterials for bioprobe applications[J].Dalton transactions: An international journal of inorganic chemistry,2008(42):5687-5697. |
| [22] | 周新木,陈慧勤,谈宏宇.稀土高分子荧光材料研究进展[J].化学试剂,2007(09):527-531,565. |
| [23] | Zhou Shanyong;Zheng Wei;Chen Zhuo et al.Dissolutionenhanced luminescent bioassay based on inorganic lanthanide nanoparticles[J].Angewandte Chem Int Ed,2014,53(46):12498. |
| [24] | 李文连.生命科学研究中的稀土发光--稀土荧光探针及荧光标记在生物大分子研究中的应用[J].物理,1991(02):89. |
| [25] | Akisada K;Noguchi Y;Isobe T .Preparation of composite PMMA microbeads hybridized with fluorescent YVO4:Bi3+,Eu3+ nanoparticles[J].Material Science and Engineering,2011,18(08):082014. |
| [26] | 田君,尹敬群.稀土紫外荧光防伪油墨的制备[J].精细化工,1999(02):31-32. |
| [27] | Wang LY;Li YD .Na(Y1.5Na0.5)F-6 single-crystal nanorods as multicolor luminescent materials[J].Nano letters,2006(8):1645-1649. |
| [28] | 孟婕,孙诚,王建清,孙文顺,郝晓秀,牟信妮.铕掺杂配合物的合成及其在荧光防伪油墨中的应用研究[J].中国印刷与包装研究,2010(z1):385-388. |
| [29] | Zhao Miao;Xi Peng;Gu Xiaohua et al.Synthesis,characterization and fluorescence properties of a novel rare earth complex for anti-counterfeiting material[J].Journal of Rare Earths,2010,28:75. |
| [30] | 刘术亮,黄渊源,韩玉梅,龙云泽,孙彬.离心静电纺丝法制备有序、交叉以及绞线结构的荧光纳米纤维[J].青岛大学学报（自然科学版）,2013(01):44-49. |
| [31] | Shyam Sarkar;Armita Dash;Venkataramanan Mahalingam .Strong Stokes and Upconversion Luminescence from Ultrasmall Ln~(3+)-Doped BiF_3 (Ln = Eu~(3+), Yb~(3+)/Er~(3+)) Nanoparticles Confined in a Polymer Matrix[J].Chemistry, an Asian journal,2014(2):447-451. |
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