欢迎登录材料期刊网

材料期刊网

高级检索

高分子聚合物与碱金属盐的络合物具有离子导电性,是电化学材料领域在过去25年里的重要发现之一,它的发现揭开了人们研究固体电解质的序幕.高分子全固态复合电解质由于具有良好的离子传输能力、成膜性能和力学性能,已成为电致变色器件等电化学装置中的重要组成部分.总结了聚合物电解质的种类,电导率的影响因素与表征方法,分析了全固态聚合物电解质材料的制备工艺与应用.新型复合聚合物电解质材料具有很好的市场前景和十分明显的社会经济效益,对此课题的进一步深入研究和技术上的突破有可能导致新能源材料领域,尤其是电池材料领域的一场新的技术革命.

参考文献

[1] M. Ueno;N. Imanishi;K. Hanai;T. Kobayashi;A. Hirano;O. Yamamoto;Y. Takeda.Electrochemical properties of cross-linked polymer electrolyte by electron beam irradiation and application to lithium ion batteries[J].Journal of Power Sources,201110(10):4756-4761.
[2] Pitawala, HMJC;Dissanayake, MAKL;Seneviratne, VA;Mellander, BE;Albinson, I.Effect of plasticizers (EC or PC) on the ionic conductivity and thermal properties of the (PEO)(9)LiTf: Al2O3 nanocomposite polymer electrolyte system[J].Journal of Solid State Electrochemistry,20087/8(7/8):783-789.
[3] So Yeon Bang;Kyung Ju Lee;Joo Hwan Koh.PEO electrolytes containing dioctyl phthalate(DOP)for dye-sensitized nanocrystalline TiO2 solar cells[J].Ionics,20082(2):143-148.
[4] An, SY;Jeong, IC;Won, MS;Jeong, ED;Shim, YB.Effect of additives in PEO/PAA/PMAA composite solid polymer electrolytes on the ionic conductivity and Li ion battery performance[J].Journal of Applied Electrochemistry,20099(9):1573-1578.
[5] 李瑾.聚合物电解质的发展及应用[J].上海电力学院学报,2009(04):369-373,395.
[6] 宋兆爽;其鲁;邱景义;马建伟.辐照交联法制备锂离子电池用凝胶聚合物电解质及其性能[J].物理化学学报,2007(12):1932-1936.
[7] Mrinal Sinha;M. Maitra Goswami;D. Mal.Effect of gamma irradiation on the polymer electrolyte PEO-NH4ClO4[J].Ionics,20084(4):323-327.
[8] 李朝晖;苏光耀;高德淑.溶胶-凝胶法制备微孔复合聚合物电解质[J].高分子材料科学与工程,2006(04):231-234.
[9] Appetecchi GB.;Passerini S..PEO-carbon composite lithium polymer electrolyte[J].Electrochimica Acta,200013(13):2139-2145.
[10] 于福新;张海朗.锂离子电池凝胶聚合物电解质[J].化工时刊,2007(9):58-61.
[11] 袁艳;陈白珍;胡拥军.聚合物电解质P(VDF-HFP)/PVP的制备和性能研究[J].电池,2006(4):260-262.
[12] Bandara, TMWJ;Mellander, BE;Albinsson, I;Dissanayake, MAKL.Effect of thermal history and characterization of plasticized, composite polymer electrolyte based on PEO and tetrapropylammonium iodide salt (Pr4N+I-)[J].Solid state ionics,20094/5(4/5):362-367.
[13] B.K. Choi;Y.W. Kim.Thermal history effects on the ionic conductivity of PEO-salt electrolytes[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,20043(3):244-250.
[14] 余丽丽;朱俊杰;赵景泰.超级电容器的现状及发展趋势[J].自然杂志,2015(3):188-196.
[15] A. Lewandowski;M. Zajder;E. Frackowiak;F. Beguin.Supercapacitor based on activated carbon and polyethylene oxide-KOH-H{sub}2O polymer electrolyte[J].Electrochimica Acta,200118(18):2777-2780.
[16] D. Kalpana;N. G. Renganathan;S. Pitchumani.A new class of alkaline polymer gel electrolyte for carbon aerogel supercapacitors[J].Journal of Power Sources,20061(1):621-623.
[17] 徐洪峰;刘晶;万莉.固体聚合物电解质电导率式湿度传感器[J].分析化学,2004(6):835-835.
[18] 卢崇考,周明军.电容式高分子湿敏材料感湿机理探讨及选择方法[C].云南大学学报(自然科学版)(Vel.19)(中国电子学会气湿敏第四届全国学术交流会:论文专辑),1996:166~170.
[19] R. TAO;T. FUJINAMI.Improvement of electrochemical properties of PEO-LiTFSI electrolyte by incorporation of boroxine polymers with different backbone lengths[J].Journal of Applied Electrochemistry,20052(2):163-168.
[20] Lu SR;Wei C;Yu JH;Yang XW;Jiang YM.Preparation and characterization of epoxy nanocomposites by using PEO-grafted silica particles as modifier[J].Journal of Materials Science,200716(16):6708-6715.
[21] Mohan VM;Raja V;Bhargav PB;Sharma AK;Rao VVRN.Structural, electrical and optical properties of pure and NaLaF4 doped PEO polymer electrolyte films[J].Journal of Polymer Research,20074(4):283-290.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%