CuInS2量子点因低毒、良好的光电性能和热电稳定性而成为量子点敏化太阳能电池（QDSSC）极具前景的量子点敏化剂。首先简单介绍了CuInS2量子点材料的光电性质和QDSSC中CuInS2量子点的合成，然后重点总结了CuInS2量子点敏化电极的制备及各电池材料对QDSSC性能的影响，最后指出了该电池目前存在的问题以及对未来的展望。
CuInS2 quantum dot has become a promising quantum dot sensitizer for quantum dot-sensitized solar cell (QDSSC)due to its low toxicity,excellent photoelectric properties and good thermoelectric stability.The photo-electric properties of CuInS2 quantum dots and the synthesis of CuInS2 quantum dots for QDSSC are summarized.Then the preparation methods of CuInS2 quantum dots-sensitized electrodes and the influence of the materials on the perfor-mance of CuInS2 QDSSC are discussed.Finally,the current problems and outlook of the CuInS2 QDSSC are also pointed out.
参考文献
| [1] | Simon Mathew;Aswani Yella;Peng Gao.Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers[J].Nature Chemistry,20143(3):242-247. |
| [2] | Prashant V. Kamat.Quantum Dot Solar Cells. The Next Big Thing in Photovoltaics[J].Journal of physical chemistry letters,20136(6):908-918. |
| [3] | Daniel N. Congreve;Jiye Lee;Nicholas J. Thompson;Eric Hontz;Shane R. Yost;Philip D. Reusswig;Matthias E. Bahlke;Sebastian Reineke;Troy Van Voorhis;Marc A. Baldo.External Quantum Efficiency Above 100% in a Singlet-Exciton-Fission-Based Organic Photovoltaic Cell[J].Science,2013Apr.19 TN.6130(Apr.19 TN.6130):334-337. |
| [4] | Zaban A.;Gregg BA.;Nozik AJ.;Micic OI..Photosensitization of nanoporous TiO2 electrodes with InP quantum dots[J].Langmuir: The ACS Journal of Surfaces and Colloids,199812(12):3153-3156. |
| [5] | Iwan Moreels;Karel Lambert;David De Muynck.Composition and Size-Dependent Extinction Coefficient of Colloidal PbSe Quantum Dots[J].Chemistry of Materials: A Publication of the American Chemistry Society,200725(25):6101-6106. |
| [6] | González-Pedro, V.;Xu, X.;Mora-Seró, I.;Bisquert, J..Modeling high-efficiency quantum dot sensitized solar cells[J].ACS nano,201010(10):5783-5790. |
| [7] | Nozik, AJ.Multiple exciton generation in semiconductor quantum dots[J].Chemical Physics Letters,20081/3(1/3):3-11. |
| [8] | Hanna MC;Nozik AJ.Solar conversion efficiency of photovoltaic and photoelectrolysis cells with carrier multiplication absorbers[J].Journal of Applied Physics,20067(7):74510-1-74510-8-0. |
| [9] | Blackburn JL;Selmarten DC;Ellingson RJ;Jones M;Micic O;Nozik AJ.Electron and hole transfer from indium phosphide quantum dots[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,20057(7):2625-2631. |
| [10] | Yu PR;Zhu K;Norman AG;Ferrere S;Frank AJ;Nozik AJ.Nanocrystalline TiO2 solar cells sensitized with InAs quantum dots[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200650(50):25451-25454. |
| [11] | Liao, Yulong;Zhang, Jin;Liu, Weiguo;Que, Wenxiu;Yin, Xingtian;Zhang, Dainan;Tang, Longhuang;He, Weidong;Zhong, Zhiyong;Zhang, Huaiwu.Enhancing the efficiency of CdS quantum dot-sensitized solar cells via electrolyte engineering[J].Nano Energy,2015:88-95. |
| [12] | Liang Tao;Yan Xiong;Hong Liu.High performance PbS quantum dot sensitized solar cells via electric field assisted in situ chemical deposition on modulated TiO2 nanotube arrays[J].Nanoscale,20142(2):931-938. |
| [13] | Zhou, Ru;Niu, Haihong;Zhang, Qifeng;Uchaker, Evan;Guo, Zhiqiang;Wan, Lei;Miao, Shiding;Xu, Jinzhang;Cao, Guozhang.Influence of deposition strategies on CdSe quantum dot-sensitized solar cells: a comparison between successive ionic layer adsorption and reaction and chemical bath deposition[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,201523(23):12539-12549. |
| [14] | Samadpour, M.;Iraji zad, A.;Taghavinia, N.;Molaei, M..A new structure to increase the photostability of CdTe quantum dot sensitized solar cells[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,20114(4):045103-1-045103-6. |
| [15] | Tubtimtae, A.;Wu, K.-L.;Tung, H.-Y.;Lee, M.-W.;Wang, G.J..Ag_2S quantum dot-sensitized solar cells[J].Electrochemistry communications,20109(9):1158-1160. |
| [16] | D.O. Henderson;R. Mu;A.Ueda.Optical and structural characterization of copper indium disulfide thin films[J].Materials & Design,20017(7):585-589. |
| [17] | Hergert F;Hock R;Schorr S.Pentanary chalcopyrite compounds without tetragonal deformation in the heptanary system Cu(Al,Ga,In)(S,Se,Te)(2)[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,20071(1):44-46. |
| [18] | Castro SL.;Bailey SG.;Raffaelle RP.;Banger KK.;Hepp AF..Nanocrystalline chalcopyrite materials (CuInS2 and CuInSe2) via low-temperature pyrolysis of molecular single-source precursors[J].Chemistry of Materials,200316(16):3142-3147. |
| [19] | Weimin Du;Xuefeng Qian;Jie Yin.Shape-and Phase-Controlled Synthesis of Monodisperse,Single-Crystalline Ternary Chalcogenide Colloids through a Convenient Solution Synthesis Strategy[J].Chemistry: A European journal,200731(31):8840-8846. |
| [20] | Xie, RG;Rutherford, M;Peng, XG.Formation of High-Quality I-III-VI Semiconductor Nanocrystals by Tuning Relative Reactivity of Cationic Precursors[J].Journal of the American Chemical Society,200915(15):5691-5697. |
| [21] | Peng, Z.;Liu, Y.;Shu, W.;Chen, K.;Chen, W..Synthesis of various sized CuInS 2 quantum dots and their photovoltaic properties as sensitizers for TiO 2 photoanodes[J].European journal of inorganic chemistry,201232(32):5239-5244. |
| [22] | Pralay K. Santra;Pratheesh V. Nair;K. George Thomas.CuInS2-Sensitized Quantum Dot Solar Cell. Electrophoretic Deposition, Excited-State Dynamics, and Photovoltaic Performance[J].Journal of physical chemistry letters,20135(5):722-729. |
| [23] | Tzung-Luen Li;Hsisheng Teng.Solution synthesis of high-quality CuInS2 quantum dots as sensitizers for TiO2 photoelectrodes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201018(18):3656-3664. |
| [24] | Xing Hu;Quanxin Zhang;Xiaoming Huang.Aqueous colloidal CuInS2 for quantum dot sensitized solar cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201140(40):15903-15905. |
| [25] | Kuan-Ting Kuo;Dean-Mo Liu;San-Yuan Chen.Gore-shell CuInS2/ZnS quantum dots assembled on short ZnO nanowires with enhanced photo-conversion efficiency[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200937(37):6780-6788. |
| [26] | Rajiv Ramanujam Prabhakar;Stevin Snellius Pramana;K. R. G. Karthik.Ultra-thin conformal deposition of CuInS2 on ZnO nanowires by chemical spray pyrolysis[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201228(28):13965-13968. |
| [27] | Yong Shi;Fanghong Xue;Chunyan Li;Qidong Zhao;Zhenping Qu;Xinyong Li.Effects of hydrothermal annealing on characteristics of CuInS_2 thin films by SILAR method[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,201219(19):7465-7469. |
| [28] | Lee, H;Wang, MK;Chen, P;Gamelin, DR;Zakeeruddin, SM;Gratzel, M;Nazeeruddin, MK.Efficient CdSe Quantum Dot-Sensitized Solar Cells Prepared by an Improved Successive Ionic Layer Adsorption and Reaction Process[J].Nano letters,200912(12):4221-4227. |
| [29] | Chang, J.-Y.;Su, L.-F.;Li, C.-H.;Chang, C.-C.;Lin, J.-M..Efficient "green" quantum dot-sensitized solar cells based on Cu _2S-CuInS _2-ZnSe architecture[J].Chemical communications,201240(40):4848-4850. |
| [30] | Chia-Chan Chang;Jem-Kun Chen;Chih-Ping Chen.Synthesis of Eco-Friendly CulnS2 Quantum Dot-Sensitized Solar Cells by a Combined Ex Situ/in Situ Growth Approach[J].ACS applied materials & interfaces,201321(21):11296-11306. |
| [31] | Zhuoyin Peng;Yueli Liu;Yinghan Zhao;Wei Shu;Keqiang Chen;Qiaoliang Bao;Wen Chen.Efficiency enhancement of TiO_2 nanodendrite array electrodes in CuInS_2 quantum dot sensitized solar cells[J].Electrochimica Acta,2013:755-761. |
| [32] | Jara, Danilo H.;Yoon, Seog Joon;Stamplecoskie, Kevin G.;Kamat, Prashant V..Size-Dependent Photovoltaic Performance of CuInS2 Quantum Dot-Sensitized Solar Cells[J].Chemistry of Materials: A Publication of the American Chemistry Society,201424(24):7221-7228. |
| [33] | Yuan-qiang Wang;Yi-chuan Rui;Qing-hong Zhang.A Facile in Situ Synthesis Route for CulnS2 Quantum-Dots/In2S3 Co-Sensitized Photoanodes with High Photoelectric Performance[J].ACS applied materials & interfaces,201322(22):11858-11864. |
| [34] | Tzung-Luen Li;Yuh-Lang Lee;Hsisheng Teng.CuInS2 quantum dots coated with CdS as high-performance sensitizers for TiO2 electrodes in photoelectrochemical cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201113(13):5089-5098. |
| [35] | Jia-Yaw Chang;Jie-Mo Lin;Li-Fong Su.Improved Performance of CulnS2 Quantum Dot-Sensitized Solar Cells Based on a Multilayered Architecture[J].ACS applied materials & interfaces,201317(17):8740-8752. |
| [36] | Santra, P.K.;Kamat, P.V..Mn-doped quantum dot sensitized solar cells: A strategy to boost efficiency over 5%[J].Journal of the American Chemical Society,20125(5):2508-2511. |
| [37] | Luo, J.;Wei, H.;Huang, Q.;Hu, X.;Zhao, H.;Yu, R.;Li, D.;Luo, Y.;Meng, Q..Highly efficient core-shell CuInS_2-Mn doped CdS quantum dot sensitized solar cells[J].Chemical communications,201337(37):3881-3883. |
| [38] | Hunter McDaniel;Nobuhiro Fuke;Jeffrey M. Pietryga.Engineered CuInSe_xS_(2-x) Quantum Dots for Sensitized Solar Cells[J].Journal of physical chemistry letters,20133(3):355-361. |
| [39] | Yuh-Lang Lee;Chi-Hsiu Chang.Efficient Polysulfide Electrolyte For Cds Quantum Dot-sensitized Solar Cells[J].Journal of Power Sources,20081(1):584-588. |
| [40] | Yuh-Lang Lee;Yi-Siou Lo.Highly Efficient Quantum-dot-sensitized Solar Cell Based On Co-sensitization Of Cds/cdse[J].Advanced functional materials,20094(4):604-609. |
| [41] | Cheng-Yu Lin;Chiao-Yi Teng;Tzung-Luen Li.Photoactive p-type PbS as a counter electrode for quantum dot-sensitized solar cells[J].Journal of Materials Chemistry, A. Materials for energy and sustainability,20134(4):1155-1162. |
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