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报道了一种新型的Eu2+离子激活硅酸盐玻璃,该玻璃组成为2CaO-MgO-3SiO2-0.015Eu2O3(CMSE).通过透射光谱、稳态荧光光谱、余辉光谱和热释光等技术手段对CMSE的发光性质进行了深入研究.研究发现CMSE可以被紫光和近紫外光激发,获得黄色长余辉发光.热释光曲线的分析表明,CMSE的长余辉性质主要来自于玻璃基质中陷阱深度为0.83 eV左右的定域能级.研究认为对CMSE发光性质的研究有利于开发新型稀土离子激活近紫外激发LED用硅酸盐玻璃发光材料.

参考文献

[1] 张耀 .应用于交流驱动白光LED荧光材料合成及发光特性研究[D].合肥工业大学,2013.
[2] 郎天春;韩涛;彭玲玲;张进.近紫外LED用荧光粉的研究进展[J].材料导报,2013(23):53-56,65.
[3] 朱立刚 .稀土离子掺杂发光玻璃的制备与性能研究[D].中南大学,2012.
[4] 江莉梅;邹翔宇;韦钦磊;宋琼;邓爽;张洪波;苏春辉.含氟CaO-P2O5-SiO2-Na2O-B2O3玻璃陶瓷的制备及性能表征[J].应用化学,2015(4):442-446.
[5] 金雷;雷小华;任林娇;冯永安;杜晓晴;陈伟民.Eu2+/Dy3+共掺高硅氧发光玻璃发光性质的影响因素分析[J].光谱学与光谱分析,2014(1):34-38.
[6] 张洪波;王轶敏;姜静;崔光;赵磊;邵晶;苏春辉.钕掺杂磷酸盐玻璃陶瓷的制备及表征[J].应用化学,2009(8):948-951.
[7] 冯玉英;顾晓天;周家宏;姚杰;莫祥银;包建春.掺锗SiO2 玻璃的发光现象[J].应用化学,2005(8):926-928.
[8] 江青云;李晨霞;叶仁广;华有杰;徐时清.Ce3+,Tb3+共掺BaYF5微晶玻璃的光学特性[J].发光学报,2011(10):1030-1035.
[9] N. Sooraj Hussain;Y. Prabhakara Reddy;S. Buddhudu.Luminescence spectra of Eu~3+-doped GeO_2--PbO-Bi_2O_3 glasses[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,200110(10):1813-1821.
[10] Lin YH.;Zhang ZT.;Zhang JY.;Chen QM.;Tang ZL..Preparation and properties of photoluminescent rare earth doped SrO-MgO-B2O3-SiO2 glass[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,20011(1):79-82.
[11] Yamazaki M.;Nagahama S.;Sawanobori N.;Mizuguchi M.;Hosono H.;Yamamoto Y..Long luminescent glass: Tb3+-activated ZnO-B2O-SiO2 glass[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,19981(1):71-73.
[12] Su Zhang;Chengyu Li;Qiang Su.Long lasting phosphorescence of Eu2+-activated MO-B2O3 glasses[J].中国光学快报(英文版),2011(7):69-71.
[13] Q.-H. Zhang;J. Wang;C.-W. Yeh;W.-C. Ke;R.-S. Liu;J.-K. Tang;M.-B. Xie;H.-B. Liang;Q. Su.Structure, composition, morphology, photoluminescence and cathodoluminescence properties of ZnGeN_2 and ZnGeN_2:Mn~(2+)for field emission displays[J].Acta materialia,201020(20):6728-6735.
[14] Yanhui Wang;Jianhui Zhang;Dejian Hou;Hongbin Liang;Pieter Dorenbos;Shuaishuai Sun;Ye Tao.Luminescence of Ce~(3+) activated NaCaPO_4 under VUV-UV and X-ray excitation[J].Optical materials,20127(7):1214-1218.
[15] Yoshihisa Ohko;Tetsu Tatsuma;Tsuyoshi Fujii;Kenji Naol;Chisa Niwa;Yoshinobu Kubota;Akira Fujishima.Multicolour photochromism of TiO_2 films loaded with silver nanoparticles[J].Nature materials,20031(1):29-31.
[16] Xiaoyong Zhang;Shiqi Wang;Meiying Liu.Size tunable fluorescent nano-graphite oxides: preparation and cell imaging applications[J].Physical chemistry chemical physics: PCCP,201343(43):19013-19018.
[17] Zhang, S.;Li, C.;Pang, R.;Jiang, L.;Shi, L.;Su, Q..Energy transfer and excitation wavelength dependent long-lasting phosphorescence in Pr~3 activated Y_3Al_5O _(12)[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,201112(12):2730-2734.
[18] Trojan-Piegza J;Niittykoski J;Holsa J;Zych E.Thermoluminescence and kinetics of persistent luminescence of vacuum-sintered Tb3+-doped and Tb3+, Ca2+-codoped LU2O3 materials[J].Chemistry of Materials: A Publication of the American Chemistry Society,20086(6):2252-2261.
[19] A. Lecointre;R. Ait Benhamou;A. Bessiere;G. Wallez;M. Elaatmani;B. Viana.Red long-lasting phosphorescence (LLP) in β-TCP type Ca_(9.5)Mn(PO_4)_7 compounds[J].Optical materials,20112(2):376-380.
[20] Ran Pang;Chengyu Li;Lili Shi;Qiang Su.A novel blue-emitting long-lasting proyphosphate phosphor Sr2P2O7:Eu2+,Y3+[J].The journal of physics and chemistry of solids,20092(2):303-306.
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