二硫化钼(MoS2)具有类石墨烯层状结构、良好的光学性能和电子传输特性,在光催化、太阳能电池、光开关等领域具有广阔的应用前景,一直备受关注。综述了近5年MoS2纳米材料在光催化降解有机物和光催化水解制氢领域内的最新研究进展,分析了MoS2纳米材料在光催化应用中存在的主要问题与挑战,重点介绍了相关解决方法。最后展望了MoS2纳米材料在光催化应用中的发展方向和应用前景。
Molybdenum disulfide (MoS2 )with graphene-like layered structure has attracted wide attention in the fields of photocatalysis,solar cell,photoswitch,etc.due to its excellent optical and electron transport properties. In this paper,research progress of high-performance MoS2 photocatalytic materials in recent five years are reviewed, especially in the fields of photocatalyzed degradation of organic compounds and photocatalytic hydrogen production. The main problems and challenges of MoS2 photocatalysts in practical applications are also analyzed and emphasis is put on introducing relevent solutions.Finally,the developing direction and application prospects of MoS2 nanomate-rials in the field of photocatalysis are summarized.
参考文献
[1] | Guo, Jinxue;Li, Fenfen;Sun, Yanfang;Zhang, Xiao;Tang, Lin.Oxygen-incorporated MoS2 ultrathin nanosheets grown on graphene for efficient electrochemical hydrogen evolution[J].Journal of Power Sources,2015Sep.30(Sep.30):195-200. |
[2] | YuLin Min;GuangQiang He;QunJie Xu.Dual-functional MoS2 sheet-modified CdS branchlike heterostructures with enhanced photostability and photocatalytic activity[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20148(8):2578-2584. |
[3] | Lee, H.S.;Min, S.-W.;Chang, Y.-G.;Park, M.K.;Nam, T.;Kim, H.;Kim, J.H.;Ryu, S.;Im, S..MoS _2 nanosheet phototransistors with thickness-modulated optical energy gap[J].Nano letters,20127(7):3695-3700. |
[4] | Sheng, Beibei;Liu, Jinsong;Li, Ziquan;Wang, Menghui;Zhu, Kongjun;Qiu, Jinhao;Wang, Jing.Effects of excess sulfur source on the formation and photocatalytic properties of flower-like MoS2 spheres by hydrothermal synthesis[J].Materials Letters,2015Apr.1(Apr.1):153-156. |
[5] | Wen-chao Peng;Xiao-yan Li.Synthesis of MoS2/g-C3N4 as a solar light-responsive photocatalyst for organic degradation[J].Catalysis Communications,2014:63-67. |
[6] | Liu, Hui;Lv, Ting;Zhu, Chunkui;Su, Xing;Zhu, Zhenfeng.Efficient synthesis of MoS2 nanoparticles modified TiO2 nanobelts with enhanced visible-light-driven photocatalytic activity[J].Journal of molecular catalysis, A. Chemical,2015:136-142. |
[7] | Mang Niu;Daojian Cheng;Dapeng Cao.Understanding the Mechanism of Photocataiysis Enhancements in the Graphene-like Semiconductor Sheet/TiO2 Composites[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201411(11):5954-5960. |
[8] | Zhou, Gang;Xu, Xiaoyong;Yu, Jianyu;Feng, Bing;Zhang, Yu;Hu, Jingguo;Zhou, Yuxue.Vertically aligned MoS2/MoOx heterojunction nanosheets for enhanced visible-light photocatalytic activity and photostability[J].CrystEngComm,201438(38):9025-9032. |
[9] | Mianzeng Zhong;Zhongming Wei;Xiuqing Meng;Fengmin Wu;Jingbo Li.From MoS_2 Microspheres to α-MoO_3 Nanoplates: Growth Mechanism and Photocatalytic Activities[J].European journal of inorganic chemistry,201420(20):3245-3251. |
[10] | Li, Honglin;Yu, Ke;Lei, Xiang;Guo, Bangjun;Li, Chao;Fu, Hao;Zhu, Ziqiang.Synthesis of the MoS2@CuO heterogeneous structure with improved photocatalysis performance and H2O adsorption analysis[J].Dalton transactions: An international journal of inorganic chemistry,201522(22):10438-10447. |
[11] | Han, Weijia;Zang, Chen;Huang, Zongyu;Zhang, Han;Ren, Long;Qi, Xiang;Zhong, Jianxin.Enhanced photocatalytic activities of three-dimensional graphene-based aerogel embedding TiO2 nanoparticles and loading MoS2 nanosheets as Co-catalyst[J].International journal of hydrogen energy,201434(34):19502-19512. |
[12] | Hemamala I. Karunadasa;Elizabeth Montalvo;Yujie Sun;Marcin Majda;Jeffrey R. Long;Christopher J. Chang.A Molecular MoS_2 Edge Site Mimic for Catalytic Hydrogen Generation[J].Science,2012Feb.10 TN.6069(Feb.10 TN.6069):698-702. |
[13] | Jakob Kibsgaard;Zhebo Chen;Benjamin N. Reinecke.Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis[J].Nature materials,201211(11):963-969. |
[14] | Shixiong Min;Gongxuan Lu.Sites for High Efficient Photocatalytic Hydrogen Evolution on a Limited-Layered MoS2 Cocatalyst Confined on Graphene Sheets-The Role of Graphene[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201248(48):25415-25424. |
[15] | Tiantian Jia;Amy Kolpin;Chensheng Ma;Ruth Chau-Ting Chan;Wai-Ming Kwok;S. C. Edman Tsang.A graphene dispersed CdS-MoS2 nanocrystal ensemble for cooperative photocatalytic hydrogen production from water[J].Chemical communications,201410(10):1185-1188. |
[16] | Xiong, Jinhua;Liu, Yuhao;Wang, Dengke;Liang, Shijing;Wu, Weiming;Wu, Ling.An efficient cocatalyst of defect-decorated MoS2 ultrathin nanoplates for the promotion of photocatalytic hydrogen evolution over CdS nanocrystal[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201524(24):12631-12635. |
[17] | Lei Ge;Changcun Han;Xinlai Xiao;Lele Guo.Synthesis and characterization of composite visible light active photocatalysts MoS_2-g-C_3N_4 with enhanced hydrogen evolution activity[J].International journal of hydrogen energy,201317(17):6960-6969. |
[18] | Tian Yuming;Ge Lei;Wang Kaiyue.Synthesis of novel MoS_2/g-C_3N_4 heterojunction photocatalysts with enhanced hydrogen evolution activity[J].Materials Characterization,2014:70-73. |
[19] | Yu-Fei Zhao;Zhi-Yu Yang;Yu-Xia Zhang.Cu2O Decorated with Cocatalyst MoS2 for Solar Hydrogen Production with Enhanced Efficiency under Visible Light[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201426(26):14238-14245. |
[20] | Guo, Xin;Cao, Guo-lin;Ding, Fei;Li, Xinyuan;Zhen, Shuyu;Xue, Yi-fei;Yan, Yi-ming;Liu, Ting;Sun, Ke-ning.A bulky and flexible electrocatalyst for efficient hydrogen evolution based on the growth of MoS2 nanoparticles on carbon nanofiber foam[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20159(9):5041-5046. |
[21] | Xiang, Q.;Yu, J.;Jaroniec, M..Synergetic effect of MoS _2 and graphene as cocatalysts for enhanced photocatalytic H _2 production activity of TiO _2 nanoparticles[J].Journal of the American Chemical Society,201215(15):6575-6578. |
[22] | Liu, Miaomiao;Li, Fengyan;Sun, Zhixia;Xu, Lin;Song, Yufei;Munventwali, Alexis.Enhanced photocatalytic H-2 evolution on CdS with cobalt polyoxotungstosilic and MoS2/graphene as noble-metal-free dual co-catalysts[J].RSC Advances,201559(59):47314-47318. |
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