近年来,以生物分子作为配体连接金属离子形成的多孔材料金属-生物分子框架配合物(MBioFs)受到广泛的关注,并成为配位化学与生物材料科学之间新的交叉学科.作为核酸的核心组分的核酸碱基,拥有氮、氧孤对电子,使其可以作为多齿配体.我们用溶剂热法以不同的核酸碱基合成了一系列的金属-生物分子框架配合物.由于桥连配体核酸碱基配位性质的不同,这些金属-生物分子框架配合物表现出不同的微观结构.此外,它们可以周期性的吸收和释放有机物分子,因此可以用于污水处理.
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