聚氧化乙烯(PEO)是聚合物电解质传统的基体材料,它最大的优势在于在不添加任何增塑剂的情况下,可以与锂盐形成稳定的络合物,但PEO易于结晶,使离子电导率降低.研究表明:采用共混、接枝、共聚、交联以及与无机物复合等方法对PEO进行改性,可以进一步提高此类聚合物电解质的性能.重点对PEO类聚合物基体的改性及其高性能固体聚合物电解质材料研究的新进展进行介绍,并对其研究前景做了展望.
参考文献
| [1] | Gorecki W.;Belorizky E.;Roux C.;Armand M.;Jeannin M..PHYSICAL PROPERTIES OF SOLID POLYMER ELECTROLYTE PEO(LITFSI) COMPLEXES[J].Journal of Physics. Condensed Matter,199534(34):6823-6832. |
| [2] | Meyer WH..Polymer electrolytes for lithium-ion batteries [Review][J].Advanced Materials,19986(6):439-448. |
| [3] | Tao Zheng;Qian Zhou;Qian Li;Liaoyun Zhang;Huayi Li;Yuan Lin.A new branched copolyether-based polymer electrolyte for lithium batteries[J].Solid state ionics,2014:9-13. |
| [4] | 陈伟;张以河.锂电池用PEO基固态聚合物电解质研究进展及应用[J].工程塑料应用,2010(6):89-92. |
| [5] | Raghavan Prasanth;Vanchiappan Aravindan;Madhavi Srinivasan.Novel polymer electrolyte based on cob-web electrospun multi component polymer blend of polyacrylonitrile/poly(methyl methacrylate)/polystyrene for lithium ion batteries-Preparation and electrochemical characterization[J].Journal of Power Sources,2012Mar.15(Mar.15):299-307. |
| [6] | Barteau, K.P.;Wolffs, M.;Lynd, N.A.;Fredrickson, G.H.;Kramer, E.J.;Hawker, C.J..Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries[J].Macromolecules,201322(22):8988-8994. |
| [7] | Yue-Jiao Li;Feng Wu;Hu-Ren Chao;Shi Chen.A new composite polymer electrolyte based on poly(ethyleneoxide)/polysiloxane/BMImTFSI/organomontmorillonite[J].中国化学快报（英文版）,2013(01):70-72. |
| [8] | N. Reddeppa;A.K. Sharma;V.V.R. Narasimha Rao;Wen Chen.Preparation and characterization of pure and KBr doped polymer blend (PVC/PEO) electrolyte thin films[J].Microelectronic engineering,2013Dec.(Dec.):57-62. |
| [9] | Sung-Il Lee;Martina Schomer;Huagen Peng.Correlations between Ion Conductivity and Polymer Dynamics in Hyperbranched Poly(ethylene oxide) Electrolytes for Lithium-Ion Batteries[J].Chemistry of Materials: A Publication of the American Chemistry Society,201111(11):2685-2688. |
| [10] | 骆伟新;刘煜平;杨树颜;刘治猛.新型梳状聚甲基丙烯酸酯固态聚合物电解质的制备及导电性能研究[J].高分子学报,2014(1):63-71. |
| [11] | 唐致远;王占良.PEO基聚合物电解质[J].高分子材料科学与工程,2003(2):48-51,56. |
| [12] | Jianying Ji;John Keen;Wei-Hong Zhong.Simultaneous improvement in ionic conductivity and mechanical properties of multi-functional block-copolymer modified solid polymer electrolytes for lithium ion batteries[J].Journal of Power Sources,201123(23):10163-10168. |
| [13] | Chiu CY;Hsu WH;Yen YJ;Kuo SW;Chang FC.Miscibility behavior and interaction mechanism of polymer electrolytes comprising LiClO4 and MPEG-block-PCL copolymers[J].Macromolecules,200515(15):6640-6647. |
| [14] | Choi, NS;Park, JK.A comparative study of coordination between host polymers and Li+ ions in UV-cured gel polymer electrolytes[J].Solid state ionics,200920/22(20/22):1204-1208. |
| [15] | Sun H.Y.;Takeda Y..Ferroelectric Materials as a Ceramic Filler in Solid Composite Polyethylene Oxide-Based Electrolytes[J].Journal of the Electrochemical Society,20007(7):2462-2467. |
| [16] | N. Angulakshmi;K. S. Nahm;Jijeesh R. Nair;C. Gerbaldi;R. Bongiovanni;N. Penazzi;A. Manuel Stephan.Cycling profile of MgAl_2O_4-incorporated composite electrolytes composed of PEO and LiPF_6 for lithium polymer batteries[J].Electrochimica Acta,2013:179-185. |
| [17] | N. Angulakhsmi;S. Thomas;Jijeesh R. Nair;R. Bongiovanni;C. Gerbaldi;A. Manuel Stephan.Cycling profile of innovative nanochitin-incorporated poly (ethylene oxide) based electrolytes for lithium batteries[J].Journal of Power Sources,2013Apr.15(Apr.15):294-299. |
| [18] | 席靖宇;邱新平;朱文涛;陈立泉.PEO-LiClO4-ZSM5复合聚合物电解质--IV.偏光显微镜研究[J].中国科学B辑,2005(6):478-483. |
| [19] | Yarjan Abdul Samad;Ali Asghar;Raed Hashaikeh.Electrospun cellulose/PEO fiber mats as a solid polymer electrolytes for Li ion batteries[J].Renewable energy,2013Aug.(Aug.):90-95. |
| [20] | Chakrabarti, A.;Juilfs, A.;Filler, R.;Mandal, B.K..Novel PEO-based dendronized polymers for lithium-ion batteries[J].Solid state ionics,201021/22(21/22):982-986. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%