以丙酮为溶剂,分别采用丙酸(AS)、磷酸(H3PO4)以及2-丙烯酰胺基-2-甲基丙磺酸(AMPS)中和甲基丙烯酸-N,N-二甲基胺基乙酯(DMAEMA),然后减压蒸馏去除溶剂,合成了3种可聚合离子液体DMAEMA-AS/H3PO/AMPS,采用差示扫描量热(DSC)表征其玻璃化温度(Tg).以过硫酸铵(APS)为引发剂,以N,N-亚甲基双丙烯酰胺(MBAM)为交联剂,甲基丙烯酸-2-羟基乙酯(HEMA)分别与3种可聚合离子液体在水溶液中交联共聚,合成了Poly(HEMA-co-DMAEMA-AS/H3 PO4/AMPS)凝胶,采用重量法研究了3种凝胶的溶胀行为.结果表明,DMAEMA-AS/H3 PO4/AMPS的玻璃化温度分别为-61.9℃、76.2℃、-45.8℃,Poly(HEMA-co-DMAEMA-AS)和Poly(HEMA-co-DMAEMA-H3 PO4)凝胶可在水及多种有机溶剂中溶胀,而Poly(HEMA-co-DMAEMA-AMPS)凝胶在任何溶剂中均不溶胀,并初步探讨了产生这种现象的原因.
参考文献
[1] | 李雪辉,李榕,陈学伟,王芙蓉,王乐夫.碱性离子液体的研究进展[J].工业催化,2007(05):1-5. |
[2] | Makoto Ue;Masayuki Takeda;Akiko Toriumi .Application of Low-Viscosity Ionic Liquid to the Electrolyte of Double-Layer Capacitors[J].Journal of the Electrochemical Society,2003(4):A499-A502. |
[3] | Tao G H;He L;Sun N et al.New generation ionic liquids:Cations derived from amino acids[J].Chemistry Communications,2005,41:3562. |
[4] | Weingartner H .Understanding ionic liquids at the molecular level:Facts,problems,and controversies[J].Angew Chem Int Ed Engl,2008,47:654. |
[5] | 王仲妮,王洁莹,司友华,周武.咪唑类离子液体的研究进展[J].化学进展,2008(07):1057-1063. |
[6] | 应安国,叶伟东,刘泺,吴国锋,陈新志,钱胜,张秋萍.离子液体在有机合成中的应用研究进展[J].有机化学,2008(12):2081-2094. |
[7] | Chen W;Zhang Y;Zhu L et al.A concept of supported amino acid ionic liquids and their application in metal scavenging and heterogeneous catalysis[J].Journal of the American Chemical Society,2007,129:13879. |
[8] | Zhu H P;Yang F;Tang J et al.Bronsted acidic ionic liquid 1-methylimidazolium tetrafluoroborate:A green catalyst and recyclable medium for esterification[J].Green Chemistry,2003,5:38. |
[9] | Jiayin Yuan;Markus Antonietti .Poly(ionic liquid)s:Polymers expanding classical property profiles[J].POLYMER,2011,52:1469. |
[10] | Jiayin Yuana;David Mecerreyes;Markus Antonietti .Poly (ionic liquid)s:An update[J].Progress in Polymer Science,2013,38:1009. |
[11] | 朱丽丽,陈正国,罗川,张萌.离子液体功能高分子[J].化学进展,2008(07):1143-1150. |
[12] | Bideau J L;Viau L;Vioux A .Ionogels,ionic liquid based hybrid materials[J].CHEMICAL SOCIETY REVIEWS,2011,40:907. |
[13] | Hosseinzadeh F;Mahkam M;Galehassadi M .Synthesis and characterization of ionic liquid functionalized polymers for drug delivery of an anti-inflammatory drug[J].Des Monom Polym,2012,15(4):379. |
[14] | Jenny Bandomir;André Schulz;Satomi Taguchi et al.Synthesis and characterization of polymerized ionic liquids:Mechanical and thermal properties of a novel type of hydrogels[J].Macromolecular Chemistry and Physics,2014,215:716. |
[15] | 翁婷婷,郭建维,黎新明,崔英德,尹国强,张步宁.可聚合离子液体 AM PS-TEA 的合成及其交联共聚物对有机溶剂的吸收行为[J].广东工业大学学报,2013(04):33-38. |
[16] | 孙萍,黎新明.VMIM-Gly可聚合离子液体的合成及其与AAm交联共聚物凝胶的溶胀行为研究[J].仲恺农业工程学院学报,2013(03):27-31. |
[17] | Yang Xuejiao;Fang Yanxiong;Li Xinming et al.Synthesis of two AMPS-based polymerizable room temperature ionic liquids and swelling difference between their co-polymeric gels with HEMA[J].E-POLYMERS,2014,14(5):335. |
[18] | Weng T;Guo J;Li X et al.Synthesis of the polymerizable room temperature ionic liquid AMPS-TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide[J].Des Monom Polym,2014,17(2):140. |
[19] | Weng T;Guo J;Li X et al.Synthesis,chloramphenicol uptake,and in vitro release of poly(AMPS-TEA-Co-AAm) gels with affinity for both water and alcohols[J].Int J Polym Mater Polym Biomater,2014,63(2):73. |
[20] | Li Xinming;Cui Yingde;Lloyd W et al.Polymeric hydrogels for novel contact lens-based ophthalmic drug delivery systems:A review[J].Contact Lens Anterior Eye,2008,31(2):57. |
[21] | Li Xinming;Cui Yingde .Hydrogel-hydrogel composite the interfacial structure and interaction between water and polymer chains[J].Journal of Applied Polymer Science,2008,108:3713. |
[22] | Xinming Li;Xuejun Pan .Hydrogels Based on Hemicellulose and Lignin from Lignocellulose Biorefinery: A Mini-Review[J].Journal of Biobased Materials and Bioenergy,2010(4):289-297. |
[23] | Li Xinming;Cui Yingde .Ultraviolet-induced decomposition of acrylic acid-based superabsorbent hydrogels crosslinked with N,N-methylenebisacrylamide[J].Journal of Applied Polymer Science,2008,108:3435. |
[24] | 黎新明,崔英德.甲基丙烯酸羟乙酯与丙稀酰胺共聚特水凝胶的合成及氯霉素缓释性能研究[J].中国化学工程学报(英文版),2008(04):640-645. |
[25] | Buning Zhang;Yingde Cui;Guoqiang Yin .Synthesis and Swelling Properties of Protein-poly(acrylic acid-co-acrylamide) Superabsorbent Composite[J].Polymer Composites,2011(5):683-691. |
[26] | High-water-content mouldable hydrogels by mixing clay and a dendritic molecular binder[J].Nature,2010(Jan.21 TN.7279):339. |
[27] | Zhang Buning;Cui Yingde;Yin Guoqiang et al.Adsorption of copper (Ⅱ) and lead (Ⅱ) ions onto cottonseed proteinPAA hydrogel composite[J].Polym-Plast Techn Eng,2012,51(6):612. |
[28] | Vania Blasques Bueno;Ricardo Bentini;Luiz Henrique Catalani .Synthesis and swelling behavior of xanthan-based hydrogels[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2013(2):1091-1099. |
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