通过钨离子印记方法,合成了对铜离子有高选择性吸附性能的碳基材料.在四乙烯五胺(TEPA)、钨酸铵和葡萄糖摩尔比为1:1:5条件下,经水热法合成的碳基吸附材料能有效地吸附铜离子,对铜离子吸附的最佳pH =5.在Cd2、Co2、Cu2+、Ni2+和Zn2摩尔浓度相近体系中,离子印记碳基吸附材料对铜离子的吸附率高达97.2%,而对Cd2+、Co2、Ni2、Zn2吸附率分别为20.1%、9.63%、20.3%、13.3%,表明这种离子印记碳基吸附材料对Cu2具有非常优异的选择吸附能力.
参考文献
[1] | Shengling Sun;Aiqin Wang.Adsorption properties of carboxymethyl-chitosan and cross-linked carboxymethyl-chitosan resin with Cu(II)as template[J].Separation and Purification Technology,20063(3):197-204. |
[2] | Qiu, H.;Zhang, S.;Pan, B.;Zhang, W.;Lv, L..Effect of sulfate on Cu(II) sorption to polymer-supported nano-iron oxides: Behavior and XPS study[J].Journal of Colloid and Interface Science,2012:37-43. |
[3] | Yueming Ren;Xizhu Wei;Milin Zhang.Adsorption Character For Removal Cu(ii) By Magnetic Cu(ii) Ion Imprinted Composite Adsorbent[J].Journal of hazardous materials,20081(1):14-22. |
[4] | Raja S. Azarudeen;R. Subha;D. Jeyakumar.Batch separation studies for the removal of heavy metal ions using a chelating terpolymer: Synthesis, characterization and isotherm models[J].Separation and Purification Technology,2013:366-377. |
[5] | Zheng Hui Xiao;Rui Zhang;Xiang Ying Chen;Xue Liang Li;Tao Fa Zhou.Magnetically recoverable Ni@carbon nanocomposites: Solid-state synthesis and the application as excellent adsorbents for heavy metal ions[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012:795-803. |
[6] | Fatma Ekmekyapar;Ali Aslan;Y. Kemal Bayhan;Avni Cakici.Biosorption of copper(II) by nonliving lichen biomass of Cladonia rangiformis hoffm[J].Journal of hazardous materials,20061(1):293-298. |
[7] | Ayhan Demirbas.Heavy metal adsorption onto agro-based waste materials: A review[J].Journal of hazardous materials,20082/3(2/3):220-229. |
[8] | E.Demirbas;N.Dizge;M.T.Sulak.Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon[J].Chemical engineering journal,20092/3(2/3):480-487. |
[9] | Zhenhua Li;Jingwen Li;Yanbin Wang;Yajun Wei.Synthesis and application of surface-imprinted activated carbon sorbent for solid-phase extraction and determination of copper (II)[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2014:422-427. |
[10] | Baojiao Gao;Fuqiang An;Yong Zhu.Novel surface ionic imprinting materials prepared via couple grafting of polymer and ionic imprinting on surfaces of silica gel particles[J].Polymer: The International Journal for the Science and Technology of Polymers,20078(8):2288-2297. |
[11] | T.Prasada Rao;R.Kala;S.Daniel.Metal ion-imprinted polymers-Novel materials for selective recognition of inorganics[J].Analytica chimica acta,20062(2):105-116. |
[12] | Huang-Hao Yang;Shu-Qiong Zhang;Wei Yang;Xiao-Lan Chen;Zhi-Xia Zhuang;Jin-Gou Xu;Xiao-Ru Wang.Molecularly Imprinted Sol-Gel Nanotubes Membrane for Biochemical Separations[J].Journal of the American Chemical Society,200413(13):4054-4055. |
[13] | Sui Wang;Ruifeng Zhang.Selective Solid-Phase Extraction of Trace Copper Ions in Aqueous Solution with a Cu(II)-Imprinted Interpenetrating Polymer Network Gel Prepared by Ionic Imprinted Polymer (IIP)Technique[J].Mikrochimica Acta: An International Journal for Physical and Chemical Methods of Analysis,20061/2(1/2):73-80. |
[14] | Chen, Chia-Yun;Yang, Cheng-Yu;Chen, Arh-Hwang.Biosorption of Cu(II), Zn(II), Ni(II) and Pb(II) ions by cross-linked metal-imprinted chitosans with epichlorohydrin[J].Journal of Environmental Management,20113(3):796-802. |
[15] | Cui, C.;He, M.;Chen, B.;Hu, B..Restricted accessed material-copper(II) ion imprinted polymer solid phase extraction combined with inductively coupled plasma-optical emission spectrometry for the determination of free Cu(II) in urine and serum samples[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2013:1040-1046. |
[16] | Vedat Yilmaz;Zikri Arslan;Orhan Hazer;Hayriye Yilmaz.Selective solid phase extraction of copper using a new Cu(II)-imprinted polymer and determination by inductively coupled plasma optical emission spectroscopy (ICP-OES)[J].Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science,2014:65-72. |
[17] | 曹玺珉;廖玲;杜黎明.依诺沙星分子印迹聚合物的分子识别[J].应用化学,2008(1):43-47. |
[18] | 辉永庆;钟志京;何小波;邓义.铅分子印迹聚合物合成及其在痕量测量中的应用[J].应用化学,2009(6):721-725. |
[19] | Ren, L.;Zhu, L.;Yang, C.;Chen, Y.;Sun, Q.;Zhang, H.;Li, C.;Nawaz, F.;Meng, X.;Xiao, F.-S..Designed copper-amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NO_x by NH_3[J].Chemical communications,201135(35):9789-9791. |
[20] | Peng, Wei;Xie, Zhenzhen;Cheng, Ge;Shi, Lei;Zhang, Yibo.Amino-functionalized adsorbent prepared by means of Cu(II) imprinted method and its selective removal of copper from aqueous solutions[J].Journal of hazardous materials,2015Aug.30(Aug.30):9-16. |
[21] | Ju, Jian;Chen, Wei.In Situ Growth of Surfactant-Free Gold Nanoparticles on Nitrogen-Doped Graphene Quantum Dots for Electrochemical Detection of Hydrogen Peroxide in Biological Environments[J].Analytical chemistry,20153(3):1903-1910. |
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