欢迎登录材料期刊网

材料期刊网

高级检索

分别将离子液体三正丁基甲铵(双三氟甲磺酰)亚胺盐([TBMA][NTf2])和1-乙基-3-甲基咪唑四氟硼酸盐([EMIM][BF4])与乙烯-醋酸乙烯共聚物弹性体(EVM)熔融共混制备复合材料,研究了离子液体与EVM的相容性及抗静电性能.样品宏观透明性和SEM测试结果显示,[TBMA][NTf2]与EVM具有较好的相容性,相应的EVM/[TBMA][NTf2]复合材料的抗静电效果更好;热重分析(TGA)结果表明,[TBMA][NTf2]促进EVM热解,而[EMIM][BF4]对EVM的热稳定影响较小.室温下在EVM中填加[TBMA][NTf2]的共混物表现出较好的柔性,当[TBMA][NTf2]质量分数为20%时,EVM/[TBMA][NTf2]复合材料的模量为0.58 MPa,断裂伸长率可达到2997%.

参考文献

[1] Jonathan G. Huddleston;Ann E. Visser;W. Matthew Reichert.Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation[J].Green chemistry,20014(4):156-164.
[2] Liping Zhao;Yongjin Li;Zhifu Liu.Carbon Nanotube-Conducting Polymer Core-Shell Hybrid Using an Imidazolium-Salt-Based Ionic Liquid As a Linker:Designed As a Potential Platinum Electrode Alternative Material for Large-Scale Solution Processing[J].Chemistry of Materials: A Publication of the American Chemistry Society,201021(21):5949-5956.
[3] Ye Chen;Jing Tao;Lin Deng.Polyetherimide/Bucky Gels Nanocomposites with Superior Conductivity and Thermal Stability[J].ACS applied materials & interfaces,201315(15):7478-7484.
[4] Scott MP.;Rahman M.;Brazel CS..Application of ionic liquids as low-volatility plasticizers for PMMA[J].European Polymer Journal,200310(10):1947-1953.
[5] Hong Xu;Fangfang Tong;Jian Yu.A one-pot method to prepare transparent poly(methyl methacrylate)/montmorillonite nanocomposites using imidazolium-based ionic liquids[J].Polymer international,20129(9):1382-1388.
[6] Chenyang Xing;Xin Zheng;Liqun Xu.Toward an Optically Transparent Antielectrostatic, and Robust Polymer Composite: Morphology and Properties of Polycarbonate/ Ionic Liquid Composites[J].Industrial & Engineering Chemistry Research,201411(11):4304-4311.
[7] Zhao, L.;Li, Y.;Cao, X.;You, J.;Dong, W..Multifunctional role of an ionic liquid in melt-blended poly(methylmethacrylate)/ multi-walled carbon nanotube nanocomposites[J].Nanotechnology,201225(25):255702-1-255702-8.
[8] Wang, L.;Jiang, P.K..Thermal and flame retardant properties of ethylene-vinyl acetate copolymer/modified multiwalled carbon nanotube composites[J].Journal of Applied Polymer Science,20115(5):2974-2983.
[9] Di Wei;Ari Ivaske.Applications of ionic liquids in electrochemical sensors[J].Analytica chimica acta,20082(2):126-135.
[10] Mark P. Scott;Christopher S. Brazel;Michael G. Benton;Jimmy W. Mays;John D. Holbrey;Robin D. Rogers.Application of ionic liquids as plasticizers for poly(methyl methacrylate)[J].Chemical communications,200213(13):1370-1371.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%