介质阻挡放电等离子体辅助球磨及其在材料制备中的应用

金属学报, 2016, 52(10): 1239-1248. doi: 10.11900/0412.1961.2016.00360

介质阻挡放电等离子体辅助球磨及其在材料制备中的应用

朱敏 ^1,2*,, , 鲁忠臣 ^2,3, , 胡仁宗 ^1,2, , 欧阳柳章 ^1,2,

1 华南理工大学材料科学与工程学院, 广州510640

2 华南理工大学广东省先进储能材料重点实验室, 广州510640

3 华南理工大学机械与汽车工程学院, 广州510640

朱敏, 男, 1962 年生, 教授;

基金项目: 国家自然科学基金项目51231003 国家重点基础研究发展计划项目2010CB631300 广东省自然科学基金项目05200618 广东省实验室体系建设项目2012A061400002 资助国家自然科学基金创新群体项目NSFC51621001

关键词：机械合金化 , 等离子体 , 外场辅助球磨 , 硬质合金 , 锂离子电池材料 , 储氢材料

Dielectric Barrier Discharge Plasma Assisted Ball Milling Technology and Its Applications in Materials Fabrication

ZHU Min ^1,2*,, , LU Zhongchen ^2,3, , HU Renzong ^1,2, , OUYANG Liuzhang ^1,2,

1 School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China

2 Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, South China University of Technology, Guangzhou 510640, China

3 School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640,China

Correspondence author: ZHU Min, memzhu@scut.edu.cn

ZHU Min, professor, Tel: (020)87113924, E-mail: memzhu@scut.edu.cn;

Keywords： mechanical alloying , plasma , external field assisted mill , cemented carbide , anode material for lithium ion battery , hydrogen storage material

简述了外场辅助球磨技术的发展及其在材料制备中的应用. 介绍了近年来发展的介质阻挡放电等离子体(DBDP)辅助球磨新技术的基本原理和方法, 阐述了DBDP辅助球磨利用等离子体的热效应、高能电子轰击效应和球磨机械力效应的协同作用, 增强粉体在球磨过程中的组织细化、活性激活、化学反应等效果和机理. 在此基础上, 简要介绍了该方法在硬质合金、锂离子电池负极材料、储氢材料等制备中的应用. 研究结果表明, 采用DBDP辅助球磨制备上述材料, 不仅极大提高了球磨方法制备材料的效率, 而且通过形成独特的结构显著提高了材料的性能; 此外, 还有可能建立新的材料生产制备工艺. 已取得的研究结果表明, DBDP辅助球磨技术在粉末材料细化、材料表面改性、机械合金化、复合材料制备和气固反应等方面具有巨大的潜力.

The development of external field assisted milling technologies and their application in materials fabrication have been briefly described. A recent developed milling method named as dielectric barrier discharge plasma assisted ball milling (DBDP-milling) was introduced. A combination of heating effect and high energy electron bombardment effect produced by plasma, as well as the milling mechanical effect was induced simultaneously in the DBDP-milling, which can effectively promote the powder refinement, activation and chemical reaction. On this basis, the DBDP-milling method was applied in the fabrication of cemented carbide, anode materials for lithium ion batteries, hydrogen storage materials, and so on. The studies have indicated that DBDP-milling could improve the efficiency of mill, produce unique structure and thus enhanced properties. In addition, DBDP-milling is also possible to establish a new material production process. Research results have demonstrated that the DBDPmilling method has a great potential in refinement, surface modification, mechanical alloying, composite fabrication and gas-solid reaction of powder materials for different applications.

参考文献

[1]	Benjamin J S. Metall Trans, 1970; 1: 2943
[2]	Koch C C. Nanostruct Mater, 1993; 2: 109
[3]	Dai L Y, Chen Q L, Lin S F, Ouyang L Z. Mater Rev, 2009; 23(2):59
[4]	(戴乐阳, 陈清林, 林少芬, 欧阳柳章. 材料导报, 2009; 23(2): 59)
[5]	Dai L Y, Zeng M Q, Tong Y Q, Ouyang L Z, Zhu M, Li Y Y. J Funct Mater, 2005; 36: 1158
[6]	Mordyuk B N, Prokopenko G I. Ultrasonics, 2004; 42: 43
[7]	(戴乐阳, 曾美琴, 童燕青, 欧阳柳章, 朱敏, 李元元. 功能材料,2005; 36: 1158)
[8]	Calka A, Radlinski A P. Mater Sci Eng, 1991; A134: 1350
[9]	Wang D P, Li X D, Chang Y, Qi M. J Rare Earth (Engl Lett), 2013;31: 366
[10]	Chelvane J A, Palit M, Basumatary H, Pandian S. J Magn Magn Mater, 2013; 343: 144
[11]	Luton M J, Jayanth C S, Disko M M, Matrasa1 S, Vallon J. In: Kear B H, McCandlish L E, Polk D E, Siegel R W eds., MRS Proceedings,Cambridge University Press, 1988; 132: 79
[12]	Chung K H, He J H, Shin D H. Mater Sci Eng, 2003; A356: 23
[13]	Calka A,Wexler D. Nature, 2002; 419: 147
[14]	Calka A,Wexler D. J Metastable Nanocryst Mater, 2004; 20: 111
[15]	Mosbah A, Calka A,Wexler D. J Alloys Compd, 2006; 424: 279
[16]	Varin R A, Chiu C, Li S, Calka A, Wexler D. J Alloys Compd,2004; 370: 230
[17]	Calka A, Mosbah A, Stanford N, Balaz P. J Alloys Compd, 2008;455: 285
[18]	Needham S A, Calka A, Wang G X, Mosbah A, Liu H K. Electochem Commun, 2006; 8: 434
[19]	Yuan Q, Zheng Y, Yu H. Int J Refract Met Hard Mater, 2009; 27:121
[20]	Quan Y, Zheng Y, Yu H Z. Trans Nonferrous Met Soc China,2011; 21: 1545
[21]	Zhu M, Dai L Y, Cao B, Zeng M Q, Ouyang L Z, Tong Y Q, Li B.China Patent, ZL200510036231, 2007)
[22]	Wang X X. High Volt Eng, 2009; 35(1): 1
[23]	Yang X P, Dai L Y, Zeng M Q, Ouyang L Z. Mater Rev, 2010; 24:320
[24]	Sun Q D. Master Thesis, Tianjin University, 2013
[25]	(朱敏, 戴乐阳, 曹彪, 曾美琴, 欧阳柳章, 童燕青, 李北. 中国专利, ZL200510036231, 2007)
[26]	Dai L Y, Lin S F, Chen Q L, Yang X P. Mod Manuf Eng, 2010; 5(5): 48
[27]	Dai L Y. PhD Dissertation, South China University of Technology,Guangzhou, 2006
[28]	(王新新. 高电压技术, 2009; 35(1): 1)
[29]	Zhu M, Dai L Y, Gu N S, Cao B, Ouyang L Z. J Alloys Compd,2009; 478: 624
[30]	Dai LY. Acta Metall Sin (Engl Lett), 2013; 26: 63
[31]	(杨小平, 戴乐阳, 曾美琴, 欧阳柳章. 材料导报, 2010; 24: 320)
[32]	Dai LY, Cao B, Zhu M. Acta Metall Sin (Engl Lett), 2006; 19: 411
[33]	Conrad H, Yang D. Acta Mater, 2002; 50: 2851
[34]	(孙启迪. 天津大学硕士学位论文, 2013)
[35]	Chen Z H. Master Thesis, South China University of Technology Guangzhou, 2015
[36]	Jia C X, Chen P, Wang Q, Wang J, Ren R. Chin J Mater Res,2015; 29: 10
[37]	(戴乐阳, 林少芬, 陈清林, 杨小平. 现代制造工程, 2010; 5(5):48)
[38]	Meng R G. Master Thesis, Jimei University, Xiamen, 2013
[39]	Yang X P. Master Thesis, South China University of Technology,Guangzhou, 2010
[40]	(戴乐阳, 华南理工大学博士学位论文, 广州, 2006)
[41]	Dai L Y, Lin S F, Chen J F, Zeng M Q, Zhu M. Int J Refract Met Hard Mater, 2012; 30: 48
[42]	Zhu M, Bao X Y, Yang X P, Gu N S, Wang H, Zeng M Q, Dai L Y.Metall Mater Trans, 2011; 42: 2930
[43]	Wang W, Lu Z C, Chen Z H, Zeng M Q, Wang H, Zhu M. J Rare Earth (Engl Lett), DOI: 10.1007/S12598-016-0769-5
[44]	Hu R Z, Yang L C, Zhu M. Chin Sci Bull (Chin Ver), 2013; 58:3140
[45]	Hu R Z. PhD Dissertation, South China University of Technology,Guangzhou, 2011
[46]	(陈志鸿. 华南理工大学硕士学位论文, 广州, 2015)
[47]	Liu H, Hu R, Zeng M, Liu J W, Zhu M. J Mater Chem, 2012;22A: 8022
[48]	Hui L, Hu R Z, Sun W, Zeng M Q, Yang L C, Liu J W, Zhu M, J Power Sources, 2013; 242: 114
[49]	(贾彩霞, 陈平, 王乾, 王静, 任荣. 材料研究学报, 2015; 29: 10)
[50]	Zhang H Y, Hu R Z, Liu H, Sun W, Lu Z C, Liu J W, Yang L C, Zhang Y, Zhu M. J Mater Chem, 2016; 4A: 10321
[51]	W. Sun, R.Z.Hu, H. Liu, M. Q. Zeng, M. Zhu. J Power Sources,2014; 268:610
[52]	(孟荣刚. 集美大学硕士学位论文, 厦门, 2013)
[53]	Ouyang L Z, Guo L N, Cai W H, Ye J S, Hu R Z, Liu J W, Yang LC, Zhu M. J Mater Chem A, 2014; 2A: 11280
[54]	Wang Y K, Yang L C, Hu R Z, Sun W, Liu J W, Ouyang L Z, Yuan B,Wang H, Zhu M. J Power Sources, 2015; 288: 314
[55]	Zaluska A, Zaluski L, Ström–Olsen J O. J Alloys Compd, 1999;288: 217
[56]	(杨小平. 华南理工大学硕士学位论文, 广州, 2010)
[57]	Huot J, Tremblay M L, Schulz R. J Alloys Compd, 2003; 356: 603
[58]	Lu Y S, Zhu M, Wang H, Li Z M, Ouyang L Z, Liu J W. Int J Hydrogen Energy, 2014; 39: 14033
[59]	Ouyang L Z, Cao Z J, Wang H, Liu J W, Sun D L, Zhang Q A,Zhu M. J Alloys Compd, 2014; 586: 113
[60]	Cao Z J, Ouyang L Z, Wu Y, Wang H, Liu J W, Fang F, Sun D L,Zhang Q A, Zhu M. Dual-tuning effects of In, Al, and Ti on the thermodynamics and kinetics of Mg85In5Al5Ti5 alloy synthesized by plasma milling. J Alloys Compd, 2015; 623: 354
[61]	Ouyang L Z, Cao Z J, Li L L, Wang H, Liu J W, Min D, Chen Y W, Xiao F M, Tang R H, Zhu M. Int J Hydrogen Energy, 2014;39: 12765
[62]	(胡仁宗, 杨黎春, 朱敏. 科学通报(中文版), 2013; 58: 3140)
[63]	Dai L Y, Zhang B J, Lin S F, Liu Z J, Wang W C. Chin J Nonferrous Met, 2015; 1: 171
[64]	(胡仁宗. 华南理工大学博士学位论文, 广州, 2011)
[65]	(戴乐阳, 张宝剑, 林少芬, 刘志杰, 王文春. 中国有色金属学报,2015; 1: 171)

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